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1.发明授权Optically active (meth)acrylamides, a process for their preparation, and their use for racemate resolution 失效光学活性（甲基）丙烯酰胺，其制备方法及其用于消旋物分解的用途
公开(公告)号：US4914159A
公开(公告)日：1990-04-03
申请号：US162529
申请日：1988-03-01
申请人： Bruno Bomer , Rolf Grosser , Ulrich Schwartz , Dieter Arlt , Karl-Erwin Piejko
发明人： Bruno Bomer , Rolf Grosser , Ulrich Schwartz , Dieter Arlt , Karl-Erwin Piejko
IPC分类号： B01J20/291 , B01J20/281 , B01J20/32 , C08F2/44 , C08F20/52 , C08F20/54 , C08F20/56 , C08L33/24 , C08L33/26 , G01N30/88
CPC分类号： B01J20/29 , B01J20/286 , B01J20/3204 , B01J20/3217 , B01J20/327 , B01J20/3276 , B01J20/3278 , C08F20/54 , B01J2220/54
摘要： The invention relates to optically active homo- and copolymers made from optically active (meth)acrylamides, the polymers being immobilized on silica gel, a process for their preparation, and their use as adsorbents, in particular as the stationary phase for chromatographic racemate resolution.
摘要翻译： 本发明涉及由光学活性（甲基）丙烯酰胺制成的光学活性均聚物和共聚物，该聚合物固定在硅胶上，其制备方法及其作为吸附剂的用途，特别是作为色谱外消旋体拆分的固定相。
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2.发明授权Optically active (meth)acrylamides, a process for their preparation, and their use for racemate resolution 失效光学活性（甲基）丙烯酰胺，其制备方法及其用于消旋物分解的用途
公开(公告)号：US4937000A
公开(公告)日：1990-06-26
申请号：US423324
申请日：1989-10-18
申请人： Bruno Bomer , Rolf Grosser , Ulrich Schwartz , Dieter Arlt , Karl-Erwin Piejko
发明人： Bruno Bomer , Rolf Grosser , Ulrich Schwartz , Dieter Arlt , Karl-Erwin Piejko
IPC分类号： B01J20/291 , B01J20/281 , B01J20/32 , C08F2/44 , C08F20/52 , C08F20/54 , C08F20/56 , C08L33/24 , C08L33/26 , G01N30/88
CPC分类号： B01J20/29 , B01J20/286 , B01J20/3204 , B01J20/3217 , B01J20/327 , B01J20/3276 , B01J20/3278 , C08F20/54 , B01J2220/54
摘要： The invention relates to optically active homo- and copolymers made from optically active (meth)acrylamides, the polymers being immobilized on silica gel, a process for their preparation, and their use as adsorbents, in particular as the stationary phase for chromatographic racemate resolution.
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3.发明授权Optical active (meth)acrylamides and polymers thereof for racemate resolution 失效光学活性（甲基）丙烯酰胺及其聚合物，用于消旋体拆分
公开(公告)号：US4931525A
公开(公告)日：1990-06-05
申请号：US274063
申请日：1988-11-21
申请人： Ulrich Schwartz , Rolf Grosser , Karl-Erwin Piejko , Bruno Bomer , Dieter Arlt
发明人： Ulrich Schwartz , Rolf Grosser , Karl-Erwin Piejko , Bruno Bomer , Dieter Arlt
IPC分类号： B01J20/291 , B01F17/52 , B01J20/281 , C07C67/00 , C07C231/00 , C07C231/02 , C07C233/09 , C08F2/18 , C08F20/00 , C08F20/10 , C08F20/20 , C08F20/52 , C08F20/54 , C08F20/56 , G01N30/88
CPC分类号： C08F20/54
摘要： In the chromatographic separation of a mixture of antipodes of optically active chemicals by passing a solution of such mixture over an optically active adsorbent to effect adsorption, and then eluting the adsorbed material, the improvement which comprises employing as the adsorbent particles of an optically active and cross-linked polymer containing the repeating structural unit ##STR1## in which R.sup.1 represents hydrogen or methyl, andR.sup.2 represents one of the stereoisomers of the eight possible stereoisomeric forms of each of the optically active radicals of the formulae ##STR2## Improved separation results. The pure monomers are also new.
摘要翻译： 在光学活性化学品的对映体的混合物的色谱分离中，将这种混合物的溶液通过光学活性吸附剂进行吸附，然后洗脱吸附的材料，其改进包括使用光学活性和 含有重复结构单元“IMAGE”的交联聚合物，其中R 1表示氢或甲基，R 2代表式的每个光学活性基团的八种可能的立体异构形式的立体异构体之一改进的分离结果。 纯单体也是新的。
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公开(公告)号：US4874473A
公开(公告)日：1989-10-17
申请号：US39550
申请日：1987-04-16
IPC分类号： C07B63/04 , B01D3/40 , C07B31/00 , C07B57/00 , C07C27/00 , C07C29/84 , C07C29/94 , C07C67/00 , C07C67/54 , C07C69/743 , C07C69/747
CPC分类号： C07C67/54 , C07B57/00 , C07C69/743
摘要： Diastereomers can be separated with good industrial success with the aid of extractive distillation. The separation process is characterized in that an auxiliary which changes the partial pressure of the various diastereomers to be separated to a different degree and thus allows easier separation of the diastereomers by distillation is added during the distillation. Using the present process diastereomic cis/trans-permetric acid methyl esters and mixtures of menthol and isomenthol can be separated with isolation of 99% pure product.
摘要翻译： 借助萃取蒸馏，非对映异构体可以在工业上获得良好的成功分离。 分离方法的特征在于，在蒸馏期间加入辅助剂，其将各种非对映异构体的分压改变为不同程度，从而允许通过蒸馏更容易地分离非对映异构体。 使用本发明方法，可以分离99％纯的产物，分离出非对映体顺式/反式多酯酸甲酯和薄荷醇和异戊醇的混合物。
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公开(公告)号：US4357278A
公开(公告)日：1982-11-02
申请号：US252841
申请日：1981-04-10
IPC分类号： C07C49/647 , A61K31/565 , C07C45/00 , C07C45/67 , C07C45/73 , C07C47/575 , C07C49/84 , C07C67/00 , C07F7/08 , C07J1/00
CPC分类号： C07J1/0059 , C07C45/00 , C07C45/67 , C07C45/676 , C07C45/73 , C07C47/575 , C07C49/84 , C07F7/0818
摘要： What are disclosed are a multi-step synthesis for the preparation of 9(11)-dehydroestrone 3-methyl ether from 2-methyl,4-methoxy benzaldehyde; 1-(4-methoxy-2-methyl-(phenyl)-3-(1-methyl-2-oxo-5-t-vinyl-cyclopent-r-yl)-propane-1-one, an intermediate in said synthesis; and a method for the preparation of 3-vinylcyclopentanone from 2-vinylcyclopropane-1,1-dicarboxylic acid.
摘要翻译： 所公开的是从2-甲基-4-甲氧基苯甲醛制备9（11） - 脱氢雌酮3-甲基醚的多步合成法; 1-（4-甲氧基-2-甲基 - （苯基）-3-（1-甲基-2-氧代-5-叔 - 乙烯基 - 环戊基 - 基） - 丙-1-酮，所述合成中的中间体 ;以及由2-乙烯基环丙烷-1,1-二羧酸制备3-乙烯基环戊酮的方法。
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