公开(公告)号：US4959135A

公开(公告)日：1990-09-25

申请号：US306730

申请日：1989-02-03

申请人： Bruce D. Zenner ,  Joseph P. Ciccone ,  Emory S. De Castro ,  Larrie A. Deardurff ,  John B. Kerr

发明人： Bruce D. Zenner ,  Joseph P. Ciccone ,  Emory S. De Castro ,  Larrie A. Deardurff ,  John B. Kerr

IPC分类号： C01B13/02 ,  C02F1/20 ,  C07F15/06

CPC分类号： C07F15/065 ,  C01B13/0244 ,  C01B2210/0046 ,  C02F1/20

摘要： Methods and apparatus for the extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising linear, pentadentate polyalkylamines and transition metal ions. The carrier compounds have the general formula: ##STR1## where, each of R.sub.1 and R.sub.2 is independently an organic group including a sulfur, an oxygen or a nitrogen coordinated to M;each of m, n, o, and p is 1, 2, 3, or 4;X is selected from the group consisting of 2,6-pyridyl, 2,6-piperidyl, 2,5-pyrrolyl, 2,4-imidazolyl, substituted heterocyclic amines, --)--, --S--, ##STR2## and ##STR3## where R.sub.3 is hydrogen, lower alkyl or aralkyl; and M is a transition metal ion.

摘要翻译： 用于从第一流体环境中提取配体如分子氧并释放配体如分子氧的方法和设备，以及其中包含直链，五齿多聚烷基胺和过渡金属离子的配体载体化合物。 载体化合物具有以下通式：其中，R1和R2各自独立地为包含与M配位的硫，氧或氮的有机基团; m，n，o和p各自为1,2,3或4; X选自2,6-吡啶基，2,6-哌啶基，2,5-吡咯基，2,4-咪唑基，取代的杂环胺， - ） - ，-S-，和其中R3是氢，低级烷基或芳烷基; M是过渡金属离子。

公开(公告)号：US4952289A

公开(公告)日：1990-08-28

申请号：US191519

申请日：1988-05-09

申请人： Joseph P. Ciccone ,  Emory S. DeCastro ,  John B. Kerr

发明人： Joseph P. Ciccone ,  Emory S. DeCastro ,  John B. Kerr

IPC分类号： B01D19/00 ,  B01D53/22 ,  B01D53/32 ,  B01D61/24 ,  C01B13/02 ,  C07D257/00 ,  C07D257/02 ,  C07D259/00 ,  C07D471/08 ,  C07D521/00 ,  C07F13/00 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  H01M8/06

CPC分类号： C07D471/08 ,  C01B13/0251 ,  C01B13/0285 ,  C07D257/02 ,  C07F15/065 ,  H01M8/06 ,  C01B2210/0046 ,  C01B2210/0062

摘要： Methods and apparatus for electrochemical extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising macrocyclic amines having the general formulas: ##STR1## where: A, B, C, D, E, and F are each nitrogen, oxygen, sulfur, or phosphorous;m, n, o, p, q, and r are each typically 2, 3, 4, 5, or 6;the R substituents are each generally H or short chain (linear or branched) alkyl, although R.sub.2 may represent ketyl (.dbd.o); andM is a suitable transition metal ion.

公开(公告)号：US5410052A

公开(公告)日：1995-04-25

申请号：US587973

申请日：1990-09-25

申请人： Kevin M. Smith ,  Joseph P. Ciccone ,  N. Venkata Ramana

发明人： Kevin M. Smith ,  Joseph P. Ciccone ,  N. Venkata Ramana

IPC分类号： C01B13/02 ,  C02F1/20 ,  C07F15/06 ,  C07D237/00 ,  C07C211/00 ,  C07F13/00

CPC分类号： C01B13/0244 ,  C07F15/065 ,  C01B2210/0046 ,  C01B2210/0062 ,  C02F1/20

摘要： Mthods and apparatus for the extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefore comprising linear, pentadentate polyalkylamines and transition metal ions. The carrier compounds have the general formula: ##STR1## where, each of R.sub.1 and R.sub.2 is independently an organic group including a sulfur, an oxygen or a nitrogen coordinated to M;each of m, n. o, and p is 1, 2 3, or 4;X is selected from the group consisting of 2,6-pyridyl, 2,6-piperidyl, 2,5pyrrolyl, 2,4-imidazolyl, substituted heterocyclic amines, --O--, --S-- >P--R.sub.3, and >N--R.sub.3 where R.sub.3 is hydrogen, lower alkyl, or aralkyl; andM is a transition metal ion.

摘要翻译： 用于从第一流体环境中提取诸如分子氧的配体和用于释放诸如分子氧的配体的配体和设备，以及因此配体载体化合物包括线性，五齿多聚烷基胺和过渡金属离子。 载体化合物具有以下通式：其中，R1和R2各自独立地为包含与M配位的硫，氧或氮的有机基团; 每个m，n。 o，p为1,2,3或4; X选自2,6-吡啶基，2,6-哌啶基，2,5-吡咯基，2,4-咪唑基，取代的杂环胺，-O - ， - S-> P-R3和> N- R3，其中R3是氢，低级烷基或芳烷基; M是过渡金属离子。

公开(公告)号：US5096724A

公开(公告)日：1992-03-17

申请号：US317172

申请日：1989-02-28

申请人： Bruce Zenner ,  Emory De Castro ,  Joseph P. Ciccone

发明人： Bruce Zenner ,  Emory De Castro ,  Joseph P. Ciccone

IPC分类号： A23L3/3436 ,  B01D69/14 ,  B01J20/32 ,  B65D51/24 ,  C01B13/02 ,  C12H1/14

CPC分类号： C12H1/14 ,  A23L3/3436 ,  B01D69/142 ,  B01J20/3204 ,  B01J20/3208 ,  B01J20/3212 ,  B01J20/3219 ,  B01J20/3265 ,  B65D51/244 ,  C01B13/0244

摘要： Compositions of matter according to the present invention comprise a carrier compound immobilized in or on a solid phase. The carrier compound is reactive to bind a ligand such as molecular oxygen and includes a complex formed from a transition metal ion and a multidentate organic chelate. The solid phase is substantially immiscible in or separated from a ligand-containing environment, and the compositions are utilized by contacting the immobilized carrier compounds with the ligand-containing environment. Desirably, the compositions may be maintained in an inactive state (i.e., unable to bind ligand) where the transition metal ion is separated from the chelate. By allowing the complex to form at a preselected time, premature ligand binding can be avoided.

摘要翻译： 根据本发明的物质组合物包含固定在固相中或固相上的载体化合物。 载体化合物与配体如分子氧反应，并且包括由过渡金属离子和多齿有机螯合物形成的络合物。 固相基本上与含配体的环境不混溶或分离，并且通过使固定的载体化合物与含配体的环境接触来使用该组合物。 理想地，组合物可以保持在非活性状态（即不能结合配体），其中过渡金属离子与螯合物分离。 通过允许复合物在预选的时间内形成，可以避免过早的配体结合。