公开(公告)号：US3864076A

公开(公告)日：1975-02-04

申请号：US28517372

申请日：1972-08-31

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M15/673 ,  B27K3/15 ,  C07F9/54 ,  C08L61/32 ,  D06M15/431 ,  D06M15/667 ,  D06M1/00

CPC分类号： D06M15/667 ,  B27K3/15 ,  B27K2240/30 ,  C07F9/54 ,  C08L61/32 ,  D06M15/431 ,  Y10S428/921 ,  Y10T428/2938

摘要： The subject of the invention is a process for the manufacture of condensation products of hydroxymethylphosphonium compounds and guanidines, characterised in that (a) 1 mol of a tetrakis(hydroxymethyl)-phosphonium compound is condensed with (b) 0.02 to 0.5 mol, preferably 0.1 to 0.3 mol, of guanidine, guanidine salt, guanylurea, guanylurea salt or methylolated guanidine or guanylurea at 40* to 120*C, optionally in the presence of formaldehyde or a formaldehyde-donating agent and optionally in the presence of an inert organic solvent, optionally subsequently further condensed at temperatures of 100* to 150*C and, if appropriate, free hydroxyl groups are at least partially etherified with at least one alkanol with 1 to 4 carbon atoms and if appropriate the salts of the condensation products are converted into the corresponding hydroxides. The condensation products are used for flameproofing organic fibre material, especially textiles.

摘要翻译： 本发明的主题是制备羟甲基鏻化合物和胍的缩合产物的方法，其特征在于：（a）1摩尔四（羟甲基）鏻化合物与（b）0.02至0.5摩尔，优选 0.1至0.3mol的胍，胍盐，脒基脲，脒基脲盐或羟甲基化胍或脒基脲，任选在甲醛或甲醛给药剂存在下，任选在惰性有机溶剂存在下，于40℃至120℃ 任选地随后在100至150℃的温度下进一步冷凝，如果合适的话，游离羟基与至少一种具有1-4个碳原子的链烷醇至少部分醚化，如果合适，将缩合产物的盐转化为 相应的氢氧化物。

公开(公告)号：US3903336A

公开(公告)日：1975-09-02

申请号：US28515072

申请日：1972-08-31

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M15/673 ,  D06M15/415 ,  D06M15/431 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  D06M101/16 ,  D06M101/30 ,  D06M101/32 ,  C09D1/00 ,  C09D3/52 ,  C09D5/18

CPC分类号： D06M15/431 ,  D06M15/415

摘要： The subject of the invention is the use of watersoluble condensation products of (a) 1 mol of a tetrakis-(hydroxymethyl)-phosphonium compound and (b) 0.02 to 1 mol, preferably 0.2 to 1 mol or especially 0.3 to 0.6 mol, of methylolated urea or its alkyl-ethers, preferably dimethylolurea, as flameproofing agents for fibre mixtures of polyester and cellulose.

摘要翻译： 本发明的主题是使用（a）1摩尔四（羟基 - 甲基） - 鏻化合物和（b）0.02-1摩尔，优选0.2-1摩尔，特别是0.3-0.6摩尔的水溶性缩合产物 的羟甲基化脲或其烷基醚，优选二羟甲基脲，作为聚酯和纤维素纤维混合物的防火剂。

公开(公告)号：US3887553A

公开(公告)日：1975-06-03

申请号：US28538372

申请日：1972-08-31

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M15/673 ,  B27K3/15 ,  C07F9/6521 ,  C08L61/32 ,  D06M15/431 ,  D06M15/667 ,  C07D55/24

CPC分类号： D06M15/667 ,  B27K3/15 ,  B27K2240/30 ,  C07F9/65212 ,  C08L61/32 ,  D06M15/431 ,  Y10S428/921

摘要： The subject of the invention is a process for the manufacture of water-soluble condensation products of hydroxymethylphosphonium compounds and a 1,3,5-triazine characterised in that (a) 1 mol of a tetrakis-(hydroxymethyl)-phosphonium compound is condensed with (b) 0.02 to 0.1 mol, preferably 0.05 to 0.1 mol of optionally methylolated 1,3,5-triazine which is substituted by at least one primary amino group, at 40* to 120*C, optionally in the presence of formaldehyde or a formaldehyde-releasing agent and optionally in the presence of an inert organic solvent, the condensation is optionally thereafter continued at temperatures of 100* to 150*C and, if appropriate, free hydroxyl groups are etherified at least partially with at least one alkanol with 1 to 4 carbon atoms and, if appropriate, the salts of the condensation products are converted into the corresponding hydroxides. The condensation products are used for flameproofing organic fibre material, especially textiles.

摘要翻译： 本发明的主题是制备羟甲基鏻化合物和1,3,5-三嗪的水溶性缩合产物的方法，其特征在于：（a）将1摩尔四（羟甲基）鏻化合物与 （b）任选在甲醛或甲醛存在下，在40至120℃下，0.02至0.1摩尔，优选0.05至0.1摩尔任意羟基化的1,3,5-三嗪，其被至少一个伯氨基取代， 甲醛释放剂，任选地在惰性有机溶剂的存在下，任选地在100-150℃的温度下继续冷凝，如果合适的话，游离羟基至少部分用至少一种链烷醇醚化1 至4个碳原子，如果合适，则缩合产物的盐转化为相应的氢氧化物。

公开(公告)号：US3878245A

公开(公告)日：1975-04-15

申请号：US28529572

申请日：1972-08-31

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M15/673 ,  B27K3/15 ,  C07F9/54 ,  C08L61/32 ,  D06M15/431 ,  D06M15/432 ,  D06M15/667 ,  C07C127/00

CPC分类号： D06M15/667 ,  B27K3/15 ,  B27K2240/30 ,  C07F9/54 ,  C07F9/5407 ,  C08L61/32 ,  D06M15/431 ,  D06M15/432

摘要： The subject of the invention is a process for the manufacture of water-soluble condensation products of hydroxymethyl-phosphonium compounds, characterised in that (a) 1 mol of a tetrakis(hydroxymethyl)-phosphonium compound is condensed with (b) 0.02 to 0.2 mol, preferably 0.05 to 0.15 mol, of urea at 40* to 120*C and optionally in the presence of an inert organic solvent and if appropriate free hydroxyl groups are at least partially etherified with at least one alkanol with 1 to 4 carbon atoms and if appropriate the salts of the condensation products are converted into the corresponding hydroxides. The condensation products are used for flameproofing organic fibre material, especially textiles.

摘要翻译： 本发明的主题是制备羟甲基鏻化合物的水溶性缩合产物的方法，其特征在于：（a）1摩尔四（羟甲基）鏻化合物与（b）0.02至0.2 mol，优选0.05至0.15mol尿素，任选在惰性有机溶剂存在下，如果合适的游离羟基至少部分用至少一个具有1-4个碳原子的链烷醇醚化，并且 如果适当，缩合产物的盐转化成相应的氢氧化物。

公开(公告)号：US3700403A

公开(公告)日：1972-10-24

申请号：US3700403D

申请日：1971-01-12

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： C07F9/40 ,  D06M13/288 ,  D06M13/32 ,  D06M15/54

CPC分类号： D06M13/288 ,  C07F9/4006 ,  Y10S8/04 ,  Y10S8/21 ,  Y10S260/24

摘要： THE PRESENT INVENTION RELATES TO A PROCESS FOR RENDERING CELLULOSE-CONTAINING FIBROUS MATERIALS FLAMEPROOF, WHICH COMPRISES APPLYING TO SAID MATERIALS AN AQUEOUS PREPARATION CONTAINING PHOSPHORUS-CONTAINING N,N-DIMETHYLOLCARBOXYLIC ACID AMIDES. THE FLAMEPROOF FINISH IS RESISTANT TO WASHING AND DRY-CLEANING AND IMPROVES THE DRY CREASE ANGLE AND THE WET CREASE ANGLE OF THE FINISHED MATERIAL.

公开(公告)号：US3679778A

公开(公告)日：1972-07-25

申请号：US3679778D

申请日：1969-12-16

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M13/44 ,  C07F9/40 ,  D06M13/288 ,  D21H21/34 ,  D21H27/28 ,  C07F9/38 ,  D06C27/00

CPC分类号： D06M13/288 ,  C07F9/4006

摘要： Phosphorus compounds are provided which correspond to the formula

WHEREIN EACH R is an alkyl, alkenyl or halogenalkyl radical, X and X'' each is a methyl radical or a hydrogen atom, Y and Y'' each is an alkyl radical or a hydrogen atom and A is an alkyl, halogenalkyl, hydroxyalkyl or a phenyl or benzyl group which both may be halogen substituted. The phosphorus compounds are manufactured from the corresponding phosphorus carboxylic acid amides and carbamates and formaldehyde. These compounds optionally together with a curable aminoplast precondensate are useful for flameproofing and creaseproofing of cellulosecontaining fiber materials.

摘要翻译： 提供了对应于下式的磷化合物：其中R是烷基，烯基或卤代烷基，X和X'各自为甲基或氢原子，Y和Y'各自为烷基或氢原子，A 是烷基，卤代烷基，羟基烷基或苯基或苄基，它们都可以被卤素取代。 磷化合物由相应的磷羧酸酰胺和氨基甲酸酯和甲醛制成。 这些化合物任选地与可固化的氨基塑料预缩合物一起可用于含纤维素纤维材料的隔爆和抗皱。

公开(公告)号：US3907898A

公开(公告)日：1975-09-23

申请号：US39957673

申请日：1973-09-21

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  KERN JOERG ,  MAEDER ARTHUR

IPC分类号： B27K3/15 ,  B27K3/50 ,  C08G61/12 ,  C08G79/06 ,  D06M13/285 ,  D06M15/431 ,  D06M15/667 ,  D06M15/673 ,  C11D3/26 ,  C07F9/28

CPC分类号： D06M15/673 ,  B27K3/15 ,  B27K2240/30 ,  C08G79/06 ,  C08K5/21 ,  C08K5/49 ,  D06M13/285 ,  D06M15/431 ,  D06M15/667 ,  Y10T442/2672

摘要： The subject of the invention is a process for the manufacture of polycondensation products from hydroxymethylphosphonium compounds, characterised in that at least one anhydrous tetrakis(hydroxymethyl)-phosphonium salt or tetrakis(hydroxymethyl)phosphonium hydroxide is condensed with itself in an anhydrous medium, optionally using an acid catalyst and optionally in the presence of at least one inert organic solvent, at 100* to 150*C, preferably 120* to 150*C, the condensation being continued until 0.5 to 1.5 mols of water have been eliminated per 1 mol of phosphonium compound employed, free hydroxyl groups are, if appropriate, at least partially etherified with at least one alkanol with 1 to 4 carbon atoms, and that the salt of the polycondensation products are, where relevant, converted into the corresponding hydroxides. The polycondensation products are used for the flameproofing of organic fibre material, especially textiles. Appropriately, the procedure followed is that an aqueous preparation is applied to these materials which contains at least (1) a polycondensation product of the indicated type and (2) a polyfunctional compound, and that the material thus treated are dried and subjected to a heat treatment.

摘要翻译： 本发明的主题是由羟甲基鏻化合物制造缩聚产物的方法，其特征在于至少一种无水四（羟甲基）鏻盐或四（羟甲基） - 鏻氢氧化物与自身在无水介质中冷凝， 任选地使用酸催化剂和任选地在至少一种惰性有机溶剂的存在下，在100-150℃，优选120-150℃下，继续进行缩合，直至每1次消除0.5至1.5摩尔的水 使用的鏻化合物的摩尔数，如果合适，游离羟基与至少一种具有1至4个碳原子的链烷醇至少部分醚化，并且缩聚产物的盐在相关时转化为相应的氢氧化物。

公开(公告)号：US3901985A

公开(公告)日：1975-08-26

申请号：US28517472

申请日：1972-08-31

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： D06M15/673 ,  B27K3/15 ,  C07F9/54 ,  C08L61/32 ,  D06M15/431 ,  D06M15/667 ,  D06M101/12 ,  C09D1/00

CPC分类号： D06M15/667 ,  B27K3/15 ,  C07F9/54 ,  C08L61/32 ,  D06M15/431

摘要： The subject of the invention is a process for the manufacture of condensation products of hydroxymethyl-phosphonium compounds and a cyclic urea, characterized in that (a) 1 mol of a tetrakis(hydroxymethyl)-phosphonium compound is condensed at 40* to 120*C with (b) 0.02 to 0.5 mol, preferably 0.1 to 0.3 mol, of an optionally N-methylolated monocyclic or bicyclic urea, which has 5 to 6 members per ring, optionally in the presence of formaldehyde or a formaldehyde-releasing agent and optionally in the presence of an inert organic solvent, if appropriate, condensation is thereafter continued at 100* to 150*C and if appropriate free hydroxyl groups are at least partially etherified with at least one alkanol with 1 to 4 carbon atoms and if appropriate the salts of the polycondensation products are converted into the corresponding hydroxides. The condensation products are used for flameproofing organic fibre material, in particular textiles.

公开(公告)号：US3874911A

公开(公告)日：1975-04-01

申请号：US28517072

申请日：1972-08-31

申请人： CIBA GEIGY AG

发明人： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC分类号： B27K3/15 ,  C07F9/50 ,  C07F9/6521 ,  C08L61/32 ,  D06M15/431 ,  D06M15/555 ,  D06M15/667 ,  C09D1/00

CPC分类号： D06M15/667 ,  B27K3/15 ,  B27K2240/30 ,  C07F9/50 ,  C07F9/65212 ,  C08L61/32 ,  D06M15/431 ,  D06M15/555 ,  Y10S428/921 ,  Y10T428/2938 ,  Y10T428/2965 ,  Y10T428/2967 ,  Y10T428/31786

摘要： The subject of the invention is a process for the manufacture of water-soluble condensation products of hydroxymethyl-phosphonium compounds and amides or carbamates, characterised in that (a) one mol of a tetrakis-(hydroxymethyl)-phosphonium compound is condensed with (b) 0.02 to I mol, preferably 0.1 to 0.6 mol, of an optionally methylolated compound of the formula R-CONH2 (1) wherein R denotes alkoxy with 1 to 4 carbon atoms, hydroxyalkoxy with 2 to 4 carbon atoms, aminocarbonyl or a radical of the formula (H2N - CO - CH2CH2)2 - Z - CH2CH2 -(1.1) wherein Z represents

AT 40* TO 120*C, optionally in the presence of formaldehyde or a formaldehyde-donating agent and optionally in the presence of an inert organic solvent, optionally subsequently further condensed at temperatures of 100* to 150*C, and if appropriate free hydroxyl groups are at least partially etherified with at least one alkanol with 1 to 4 carbon atoms and if appropriate the salts of the condensation products are converted into the corresponding hydroxides. The condensation products are used for flameproofing organic fibre material, especially textiles.

摘要翻译： 本发明的主题是制备羟甲基鏻化合物和酰胺或氨基甲酸酯的水溶性缩合产物的方法，其特征在于（a）一摩尔四（羟甲基） - 鏻化合物与（b ）0.02至1mol，优选0.1至0.6mol的式R-CONH 2（1）的任选羟甲基化的化合物，其中R表示具有1至4个碳原子的烷氧基，具有2至4个碳原子的羟基烷氧基，氨基羰基或 式（H2N-CO-CH2CH2）2 -Z-CH2CH2 - （1。