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公开(公告)号：US20140134317A1
公开(公告)日：2014-05-15
申请号：US14125405
申请日：2012-06-06
申请人： Britta Huebner-Keese , Carol E. Mohler , Meinolf Brackhagen , Roland Adden , Robert L. Sammler , Jonathan D. Moore , Matthias Knarr
发明人： Britta Huebner-Keese , Carol E. Mohler , Meinolf Brackhagen , Roland Adden , Robert L. Sammler , Jonathan D. Moore , Matthias Knarr
IPC分类号： A23L1/0522
CPC分类号： A23L11/07 , A23L29/219 , A23L29/262 , C08B11/193 , C08B11/20 , C08L1/28
摘要： Cellulose ethers are described herein which are useful in food compositions. In these cellulose ethers the ether substituents are methyl groups, hydroxyalkyl groups, and optionally alkyl groups being different from methyl, the cellulose ether has a DS(methyl) of from 1.65 to 2.20, an MS(hydroxyalkyl) of from 0.10 to 1.00, and hydroxy groups of anhydroglucose units are substituted with methyl groups such that [s23/s26−0.2*MS(hydroxyalkyl)] is 0.35 or less, wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups.
摘要翻译： 本文描述了可用于食品组合物的纤维素醚。 在这些纤维素醚中，醚取代基是甲基，羟烷基和任选的不同于甲基的烷基，纤维素醚的DS（甲基）为1.65〜2.20，MS（羟烷基）为0.10〜1.00，和 脱水葡萄糖单元的羟基被甲基取代，使得[s23 / s26-0.2 * MS（羟烷基）]为0.35以下，其中s23是脱水葡萄糖单元的摩尔分数，其中只有2-和3中的两个羟基 脱水葡萄糖单元的位置被甲基取代，其中s26是脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和6-位中的两个羟基仅被甲基取代。
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公开(公告)号：US09591870B2
公开(公告)日：2017-03-14
申请号：US14125405
申请日：2012-06-06
申请人： Britta Huebner-Keese , Carol E. Mohler , Meinolf Brackhagen , Roland Adden , Robert L. Sammler , Jonathan D. Moore , Matthias Knarr
发明人： Britta Huebner-Keese , Carol E. Mohler , Meinolf Brackhagen , Roland Adden , Robert L. Sammler , Jonathan D. Moore , Matthias Knarr
IPC分类号： A23L1/0522 , C08B11/20 , C08L1/28 , C08B11/193
CPC分类号： A23L11/07 , A23L29/219 , A23L29/262 , C08B11/193 , C08B11/20 , C08L1/28
摘要： Cellulose ethers are described herein which are useful in food compositions. In these cellulose ethers the ether substituents are methyl groups, hydroxyalkyl groups, and optionally alkyl groups being different from methyl, the cellulose ether has a DS(methyl) of from 1.65 to 2.20, an MS(hydroxyalkyl) of from 0.10 to 1.00, and hydroxy groups of anhydroglucose units are substituted with methyl groups such that [s23/s26−0.2*MS(hydroxyalkyl)] is 0.35 or less, wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups.
摘要翻译： 本文描述了可用于食品组合物的纤维素醚。 在这些纤维素醚中，醚取代基是甲基，羟烷基和任选的不同于甲基的烷基，纤维素醚的DS（甲基）为1.65〜2.20，MS（羟烷基）为0.10〜1.00，和 脱水葡萄糖单元的羟基被甲基取代，使得[s23 / s26-0.2 * MS（羟烷基）]为0.35以下，其中s23是脱水葡萄糖单元的摩尔分数，其中只有2-和3中的两个羟基 脱水葡萄糖单元的位置被甲基取代，其中s26是脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和6-位中的两个羟基仅被甲基取代。
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公开(公告)号：US09394376B2
公开(公告)日：2016-07-19
申请号：US13825697
申请日：2011-10-06
申请人： Roland Adden , Meinolf Brackhagen , Matthias Knarr , Jin Zhao
发明人： Roland Adden , Meinolf Brackhagen , Matthias Knarr , Jin Zhao
CPC分类号： C08B11/02 , A61J3/077 , A61K9/4816 , A61K9/4866 , A61K47/38 , C08B11/193 , C08L1/284
摘要： Cellulose ethers are described herein which are useful in capsules or in coatings for dosage forms. In these cellulose ethers the ether substituents are methyl groups, hydroxyalkyl groups, and optionally alkyl groups being different from methyl, the cellulose ether has an MS (hydroxyalkyl) of 0.05 to 1.00, and hydroxy groups of anhydroglucose units are substituted with methyl groups such that [s23/s26−0.2*MS(hydroxyalkyl)] is 0.35 or less, wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups.
摘要翻译： 本文描述了纤维素醚，其可用于胶囊或用于剂型的包衣。 在这些纤维素醚中，醚取代基是甲基，羟基烷基和任选的不同于甲基的烷基，纤维素醚具有0.05至1.00的MS（羟基烷基），脱水葡萄糖单元的羟基被甲基取代，使得 [s23 / s26-0.2 * MS（羟烷基）]为0.35以下，其中s23为脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和3-位上的两个羟基仅被甲基取代， 其中s26是脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和6-位中的两个羟基仅被甲基取代。
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公开(公告)号：US20140287148A1
公开(公告)日：2014-09-25
申请号：US13993259
申请日：2012-11-15
CPC分类号： C04B24/383 , B28B11/04 , B28B11/042 , C04B16/02 , C04B18/24 , C04B28/02 , C04B28/04 , C04B40/0028 , C08B11/193 , C04B14/06 , C04B24/04 , C04B2103/0027 , C04B2103/302
摘要： Cellulose ethers, wherein at least a part of the hydroxyl groups of the cellulose backbone are substituted by methoxy groups and hydroxyalkoxy groups, and optionally alkoxy groups being different from methoxy groups, having an unconventional distribution of methoxy substituents at the 2-, 3- and 6-positions of the anhydroglucose units are described. Such cellulose ethers exhibit significantly higher thermoreversible gel strengths than any known hydroxyalkyl methyl celluloses of comparable viscosity and kind and level of substitution rendering them useful as additives for building compositions such as cement based tile adhesives. In particular, such cellulose ethers can be used to improve the attainable adhesion strength after heat storage conditioning and the temporal setting characteristics of a building composition.
摘要翻译： 纤维素醚，其中纤维素骨架的至少一部分羟基被甲氧基和羟基烷氧基取代，以及任选的不同于甲氧基的烷氧基，其具有在2-，3-和及其上的非常规分布的甲氧基取代基 描述了脱水葡萄糖单元的6-位。 这种纤维素醚比任何已知的具有相似的粘度和种类和取代度的任何已知的羟烷基甲基纤维素显示出显着更高的热可逆凝胶强度，使得它们可用作建筑组合物如水泥基瓷砖粘合剂的添加剂。 特别地，这种纤维素醚可以用于改善储热调节后的可达到的粘合强度和建筑组合物的时间凝固特性。
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公开(公告)号：US20130193370A1
公开(公告)日：2013-08-01
申请号：US13825733
申请日：2011-10-06
申请人： Roland Adden , Meinolf Brackhagen , Matthias Knarr , Roland Bayer
发明人： Roland Adden , Meinolf Brackhagen , Matthias Knarr , Roland Bayer
IPC分类号： C08L1/28
CPC分类号： C08L1/284 , B01J35/04 , B01J37/0018 , C04B35/185 , C04B35/195 , C04B35/6365 , C04B38/0006 , C04B2111/00793 , C04B2111/0081 , C08B11/193 , C08K3/01 , C08L1/28 , C08L2666/54 , C04B38/0645
摘要： Cellulose ethers are described which are useful in compositions for extrusion-molded bodies. In these cellulose ethers the ether substituents are methyl groups, hydroxyalkyl groups, and optionally alkyl groups being different from methyl, the cellulose ether has an MS (hydroxyalkyl) of 0.11 to 1.00, and hydroxy groups of anhydroglucose units are substituted with methyl groups such that [s23/s26−0.2*MS (hydroxyalkyl)] is 0.35 or less, wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups.
摘要翻译： 描述了可用于挤出成型体的组合物中的纤维素醚。 在这些纤维素醚中，醚取代基是甲基，羟烷基和任选的不同于甲基的烷基，纤维素醚具有0.11至1.00的MS（羟烷基），脱水葡萄糖单元的羟基被甲基取代，使得 [s23 / s26-0.2 * MS（羟烷基）]为0.35以下，其中s23为脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和3-位上的两个羟基仅被甲基取代， 其中s26是脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和6-位中的两个羟基仅被甲基取代。
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公开(公告)号：US09051218B2
公开(公告)日：2015-06-09
申请号：US13993259
申请日：2012-11-15
IPC分类号： C04B24/38 , C04B28/02 , C04B28/04 , C04B40/00 , C08B11/193 , B28B11/04 , C04B16/02 , C04B18/24
CPC分类号： C04B24/383 , B28B11/04 , B28B11/042 , C04B16/02 , C04B18/24 , C04B28/02 , C04B28/04 , C04B40/0028 , C08B11/193 , C04B14/06 , C04B24/04 , C04B2103/0027 , C04B2103/302
摘要： Cellulose ethers, wherein at least a part of the hydroxyl groups of the cellulose backbone are substituted by methoxy groups and hydroxyalkoxy groups, and optionally alkoxy groups being different from methoxy groups, having an unconventional distribution of methoxy substituents at the 2-, 3- and 6-positions of the anhydroglucose units are described. Such cellulose ethers exhibit significantly higher thermoreversible gel strengths than any known hydroxyalkyl methyl celluloses of comparable viscosity and kind and level of substitution rendering them useful as additives for building compositions such as cement based tile adhesives. In particular, such cellulose ethers can be used to improve the attainable adhesion strength after heat storage conditioning and the temporal setting characteristics of a building composition.
摘要翻译： 纤维素醚，其中纤维素骨架的至少一部分羟基被甲氧基和羟基烷氧基取代，以及任选的不同于甲氧基的烷氧基，其具有在2-，3-和及其上的非常规分布的甲氧基取代基 描述了脱水葡萄糖单元的6-位。 这种纤维素醚比任何已知的具有相似的粘度和种类和取代度的任何已知的羟烷基甲基纤维素显示出显着更高的热可逆凝胶强度，使得它们可用作建筑组合物如水泥基瓷砖粘合剂的添加剂。 特别地，这种纤维素醚可以用于改善储热调节后的可达到的粘合强度和建筑组合物的时间凝固特性。
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公开(公告)号：US20130236512A1
公开(公告)日：2013-09-12
申请号：US13825697
申请日：2011-10-06
申请人： Roland Adden , Meinolf Brackhagen , Matthias Knarr , Jin Zhao
发明人： Roland Adden , Meinolf Brackhagen , Matthias Knarr , Jin Zhao
IPC分类号： C08B11/02
CPC分类号： C08B11/02 , A61J3/077 , A61K9/4816 , A61K9/4866 , A61K47/38 , C08B11/193 , C08L1/284
摘要： Cellulose ethers are described herein which are useful in capsules or in coatings for dosage forms. In these cellulose ethers the ether substituents are methyl groups, hydroxyalkyl groups, and optionally alkyl groups being different from methyl, the cellulose ether has an MS (hydroxyalkyl) of 0.05 to 1.00, and hydroxy groups of anhydroglucose units are substituted with methyl groups such that [s23/s26−0.2*MS(hydroxyalkyl)] is 0.35 or less, wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups.
摘要翻译： 本文描述了纤维素醚，其可用于胶囊或用于剂型的包衣。 在这些纤维素醚中，醚取代基是甲基，羟基烷基和任选的不同于甲基的烷基，纤维素醚具有0.05至1.00的MS（羟基烷基），脱水葡萄糖单元的羟基被甲基取代，使得 [s23 / s26-0.2 * MS（羟烷基）]为0.35以下，其中s23为脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和3-位上的两个羟基仅被甲基取代， 其中s26是脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和6-位中的两个羟基仅被甲基取代。
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公开(公告)号：US09580581B2
公开(公告)日：2017-02-28
申请号：US13825733
申请日：2011-10-06
申请人： Roland Adden , Meinolf Brackhagen , Matthias Knarr , Roland Bayer
发明人： Roland Adden , Meinolf Brackhagen , Matthias Knarr , Roland Bayer
IPC分类号： C08F299/04 , C08L1/28 , C08K3/00 , B01J37/00 , C04B35/185 , C04B35/195 , C04B35/636 , C04B38/00 , C08B11/193 , B01J35/04 , C04B111/00
CPC分类号： C08L1/284 , B01J35/04 , B01J37/0018 , C04B35/185 , C04B35/195 , C04B35/6365 , C04B38/0006 , C04B2111/00793 , C04B2111/0081 , C08B11/193 , C08K3/01 , C08L1/28 , C08L2666/54 , C04B38/0645
摘要： Cellulose ethers are described which are useful in compositions for extrusion-molded bodies. In these cellulose ethers the ether substituents are methyl groups, hydroxyalkyl groups, and optionally alkyl groups being different from methyl, the cellulose ether has an MS (hydroxyalkyl) of 0.11 to 1.00, and hydroxy groups of anhydroglucose units are substituted with methyl groups such that [s23/s26−0.2*MS (hydroxyalkyl)] is 0.35 or less, wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups.
摘要翻译： 描述了可用于挤出成型体的组合物中的纤维素醚。 在这些纤维素醚中，醚取代基是甲基，羟烷基和任选的不同于甲基的烷基，纤维素醚具有0.11至1.00的MS（羟烷基），脱水葡萄糖单元的羟基被甲基取代，使得 [s23 / s26-0.2 * MS（羟烷基）]为0.35以下，其中s23为脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和3-位上的两个羟基仅被甲基取代， 其中s26是脱水葡萄糖单元的摩尔分数，其中脱水葡萄糖单元的2-和6-位中的两个羟基仅被甲基取代。
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9.发明申请公开(公告)号：US20130012696A1
公开(公告)日：2013-01-10
申请号：US13576523
申请日：2010-03-30
IPC分类号： C08B11/12
CPC分类号： C08B11/12
摘要： The invention is directed to a process of preparing carboxymethyl cellulose comprising the steps of (a) reacting non-regenerated cellulose with an alkalization agent in the presence of water and isopropyl alcohol and (b) reacting the alkalized cellulose with monohaloacetic acid or a salt thereof, wherein 1.0 to 1.6 mol of the alkalization agent and 15 to 30 mol of water are used in step (a) and 0.5 to 0.8 mol of monohaloacetic acid or a salt thereof are used in step (b), each based on 1 mol of anhydroglucose unit of the cellulose. The invention also relates to carboxymethyl cellulose prepared by that process.
摘要翻译： 本发明涉及一种制备羧甲基纤维素的方法，包括以下步骤：（a）在水和异丙醇的存在下使非再生纤维素与碱化剂反应，和（b）碱化纤维素与单卤代乙酸或其盐的反应 其中，在工序（a）中使用1.0〜1.6摩尔碱化剂和15〜30摩尔水，在工序（b）中使用0.5〜0.8摩尔一卤代乙酸或其盐，各自以1摩尔 脱水葡萄糖单位的纤维素。 本发明还涉及通过该方法制备的羧甲基纤维素。
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公开(公告)号：US20110111229A1
公开(公告)日：2011-05-12
申请号：US12741767
申请日：2008-10-15
IPC分类号： C08B1/00
CPC分类号： C08B11/193 , Y10T428/2982
摘要： The invention relates to innovative cellulose derivatives with low surface swelling in aqueous suspension, with high relative high-shear viscosity, and with high thermal flocculation point in water, and also to their use in building-material systems.
摘要翻译： 本发明涉及在水悬浮液中具有低表面膨胀，具有高相对高剪切粘度和在水中具有高热絮凝点的创新纤维素衍生物，以及它们在建筑材料体系中的应用。
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