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公开(公告)号:US08434857B2
公开(公告)日:2013-05-07
申请号:US12872018
申请日:2010-08-31
IPC分类号: B41J2/02
CPC分类号: C09D11/326 , C09D11/102 , C09D11/322
摘要: A printing system for applying a printing fluid to a substrate, comprising a printing fluid applicator and a recirculating printing fluid supply supplying printing fluid to the applicator, wherein the printing fluid comprising water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; X1—Y1—X1 represents one or more soft segments wherein Y1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X2—Y2—X2 represents one or more hard segments wherein Y2 represents the central portion of a unit that is the polymerization product of a C2-C8 diol or diamine having a molecular weight of less than 250 Daltons; and X1, V and X2 can be the same or different and are an —O— or —N— atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X2—Y2—X2 hard segments are present at from 1 wt % to less than 13 wt % of the polyurethane additive.
摘要翻译: 一种印刷系统,用于将印刷液体施加到基材上,包括印刷液体涂抹器和将印刷液体供应给涂布器的再循环印刷液体供应装置,其中包含水的印刷液和(I)通式的水分散性聚氨酯添加剂, 其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; X1-Y1-X1表示一个或多个软链段,其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段,其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1,V和X2可以相同或不同,为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值,并且所述一个或多个X2-Y2-X2硬链段存在于1 wt%至小于13wt%的聚氨酯添加剂。
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公开(公告)号:US20120050415A1
公开(公告)日:2012-03-01
申请号:US12872018
申请日:2010-08-31
IPC分类号: B41J2/02
CPC分类号: C09D11/326 , C09D11/102 , C09D11/322
摘要: A printing system for applying a printing fluid to a substrate, comprising a printing fluid applicator and a recirculating printing fluid supply supplying printing fluid to the applicator, wherein the printing fluid comprising water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; X1—Y1—X1 represents one or more soft segments wherein Y1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X2—Y2—X2 represents one or more hard segments wherein Y2 represents the central portion of a unit that is the polymerization product of a C2-C8 diol or diamine having a molecular weight of less than 250 Daltons; and X1, V and X2 can be the same or different and are an —O— or —N— atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X2—Y2—X2 hard segments are present at from 1 wt % to less than 13 wt % of the polyurethane additive.
摘要翻译: 一种印刷系统,用于将印刷液体施加到基材上,包括印刷液体涂抹器和将印刷液体供应给涂布器的再循环印刷液体供应装置,其中包含水的印刷液和(I)通式的水分散性聚氨酯添加剂, 其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; X1-Y1-X1表示一个或多个软链段,其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段,其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1,V和X2可以相同或不同,为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值,并且所述一个或多个X2-Y2-X2硬链段存在于1 wt%至小于13wt%的聚氨酯添加剂。
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公开(公告)号:US08430492B2
公开(公告)日:2013-04-30
申请号:US12871982
申请日:2010-08-31
IPC分类号: G01D11/00
CPC分类号: C09D11/322 , C09D11/102 , C09D11/326
摘要: An inkjet printing fluid composition including water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; X1—Y1—X1 represents one or more soft segments wherein Y1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X2—Y2—X2 represents one or more hard segments wherein Y2 represents the central portion of a unit that is the polymerization product of a C2-C8 diol or diamine having a molecular weight of less than 250 Daltons; and X1, V and X2 can be the same or different and are an —O— or —N— atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X2—Y2—X2 hard segments are present at from 1 wt % to less than 13 wt % of the polyurethane additive. Also disclosed is a method for printing an inkjet image including I) providing an inkjet printing fluid according to the invention; and II) jetting the inkjet printing fluid in the form of ink drops onto a recording element to form a printed image.
摘要翻译: 一种喷墨印刷液组合物,其包含水和通式(I)的水分散性聚氨酯添加剂,其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; X1-Y1-X1表示一个或多个软链段,其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段,其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1,V和X2可以相同或不同,为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值,并且所述一个或多个X2-Y2-X2硬链段存在于1 wt%至小于13wt%的聚氨酯添加剂。 还公开了一种用于印刷喷墨图像的方法,包括:I)提供根据本发明的喷墨印刷液; 和II)将墨滴形式的喷墨打印流体喷射到记录元件上以形成打印图像。
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公开(公告)号:US20120050380A1
公开(公告)日:2012-03-01
申请号:US12871982
申请日:2010-08-31
CPC分类号: C09D11/322 , C09D11/102 , C09D11/326
摘要: An inkjet printing fluid composition including water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; X1—Y1—X1 represents one or more soft segments wherein Y1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X2—Y2—X2 represents one or more hard segments wherein Y2 represents the central portion of a unit that is the polymerization product of a C2-C8 diol or diamine having a molecular weight of less than 250 Daltons; and X1, V and X2 can be the same or different and are an —O— or —N— atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X2—Y2—X2 hard segments are present at from 1 wt % to less than 13 wt % of the polyurethane additive. Also disclosed is a method for printing an inkjet image including I) providing an inkjet printing fluid according to the invention; and II) jetting the inkjet printing fluid in the form of ink drops onto a recording element to form a printed image.
摘要翻译: 一种喷墨印刷液组合物,其包含水和通式(I)的水分散性聚氨酯添加剂,其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; X1-Y1-X1表示一个或多个软链段,其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段,其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1,V和X2可以相同或不同,为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值,并且所述一个或多个X2-Y2-X2硬链段存在于1 wt%至小于13wt%的聚氨酯添加剂。 还公开了一种用于印刷喷墨图像的方法,包括:I)提供根据本发明的喷墨印刷液; 和II)将墨滴形式的喷墨打印流体喷射到记录元件上以形成打印图像。
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5.
公开(公告)号:US07022392B2
公开(公告)日:2006-04-04
申请号:US10700873
申请日:2003-11-04
申请人: Joseph P. Dinnocenzo , Douglas R. Robello , Samir Y. Farid , Mark R. Mis , Lorraine Ferrar , Aaron S. Peer , Thomas G. Brown
发明人: Joseph P. Dinnocenzo , Douglas R. Robello , Samir Y. Farid , Mark R. Mis , Lorraine Ferrar , Aaron S. Peer , Thomas G. Brown
IPC分类号: B32B3/02
CPC分类号: G11B7/0065 , B82Y10/00 , G11B7/24044 , G11B7/245 , Y10T428/21
摘要: An optically recorded article comprising a pattern of isomerized material in two isomeric forms in a matrix, wherein one of the isomeric forms is capable of being converted to the other form by one-electron oxidation and wherein said matrix was polymerized in-situ.
摘要翻译: 一种光学记录的制品,其包含在基质中具有两种异构体形式的异构化材料的图案,其中异构体形式之一能够通过单电子氧化转化为其它形式,并且其中所述基质原位聚合。
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公开(公告)号:US20140148330A1
公开(公告)日:2014-05-29
申请号:US13686941
申请日:2012-11-28
申请人: Douglas R. Robello , Mridula Nair , Mark R. Mis , Matthew Dirmyer
发明人: Douglas R. Robello , Mridula Nair , Mark R. Mis , Matthew Dirmyer
IPC分类号: B01J31/06 , C07C67/303 , C07C29/17
CPC分类号: B01J31/06 , B01J23/42 , B01J23/44 , B01J23/70 , B01J23/755 , B01J35/0013 , B01J35/023 , B01J37/0203 , B01J37/0211 , B01J37/0213 , B01J2231/645 , C07C29/17 , C07C29/172 , C07C67/303 , C07C33/035 , C07C31/207 , C07C69/28
摘要: Semi-permeable particle can be used to facilitate chemical reactions. The semi-permeable particles are permeable to molecules having a molar mass of 1000 Daltons or less, have a mode particle size of at least 1 μm, and comprise nanoparticles of catalytically active metallic materials disposed within at least some of multiple discrete cavities in the continuous polymeric phase. The nanoparticles of catalytically active metallic materials (a) comprise one or more elements selected from Groups 8, 9, 10, and 11 of the Periodic Table, and (b) have an effective diameter of at least 1 nm and up to and including 200 nm.
摘要翻译: 半渗透颗粒可用于促进化学反应。 半透性颗粒对摩尔质量为1000道尔顿或更低的分子是可渗透的,具有至少1μm的模式粒度,并且包含催化活性金属材料的纳米颗粒,其设置在连续的多个离散空腔的至少一些中 聚合物相。 催化活性金属材料的纳米颗粒(a)包含选自元素周期表第8,9,10和11族的一种或多种元素,和(b)具有至少1nm的有效直径和至多并包括200 nm。
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公开(公告)号:US09109221B2
公开(公告)日:2015-08-18
申请号:US13686946
申请日:2012-11-28
申请人: Mark R. Mis , Mridula Nair , Douglas R. Robello
发明人: Mark R. Mis , Mridula Nair , Douglas R. Robello
摘要: Semi-permeable particle can be used to facilitate chemical reactions such as catalytic reactions. The semi-permeable particles are permeable to molecules having a molar mass of 1000 Daltons or less and have a mode particle size of at least 1 μm. The semi-permeable particles have multiple discrete cavities containing an aqueous solution or suspension of an organic catalytic material. The semi-permeable particles are also impermeable to the organic catalytic materials so they are retained within the multiple discrete cavities, and the semi-permeable particles can be reused multiple times for the same or different chemical reaction.
摘要翻译: 半渗透颗粒可用于促进化学反应,如催化反应。 半透性颗粒对摩尔质量为1000道尔顿或更低的分子是可渗透的,并且模式粒径至少为1μm。 半渗透颗粒具有多个离散腔,其含有有机催化材料的水溶液或悬浮液。 半渗透颗粒对于有机催化材料也是不可渗透的,因此它们被保留在多个分立的空腔内,并且半渗透颗粒可以多次重复用于相同或不同的化学反应。
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公开(公告)号:US20140147885A1
公开(公告)日:2014-05-29
申请号:US13686946
申请日:2012-11-28
申请人: Mark R. Mis , Mridula Nair , Douglas R. Robello
发明人: Mark R. Mis , Mridula Nair , Douglas R. Robello
IPC分类号: C12N11/04
摘要: Semi-permeable particle can be used to facilitate chemical reactions such as catalytic reactions. The semi-permeable particles are permeable to molecules having a molar mass of 1000 Daltons or less and have a mode particle size of at least 1 μm. The semi-permeable particles have multiple discrete cavities containing an aqueous solution or suspension of an organic catalytic material. The semi-permeable particles are also impermeable to the organic catalytic materials so they are retained within the multiple discrete cavities, and the semi-permeable particles can be reused multiple times for the same or different chemical reaction.
摘要翻译: 半渗透颗粒可用于促进化学反应,如催化反应。 半透性颗粒对摩尔质量为1000道尔顿或更低的分子是可渗透的,并且模式粒径至少为1μm。 半渗透颗粒具有多个离散腔,其含有有机催化材料的水溶液或悬浮液。 半渗透颗粒对于有机催化材料也是不可渗透的,因此它们被保留在多个分立的空腔内,并且半渗透颗粒可以多次重复用于相同或不同的化学反应。
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公开(公告)号:US08692238B2
公开(公告)日:2014-04-08
申请号:US13455398
申请日:2012-04-25
IPC分类号: H01L35/24
CPC分类号: H01L51/052 , H01L51/0541 , H01L51/0545
摘要: An organic film-forming polymer has a Tg of at least 70° C. and comprises a backbone comprising recurring units of Structure (A) shown in this application. These organic film-forming polymers can be used as dielectric materials in various devices with improved properties such as improved mobility.
摘要翻译: 有机成膜聚合物的Tg至少为70℃,并且包含一种骨架,其包含本申请中所示的结构(A)的重复单元。 这些有机成膜聚合物可以用作各种具有改进性能的改进性能的器件中的介电材料。
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公开(公告)号:US07989536B2
公开(公告)日:2011-08-02
申请号:US12240073
申请日:2008-09-29
IPC分类号: C08L25/06
摘要: A polymeric nanocomposite comprises a non-polar hyperbranched polystyrene resin. An exfoliated or intercalated onium functionalized clay is dispersed within the resin. Such nanocomposites are more compatible with non-polar polymer matrices used in various articles of manufacture.
摘要翻译: 聚合物纳米复合材料包括非极性超支化聚苯乙烯树脂。 剥离或嵌入的鎓官能化粘土分散在树脂内。 这种纳米复合材料与用于各种制品的非极性聚合物基质更相容。
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