Abstract:
The invention is directed to high surface area graphitized carbon and to processes for making high surface area graphitized carbon. The process includes steps of graphitizing and increasing the surface area of (in either order) a starting carbon material to form high surface area graphitized carbon. The step of increasing the surface area optionally comprises an oxidizing step (e.g., through steam etching) or template removal from composite particles. The invention is also directed to catalyst particles and electrodes employing catalyst particles that are formed from the high surface area graphitized carbon.
Abstract:
Disclosed herein are compositions comprising: a carbon additive prewetted with an acid (e.g., H2SO4); and a lead-containing material. Also disclosed are methods of making such compositions, and pastes and electrodes made therefrom.
Abstract translation:本文公开了包含:用酸(例如H 2 SO 4)预润湿的碳添加剂的组合物; 和含铅材料。 还公开了制备这种组合物的方法,以及由其制成的糊剂和电极。
Abstract:
A paste suitable for a negative plate of a lead-acid battery, the paste comprising lead oxide and carbon black, wherein the carbon black has the following properties: (a) a BET surface area between about 100 and about 2100 m2/g; and (b) an oil adsorption number (OAN) in the range of about 35 to about 360 cc/100 g, provided that the oil absorption number is less than the 0.14×the BET surface area+65.
Abstract:
A carbon-based additive for negative active materials includes carbon nanostructures free of a fiber substrate, carbon nanostructures fused to a fiber substrate or any combination thereof. In many cases, the carbon-based additive further includes carbon black. The additive is used to prepare electrode compositions for lead acid batteries. Batteries that include such electrode compositions are characterized by improved dynamic charge acceptance and lead utilization, typically at acceptable water loss levels. Some of the batteries described herein exhibit a negligible memory effect.
Abstract:
A composition suitable for a negative plate of lead-acid battery includes (a) a lead-based active material; (b) at least one material selected from the group consisting of a lignosulfonate and barium sulfate; and (c1) carbon black particles having a Brunauer-Emmett-Teller (BET) surface area greater than or equal to 90 m2/g and less than or equal to 900 m2/g, and an oil adsorption number (OAN) greater than or equal to 150 mL/100 g and less than or equal to 300 mL/100 g, or (c2) carbon black particles having a BET surface area greater than or equal to 40 m2/g and less than or equal to 500 m2/g, and graphenes particles. The composition has a theoretical negative active mass (NAM) BET surface area greater than or equal to 0.75 m2/g and less than or equal to 2 m2/g. The compositions can be used in electrodes, e.g., those used in lead-acid batteries.
Abstract:
Disclosed herein are compositions, which can be used to coat electrode plates, comprising at least one carbonaceous material and at least one additive, wherein the at least one additive comprises a metal ion selected from calcium, barium, potassium, magnesium, and strontium ion, and wherein the metal ion is present in an amount ranging from 0.5 wt. % to 3 wt. % relative to the total weight of carbonaceous material. Also disclosed are electrodes and lead acid batteries comprising such compositions, and methods of making the compositions.
Abstract:
A composition, includes: carbon black particles having a surface energy less than 5 mJ/m2; graphite particles having a BET surface area greater than 5 m2/g and more than about 50 graphitic layers, wherein the ratio of the carbon black particles to the graphite particles ranges from 0.25:1 to 4:1 by weight; and a liquid medium.
Abstract:
Disclosed herein are compositions, which can be used to coat electrode plates, comprising at least one carbonaceous material and at least one additive, wherein the at least one additive comprises a metal ion selected from calcium, barium, potassium, magnesium, and strontium ion, and wherein the metal ion is present in an amount ranging from 0.5 wt. % to 3 wt. % relative to the total weight of carbonaceous material. Also disclosed are electrodes and lead acid batteries comprising such compositions, and methods of making the compositions.
Abstract:
Disclosed herein are electrode compositions comprising a homogeneous mixture comprising: a lead-containing material and a carbon additive comprising carbon black and activated carbon. A total amount of the carbon additive ranges from 0.1% to 2% by weight, relative to the total weight of the composition. The composition can have a ratio of carbon black to activated carbon ranging from 0.1:0.9 to 0.5:0.5. The activated carbon can have a d50 particle size distribution ranging from 4 μm to 100 μm, and a pore volume of at least 0.7 cm3/g. Also disclosed are electrodes formed from the electrode composition, cells (e.g., lead-acid battery) comprising the electrodes/electrode compositions, and methods of making thereof.
Abstract:
The invention is directed to high surface area graphitized carbon and to processes for making high surface area graphitized carbon. The process includes steps of graphitizing and increasing the surface area of (in either order) a starting carbon material to form high surface area graphitized carbon. The step of increasing the surface area optionally comprises an oxidizing step (e.g., through steam etching) or template removal from composite particles. The invention is also directed to catalyst particles and electrodes employing catalyst particles that are formed from the high surface area graphitized carbon.