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公开(公告)号：US4387246A
公开(公告)日：1983-06-07
申请号：US328067
申请日：1981-12-07
IPC分类号： C07B61/00 , A01N33/06 , B01J25/02 , B01J27/00 , B01J27/10 , B01J29/00 , C07C20060101 , C07C67/00 , C07C209/00 , C07C209/36 , C07C211/52 , C07C87/48
CPC分类号： B01J25/02 , B01J23/18 , B01J23/745 , B01J27/10 , B01J27/128 , C07C17/12 , C07C201/08 , C07C209/36 , C07C67/00 , A01N33/06
摘要： A process for preparing orthotrifluoromethyl aniline from trifluoromethyl benzene is disclosed. The steps are (a) reacting the trifluoromethyl benzene with gaseous chlorine in the presence of a chlorination catalyst until at least 90% of the trifluoromethyl benzene is consumed; (b) nitrating the crude mixture from step (a) using a mixture of sulfuric acid and nitric acid until disappearance of the chlorotrifluoromethyl benzenes; (c) settling and washing the organic phase from step (b); (d) subjecting the organic phase from step (c) to a first hydrogenation under pressure in the presence of a hydrogenation catalyst consisting of Raney nickel and/or Raney nickel doped with chromium, in an organic-solvent medium until complete disappearance of the chloronitrotrifluoromethyl benzenes; (e) subjecting the mixture from step (d) to a second hydrogenation in the presence of an additional amount of Raney nickel and in the presence of at least one alkaline base; and (f) removing the orthotrifluoromethyl aniline by distillation from the reaction mixture.
摘要翻译： 公开了一种由三氟甲苯制备邻三氟甲基苯胺的方法。 步骤是（a）在氯化催化剂的存在下使三氟甲基苯与气态氯反应，直到三氟甲基苯的至少90％被消耗; （b）使用硫酸和硝酸的混合物硝化来自步骤（a）的粗混合物，直至氯三氟甲苯苯消失; （c）沉淀并洗涤步骤（b）的有机相; （d）在有机溶剂介质中，在有机溶剂介质中，在由含有铬的阮内镍和/或阮内镍组成的氢化催化剂的存在下，在压力下使步骤（c）的有机相进行第一次氢化，直到氯三氟甲基甲基 苯; （e）使来自步骤（d）的混合物在额外量的阮内镍存在下并在至少一种碱性碱的存在下进行第二次氢化; 和（f）通过蒸馏从反应混合物中除去邻三氟甲基苯胺。
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2.发明授权Acid extracted-alkalized/carbon catalyst support with coordination complex catalyst and method of manufacture 失效酸提取碱化/碳催化剂载体与配位络合催化剂及制备方法
公开(公告)号：US3974227A
公开(公告)日：1976-08-10
申请号：US560144
申请日：1975-03-20
CPC分类号： C07C45/50 , B01J21/18 , B01J31/1616 , B01J31/185 , B01J31/20 , B01J2231/321 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , Y02P20/588
摘要： A catalyst for hydrogenation, hydroformylation, olefin oxidation and similar reactions is prepared by treating activated carbon first with a volatile acid and then with a basic substance to provide a suitable support for the catalyst, and then adsorbing onto such support a coordination complex of a transition metal. The adsorption of the catalyst onto the support may be effected in situ during the hydrogenation, hydroformylation, oxidation, etc. reaction.
摘要翻译： 通过首先用挥发性酸然后用碱性物质处理活性炭以提供合适的催化剂载体，然后将这种载体上的配位络合物吸附到载体上来制备用于氢化，加氢甲酰化，烯烃氧化和类似反应的催化剂 金属。 催化剂在载体上的吸附可以在氢化，加氢甲酰化，氧化等反应期间原位进行。
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公开(公告)号：US4096150A
公开(公告)日：1978-06-20
申请号：US420976
申请日：1973-12-03
IPC分类号： C07C209/26 , B01J31/16 , B01J31/18 , B01J31/20 , C07C67/00 , C07C209/00 , C07C209/60 , C07C211/03 , C07D211/02
CPC分类号： C07C209/60 , B01J31/185 , B01J31/20 , B01J2531/822
摘要： Substituted amines are prepared with high selectivity by reacting olefin, hydrogen, CO and secondary amine in the presence of a coordination complex catalyst of a Group VIII metal and a ligand, the donor atom of which is oxygen, nitrogen or sulfur.
摘要翻译： 在第VIII族金属和配体的配位络合物催化剂（其供体原子是氧，氮或硫）的存在下，通过使烯烃，氢，CO和仲胺反应，通过高选择性制备取代的胺。
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公开(公告)号：US4107079A
公开(公告)日：1978-08-15
申请号：US762474
申请日：1977-01-26
IPC分类号： B01J31/18 , B01J31/20 , B01J31/24 , B01J37/22 , B01J37/24 , B01J23/42 , B01J23/44 , B01J23/46 , B01J27/10
CPC分类号： B01J37/24 , B01J31/1805 , B01J31/181 , B01J31/1855 , B01J31/20 , B01J31/2404 , B01J37/22 , B01J2231/321 , B01J2231/641 , B01J2531/80 , B01J2531/822 , C07C2531/22
摘要： Solid catalyst, insoluble in organic and aqueous solvents and having the general formula:A -- M (L').sub.n (L").sub.qin which A is an insoluble ligand, M is a Group VIII noble metal, L' and L" are ligands and n and q are intergers of 0 to 6 are provided for the advantageous catalysis of hydroformylation, and hydrogenation of olefins and the preparation of tertiary amines from olefins.
摘要翻译： 固体催化剂，不溶于有机和含水溶剂，具有以下通式：
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