Process for the synthesis of bisphenol
    2.
    发明授权
    Process for the synthesis of bisphenol 有权
    合成双酚的方法

    公开(公告)号:US07132575B2

    公开(公告)日:2006-11-07

    申请号:US10612101

    申请日:2003-07-01

    IPC分类号: C07C39/12 C07C39/16

    CPC分类号: C07C37/20 C08G64/20 C07C39/16

    摘要: A process for the production of a bisphenol comprises reacting a feed comprising a phenol, a ketone and water in the presence of an ion exchange resin catalyst to produce an effluent; determining the para—para bisphenol selectivity of the reaction; and adjusting the concentration of the water in the feed based upon the para—para bisphenol selectivity in the effluent.

    摘要翻译: 制备双酚的方法包括在离子交换树脂催化剂存在下使包含苯酚,酮和水的进料反应以产生流出物; 确定反应的对位双酚选择性; 并且基于流出物中对位双酚选择性调节进料中的水的浓度。

    Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom

    公开(公告)号:US20070100038A1

    公开(公告)日:2007-05-03

    申请号:US11263325

    申请日:2005-10-31

    IPC分类号: C08K5/41

    摘要: A thermoplastic composition comprises a polycarbonate, and an aromatic sulfonate compound of formula (Y)m—Ar-(Z-S(O)2—X)n wherein each X is independently a substituted or unsubstituted C1-C20 alkyl, substituted or unsubstituted C1-C20 arylalkyl, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C7-C40 alkylaryl; Z is —O—, or substituted or unsubstituted —(O—C1-20—)w—O—, wherein w is 1 to 20; Ar is a C6-C62 aromatic group; m is 0-3 and n is 3-6; and each Y is independently C1-C20 alkyl, substituted C1-C20 alkyl, C6-C20 aryl, C1-C8 alkyl-substituted C6-C20 aryl, halogen, nitro, C1-C20 alkoxycarbonyl, C1-C20 alkoxy, or C1-C20 acyl, and further wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, aromatic sulfonate compound, and an effective amount of each of a mold-release agent and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.

    Ionizing radiation stable polyarylestercarbonate compositions
    9.
    发明授权
    Ionizing radiation stable polyarylestercarbonate compositions 有权
    电离辐射稳定聚芳酯碳酸酯组合物

    公开(公告)号:US07078447B2

    公开(公告)日:2006-07-18

    申请号:US10718979

    申请日:2003-11-21

    IPC分类号: C08J3/28 C08K5/053 C08L69/00

    摘要: Embodiments of ionizing radiation stable polyarylestercarbonate resin compositions, methods for making the ionizing radiation stable compositions, and articles and medical devices made from these ionizing radiation stable compositions are disclosed. For examples the specification discloses a composition which comprises a block copolyarylestercarbonate and a ionizing radiation stablizing additive. The said copolyarylestercarbonate comprises an organic carbonate block and at least one arylate block. The arylate block comprises arylate structural units derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety. The arylate block has a degree of polymerization of 1 or greater.

    摘要翻译: 公开了电离辐射稳定聚芳酯酯树脂组合物的实施方案,制备电离辐射稳定组合物的方法,以及由这些电离辐射稳定组合物制成的制品和医疗装置。 例如,该说明书公开了一种组合物,其包含嵌段共聚芳酯酯和电离辐射稳定添加剂。 所述共聚酯酯碳酸酯包括有机碳酸酯嵌段和至少一种芳基化物嵌段。 芳基化物嵌段包含衍生自至少一个1,3-二羟基苯部分和至少一个芳族二羧酸部分的芳基化物结构单元。 芳基化物嵌段的聚合度为1以上。