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1.发明授权Silicone composition crosslinkable into elastomer by hydrosilylation, in the presence of carbene-based metal catalysts, and catalysts 有权通过氢化硅烷化，在卡宾系金属催化剂和催化剂的存在下可交联成弹性体的硅氧烷组合物公开(公告)号：US07202320B2
公开(公告)日：2007-04-10
申请号：US10479720
申请日：2002-06-03
IPC分类号： C08G77/08
CPC分类号： C07F15/0086 , C08G77/045 , C08G77/12 , C08G77/14 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/70 , C08L83/04 , C08L83/00 , C08L2666/52
摘要： The invention concerns a silicone composition crosslinkable into elastomer by hydrosilylation, in the presence of carbene-based metal catalysts. The invention aims at providing a composition of that type, stable over long periods at room temperature (one day to several months), without loss of its characteristic of being heat-curable by hydrosilylation and without generating secondary isomerization or coloring reactions. The invention is characterised in that the composition comprises: a polyorganovinylsiloxane(polydimethyl)(methylvinyl) siloxane; a polyorganohydrogenosiloxane; a platinum catalyst formed by a complex of formula C3 and optionally an acetylene crosslinking inhibitor, optionally a siliceous filler. The invention also concerns novel hydrosilylation catalysts of the metal complex type of formula C3 above. The life span of the potted single-constituent compositions of the invention is significantly increased
摘要翻译： 本发明涉及在卡宾型金属催化剂存在下通过氢化硅烷化可交联成弹性体的有机硅组合物。 本发明的目的在于提供一种在室温下（一天至几个月）长期稳定的那种类型的组合物，而不会失去其通过氢化硅烷化可热固化的特性，而不产生二次异构化或着色反应。 本发明的特征在于该组合物包括：聚有机基乙烯基硅氧烷（聚二甲基）（甲基乙烯基）硅氧烷; 聚有机基氢硅氧烷; 由式C3的络合物和任选的乙炔交联抑制剂，任选的硅质填料形成的铂催化剂。 本发明还涉及上述式C3金属络合物的新型氢化硅烷化催化剂。 本发明的盆栽单组分组合物的寿命显着增加
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2.发明申请Adhesive Silicon Elastomer Single-Component Composition Crosslinkable by Polyaddition 失效通过加聚可交联的粘合硅弹性体单组分组合物公开(公告)号：US20090111931A1
公开(公告)日：2009-04-30
申请号：US11793497
申请日：2005-12-09
IPC分类号： C08L83/04 , C09D183/04 , C09J183/04
CPC分类号： C08L83/04 , C08G77/12 , C08G77/14 , C08G77/20 , C08G77/80 , C08L83/00 , C08L2666/28 , C09J183/04 , C08L2666/04 , C08L2666/44
摘要： Single-component silicone elastomer compositions (SEA) are crosslinkable by polyaddition into self-adhesive state, contain at least one polyorganosiloxane (POS) including sites of ethylenic and/or acetylenic unsaturation {POS containing units ═Si— [unsaturation]}; at least one polyorganosiloxane (POS) containing units ═Si—H; a catalytic system including at least one metal catalyst and at least one crosslinking inhibitor; a filler; at least one adhesion promoter; optionally, at least one POS resin; optionally, at least one thermal resistance agent; and, optionally, at least one other functional additive, and are useful for gluing, assembling, sealing, e.g., joints, coatings, electrical, electronic and automobile engineering parts.
摘要翻译： 单组分硅氧烷弹性体组合物（SEA）可以通过加聚成自粘合状态而交联，含有至少一种包含烯属和/或炔属不饱和位点（POS含有单元-Si- [不饱和键]}的聚有机硅氧烷（POS））; 至少一种含有单元-Si-H的聚有机硅氧烷（POS）; 包括至少一种金属催化剂和至少一种交联抑制剂的催化体系; 填料; 至少一种粘合促进剂; 任选地，至少一种POS树脂; 任选的至少一种耐热剂; 和任选的至少一种其它功能性添加剂，并且可用于胶合，组装，密封，例如接头，涂料，电气，电子和汽车工程部件。
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3.发明授权Single-component silicone elastomer compositions crosslinkable into self-adhesive state 失效单组分有机硅弹性体组合物可交联成自粘状态公开(公告)号：US08557942B2
公开(公告)日：2013-10-15
申请号：US11793497
申请日：2005-12-09
IPC分类号： C08G77/08
CPC分类号： C08L83/04 , C08G77/12 , C08G77/14 , C08G77/20 , C08G77/80 , C08L83/00 , C08L2666/28 , C09J183/04 , C08L2666/04 , C08L2666/44
摘要： Single-component silicone elastomer compositions (SEA) are crosslinkable by polyaddition into self-adhesive state, contain at least one polyorganosiloxane (POS) including sites of ethylenic and/or acetylenic unsaturation {POS containing units ═Si— [unsaturation]}; at least one polyorganosiloxane (POS) containing units ═Si—H; a catalytic system including at least one metal catalyst and at least one crosslinking inhibitor; a filler; at least one adhesion promoter; optionally, at least one POS resin; optionally, at least one thermal resistance agent; and, optionally, at least one other functional additive, and are useful for gluing, assembling, sealing, e.g., joints, coatings, electrical, electronic and automobile engineering parts.
摘要翻译： 单组分硅氧烷弹性体组合物（SEA）可以通过加聚成自粘合状态而交联，含有至少一种包含乙烯和/或炔属不饱和位点（POS含有单元= Si- [不饱和键]}）的聚有机硅氧烷（POS）。 至少一种含有单元= Si-H的聚有机硅氧烷（POS）; 包括至少一种金属催化剂和至少一种交联抑制剂的催化体系; 填料; 至少一种粘合促进剂; 任选地，至少一种POS树脂; 任选的至少一种耐热剂; 和任选的至少一种其它功能性添加剂，并且可用于胶合，组装，密封，例如接头，涂料，电气，电子和汽车工程部件。
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4.发明授权Single-component adhesive silicone elastomer composition which can be crosslinked by polyaddition 失效可通过加聚交联的单组分粘合性有机硅弹性体组合物公开(公告)号：US07494694B2
公开(公告)日：2009-02-24
申请号：US10537782
申请日：2003-11-25
CPC分类号： C09K3/1018 , C08G77/12 , C08G77/14 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/70 , C08G77/80 , C08K5/526 , C08K5/5393 , C08L83/00 , C08L83/04 , C08L2666/28 , C09J183/04 , C08L2666/52
摘要： The invention relates to adhesive silicone elastomer compositions which can be crosslinked by polyaddition. The composition, crosslinkable by polyaddition (hydrosilylation), comprises: α/ at least one polyorganosiloxane (POS) bearing ethylenic and/or acetylenic unsaturations [POS with ≡Si-(unsaturated) units]; β/ at least one polyorganosiloxane (POS) with ≡Si—H units; γ/ a catalytic combination comprising γ.1 at least one metallic catalyst (preferably platinum based), γ.2 and at least one crosslinking inhibitor; δ/ a filler; ε/ at least one adhesion promoter; ρ/ at least one POS resin; λ/ at least one thermal resistance agent; and φ/ optionally at least one other functional additive. Methods of making and using the subject composition are also described.
摘要翻译： 本发明涉及可通过加聚交联的粘合性硅氧烷弹性体组合物。 通过加聚（氢化硅烷化）可交联的组合物包含：α/至少一种带有烯属和/或炔属不饱和基团的聚有机硅氧烷（POS）[具有≡Si-（不饱和单元）的POS]; β/至少一种具有≡Si-H单元的聚有机硅氧烷（POS）; γ/催化剂组合，其包含γ.1至少一种金属催化剂（优选基于铂的），γ2和至少一种交联抑制剂; 三角填料 ε/至少一种粘合促进剂; rho /至少一个POS树脂; λ/至少一种耐热剂; 和phi /任选的至少一种其它功能添加剂。 还描述了制备和使用该主题组合物的方法。
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5.发明申请USE OF A SPECIFIC PLATINUM COMPOUND IN ORDER TO IMPROVE THE RESISTANCE OF SILICON ELASTOMERS TO DEGREDATION CAUSED BY VERY HIGH TEMPERATURES 有权使用特定的铂化合物在订单中提高硅弹性体耐受非常高的温度降解的电阻公开(公告)号：US20090264563A1
公开(公告)日：2009-10-22
申请号：US11817645
申请日：2006-02-22
IPC分类号： C08K5/3445 , C07F15/00 , C08L83/04 , C08K5/04 , C09K3/00
CPC分类号： C08K5/56 , C08G77/08 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/44 , C08G77/70 , C08L83/04 , C08L83/00 , C08L2666/52
摘要： This invention is directed to stabilizing additives that contain at least one platinum complex, with the complex including a carbene group. The stabilizing additives make it possible to improve the resistance to decomposition of silicone elastomers under high temperatures. The additive can be used in a polyorganosiloxane composition intended for the production of a silicone elastomer with either crosslinks at high temperature under the action of organic peroxides or crosslinks at ambient temperature or with heat by polyaddition reactions in the presence of a metal catalyst.
摘要翻译： 本发明涉及包含至少一种铂络合物的稳定添加剂，其中络合物包括卡宾基团。 稳定添加剂可以提高硅橡胶在高温下的分解性。 该添加剂可用于生产有机硅弹性体的聚有机硅氧烷组合物中，所述聚硅氧烷组合物在有机过氧化物的作用下在高温下交联或在环境温度下交联，或在金属催化剂存在下通过加聚反应进行加热。
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6.发明授权Use of a specific platinum compound in order to improve the resistance of silicon elastomers to degredation caused by very high temperatures 有权使用特定的铂化合物以提高由非常高的温度引起的硅弹性体对降解的抵抗力公开(公告)号：US08129452B2
公开(公告)日：2012-03-06
申请号：US11817645
申请日：2006-02-22
CPC分类号： C08K5/56 , C08G77/08 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/44 , C08G77/70 , C08L83/04 , C08L83/00 , C08L2666/52
摘要： This invention is directed to stabilizing additives that contain at least one platinum complex, with the complex including a carbene group. The stabilizing additives make it possible to improve the resistance to decomposition of silicone elastomers under high temperatures. The additive can be used in a polyorganosiloxane composition intended for the production of a silicone elastomer with either crosslinks at high temperature under the action of organic peroxides or crosslinks at ambient temperature or with heat by polyaddition reactions in the presence of a metal catalyst.
摘要翻译： 本发明涉及包含至少一种铂络合物的稳定添加剂，其中络合物包括卡宾基团。 稳定添加剂可以提高硅橡胶在高温下的分解性。 该添加剂可用于生产有机硅弹性体的聚有机硅氧烷组合物中，所述聚硅氧烷组合物在有机过氧化物的作用下在高温下交联或在环境温度下交联，或在金属催化剂存在下通过加聚反应进行加热。
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7.发明申请公开(公告)号：US20090301750A1
公开(公告)日：2009-12-10
申请号：US12296576
申请日：2007-04-12
申请人： Catherine George , Alain Pouchelon , Rémi Thiria
发明人： Catherine George , Alain Pouchelon , Rémi Thiria
摘要： A polyorganosiloxane composition that can be vulcanized at high temperature to a silicone elastomer, useful in the field of the manufacture of electrical wires or cables having an improved fire performance is provided. The composition includes a semi-reinforcing filler chosen from the group composed of:—calcined kaolin powders, preferably that have undergone a chemical surface treatment;- talc;- calcium carbonate that may or may not have been surface-treated, for example with vinylsilanes, aminosilanes or (reactive or unreactive) silicone oils; and mixtures thereof.
摘要翻译： 提供了可以在高温下硫化成有机硅弹性体的聚有机硅氧烷组合物，其可用于具有改进的防火性能的电线或电缆的制造领域。 组合物包括选自以下的半增强填料：煅烧高岭土粉末，优选已进行化学表面处理; - 滑石; - 可以或可以不经表面处理的碳酸钙，例如用乙烯基硅烷 ，氨基硅烷或（反应性或非反应性）硅油; 及其混合物。
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8.发明申请Single-component adhesive silicone elastomer composition which can be crosslinked by polyaddition 失效可通过加聚交联的单组分粘合性有机硅弹性体组合物公开(公告)号：US20060128881A1
公开(公告)日：2006-06-15
申请号：US10537782
申请日：2003-11-25
CPC分类号： C09K3/1018 , C08G77/12 , C08G77/14 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/70 , C08G77/80 , C08K5/526 , C08K5/5393 , C08L83/00 , C08L83/04 , C08L2666/28 , C09J183/04 , C08L2666/52
摘要： The invention relates to adhesive silicone elastomer compositions which can be crosslinked by polyaddition. The composition, crosslinkable by polyaddition (hydrosilylation), comprises: α/ at least one polyorganosiloxane (POS) bearing ethylenic and/or acetylenic unsaturations [POS with≡Si-(unsaturated) units]; β/ at least one polyorganosiloxane (POS) with ≡Si—H units; γ/ a catalytic combination comprising γ.1 at least one metallic catalyst (preferably platinum based), γ.2 and at least one crosslinking inhibitor; δ/ a filler; ε/ at least one adhesion promoter; ρ/ at least one POS resin; λ/ at least one thermal resistance agent; and φ/ optionally at least one other functional additive. Methods of making and using the subject composition are also described.
摘要翻译： 本发明涉及可通过加聚交联的粘合性硅氧烷弹性体组合物。 通过加聚（氢化硅烷化）可交联的组合物包含：α/至少一个带有烯属和/或炔属不饱和基团的聚有机硅氧烷（POS）[具有≡Si-（不饱和单元）的POS]; β/至少一种具有≡Si-H单元的聚有机硅氧烷（POS）; γ/催化剂组合，其包含γ.1至少一种金属催化剂（优选基于铂的），γ2和至少一种交联抑制剂; 三角填料 ε/至少一种粘合促进剂; rho /至少一个POS树脂; λ/至少一种耐热剂; 和phi /任选的至少一种其它功能添加剂。 还描述了制备和使用该主题组合物的方法。
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9.发明授权公开(公告)号：US08193268B2
公开(公告)日：2012-06-05
申请号：US12296576
申请日：2007-04-12
申请人： Catherine George , Alain Pouchelon , Rémi Thiria
发明人： Catherine George , Alain Pouchelon , Rémi Thiria
摘要： A polyorganosiloxane composition that can be vulcanized at high temperature to a silicone elastomer, useful in the field of the manufacture of electrical wires or cables having an improved fire performance is provided. The composition includes a semi-reinforcing filler chosen from the group composed of:—calcined kaolin powders, preferably that have undergone a chemical surface treatment;—talc;—calcium carbonate that may or may not have been surface-treated, for example with vinylsilanes, aminosilanes or (reactive or unreactive) silicone oils; and mixtures thereof.
摘要翻译： 提供了可以在高温下硫化成有机硅弹性体的聚有机硅氧烷组合物，其可用于具有改进的防火性能的电线或电缆的制造领域。 该组合物包括选自下组的半增强填料：煅烧高岭土粉末，优选已进行化学表面处理; - 碳酸钙，碳酸钙，可以或可能不经过表面处理，例如用乙烯基硅烷 ，氨基硅烷或（反应性或非反应性）硅油; 及其混合物。
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10.发明授权Process for the surface treatment of an article containing silicone crosslinked by polyaddition 失效用于通过加聚交联的含有硅氧烷的制品的表面处理方法公开(公告)号：US07423234B2
公开(公告)日：2008-09-09
申请号：US10518344
申请日：2003-06-17
申请人： Laurent Dumont , Alain Pouchelon
发明人： Laurent Dumont , Alain Pouchelon
IPC分类号： B23K10/00
CPC分类号： C08J5/124 , B29C59/005 , B29C59/14 , B29C2059/145 , B29K2083/00 , C08J7/123 , C08J2383/04 , C09J5/02
摘要： A process for increasing the surface tension (“wettability”) of a silicone element crosslinked by polyaddition from a liquid composition containing one or more α,ω-dimethylvinylpolydimethylsiloxanes (PDMS), one or more poly(dimethyl)(methylhydrogenosiloxy)-α,ω-dimethylhydrogenosiloxanes, and a platinum crosslinking catalyst. The silicone surface is treated with a homogeneous atmospheric plasma using a plasma spraying apparatus having a rotating head with one or more plasma nozzles that are offset relative to the axis of rotation, each one being capable of generating a plasma jet whose axis is parallel to said axis of rotation. The articles to which the invention relate include composites of flexible substrate (e.g. textile)/silicone coating. Application: adhesive bonding of silicone surfaces crosslinked by ≡Si—H/≡Si-vinyl polyaddition.
摘要翻译： 通过加聚从含有一种或多种α，ω-二甲基乙烯基聚二甲基硅氧烷（PDMS），一种或多种聚（二甲基）（甲基氢甲硅烷氧基）-α，ω，ω-二甲基乙烯基聚二甲基硅氧烷的液体组合物的组合物交联的硅氧烷元素的表面张力（“润湿性” 二甲基氢硅氧烷和铂交联催化剂。 使用具有旋转头部的等离子体喷涂装置处理硅树脂表面，所述等离子体喷涂装置具有相对于旋转轴线偏移的一个或多个等离子体喷嘴，每个等离子体喷嘴能够产生其轴线平行于所述 旋转轴。 本发明涉及的制品包括柔性基底（例如织物）/硅氧烷涂层的复合材料。 应用：通过≡Si-H /≡Si-乙烯基加聚交联的硅氧烷表面的粘合剂。
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