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    CATALYST SUPPORT MATERIALS, CATALYSTS, METHODS OF MAKING THEM AND USES THEREOF
    1.
    发明申请
    CATALYST SUPPORT MATERIALS, CATALYSTS, METHODS OF MAKING THEM AND USES THEREOF 审中-公开
    催化剂支持材料，催化剂，制备方法及其用途

    公开(公告)号：US20150314268A1

    公开(公告)日：2015-11-05

    申请号：US14799673

    申请日：2015-07-15

    Applicant: CRISTAL USA INC.

    Inventor： Steve M. Augustine ,  David M. Chapman ,  Dennis F. Clark

    IPC: B01J23/28 ,  B01J37/00

    CPC classification number: B01J23/28 ,  B01D53/565 ,  B01D53/9418 ,  B01D2255/20707 ,  B01D2255/20769 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/22 ,  B01J27/051 ,  B01J27/19 ,  B01J27/199 ,  B01J35/1014 ,  B01J37/00 ,  B01J37/0201 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/68

    Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titanic slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3-SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

    Abstract translation: 描述了催化剂载体材料，催化剂，制备方法和用途。 制备催化剂载体材料的方法包括将锐钛矿钛浆料与i）低分子量二氧化硅组合; 和ii）Mo的源以形成TiO 2 -MoO 3 -SiO 2混合物。 催化剂载体材料包括约86％至约94％重量的锐钛矿型二氧化钛; 约0.1重量％至约10重量％的MoO 3; 和约0.1％至约10％重量的SiO 2。 二氧化硅的低分子量形式包括体积加权中值大小小于4nm，平均分子量小于44,000的二氧化硅的形式，单独地或两种或更多种的组合。 催化剂包括这样的催化剂载体材料，其具有约0.1至约3重量％的V 2 O 5和任选的约0.01重量％至约2.5重量％的P.

    SILICA-STABILIZED ULTRAFINE ANATASE TITANIA, VANADIA CATALYSTS, AND METHODS OF PRODUCTION THEREOF
    3.
    发明申请
    SILICA-STABILIZED ULTRAFINE ANATASE TITANIA, VANADIA CATALYSTS, AND METHODS OF PRODUCTION THEREOF 审中-公开
    二氧化硅稳定超细钛铁矿，VANADIA催化剂及其生产方法

    公开(公告)号：US20130331259A1

    公开(公告)日：2013-12-12

    申请号：US13967601

    申请日：2013-08-15

    Applicant: CRISTAL USA INC.

    Inventor： David M. Chapman

    IPC: B01J23/30

    CPC classification number: B01J21/08 ,  B01D53/9418 ,  B01D53/9477 ,  B01D2251/2067 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20776 ,  B01D2255/30 ,  B01D2258/012 ,  B01J21/063 ,  B01J23/22 ,  B01J23/30 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0209 ,  B01J37/035 ,  B01J37/04 ,  B01J37/08

    Abstract: The invention is directed to compositions and processes for the production of silica-stabilized ultrafine anatase titanias and which may further comprise tungsten and vanadia. The surface stabilization may be by treatment of the TiO2 particles with a low molecular weight and/or small nanoparticle form of silica such as, in preferred embodiments, a tetra(alkyl)ammonium silicate or silicic acid, which serves to efficiently maintain the anatase phase and prevent crystal growth under severe thermal and hydrothermal conditions, even in the presence of vanadia. The vanadia catalysts produced from the novel titanias have equal or improved catalytic activity for selective catalytic reduction of NOx compared to conventional vanadia supported silica-titania based catalysts. The invention is further directed to diesel emission catalytic devices comprising the novel titania-based catalyst compositions.

    Abstract translation: 本发明涉及用于生产二氧化硅稳定的超细锐钛矿钛的组合物和方法，并且其还可以包含钨和钒。 表面稳定化可以通过用低分子量和/或二氧化硅的小纳米颗粒形式的TiO 2颗粒进行处理，例如在优选的实施方案中为四（烷基）硅酸铵或硅酸，其用于有效地保持锐钛矿相 并且在严重的热和水热条件下，即使在存在氧化钒的情况下也能防止晶体生长。 与常规的支持二氧化钛 - 二氧化钛的催化剂相比，从新型钛合金制备的氧钒催化剂与NOx的选择性催化还原具有相同或改善的催化活性。 本发明还涉及包含新型二氧化钛基催化剂组合物的柴油发射催化装置。

    CATALYST SUPPORT MATERIALS, CATALYSTS, METHODS OF MAKING THEM AND USES THEREOF
    6.
    发明申请
    CATALYST SUPPORT MATERIALS, CATALYSTS, METHODS OF MAKING THEM AND USES THEREOF 有权
    催化剂支持材料，催化剂，制备方法及其用途

    公开(公告)号：US20150038324A1

    公开(公告)日：2015-02-05

    申请号：US14518257

    申请日：2014-10-20

    Applicant: CRISTAL USA INC.

    Inventor： Steve M. Augustine ,  David M. Chapman ,  Dennis F. Clark

    IPC: B01J23/28 ,  B01J23/22

    CPC classification number: B01J23/28 ,  B01D53/565 ,  B01D53/9418 ,  B01D2255/20707 ,  B01D2255/20769 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/22 ,  B01J27/051 ,  B01J27/19 ,  B01J27/199 ,  B01J35/1014 ,  B01J37/00 ,  B01J37/0201 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/68

    Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titania slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3—SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

    Abstract translation: 描述了催化剂载体材料，催化剂，制备方法和用途。 制备催化剂载体材料的方法包括将锐钛型二氧化钛浆料与i）低分子量形式的二氧化硅组合; 和ii）Mo的源以形成TiO 2 -MoO 3 -SiO 2混合物。 催化剂载体材料包括约86％至约94％重量的锐钛矿型二氧化钛; 约0.1重量％至约10重量％的MoO 3; 和约0.1％至约10％重量的SiO 2。 二氧化硅的低分子量形式包括体积加权中值大小小于4nm，平均分子量小于44,000的二氧化硅的形式，单独地或两种或更多种的组合。 催化剂包括这样的催化剂载体材料，其具有约0.1至约3重量％的V 2 O 5和任选的约0.01重量％至约2.5重量％的P.

    CATALYST SUPPORT MATERIALS, CATALYSTS, METHODS OF MAKING THEM AND USES THEREOF
    9.
    发明申请
    CATALYST SUPPORT MATERIALS, CATALYSTS, METHODS OF MAKING THEM AND USES THEREOF 有权
    催化剂支持材料，催化剂，制备方法及其用途

    公开(公告)号：US20140056793A1

    公开(公告)日：2014-02-27

    申请号：US13975073

    申请日：2013-08-23

    Applicant: CRISTAL USA INC.

    Inventor： Steve M. Augustine ,  David M. Chapman ,  Dennis F. Clark

    IPC: B01J27/199 ,  B01D53/56 ,  B01J23/28

    CPC classification number: B01J23/28 ,  B01D53/565 ,  B01D53/9418 ,  B01D2255/20707 ,  B01D2255/20769 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/22 ,  B01J27/051 ,  B01J27/19 ,  B01J27/199 ,  B01J35/1014 ,  B01J37/00 ,  B01J37/0201 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/68

    Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titania slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3—SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

    Abstract translation: 描述了催化剂载体材料，催化剂，制备方法和用途。 制备催化剂载体材料的方法包括将锐钛型二氧化钛浆料与i）低分子量形式的二氧化硅组合; 和ii）Mo的源以形成TiO 2 -MoO 3 -SiO 2混合物。 催化剂载体材料包括约86％至约94％重量的锐钛矿型二氧化钛; 约0.1重量％至约10重量％的MoO 3; 和约0.1％至约10％重量的SiO 2。 二氧化硅的低分子量形式包括体积加权中值大小小于4nm，平均分子量小于44,000的二氧化硅的形式，单独地或两种或更多种的组合。 催化剂包括这样的催化剂载体材料，其具有约0.1至约3重量％的V 2 O 5和任选的约0.01重量％至约2.5重量％的P.

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