Substituted metallocene catalyst for the (co)polymerization of olefins
    6.
    发明授权
    Substituted metallocene catalyst for the (co)polymerization of olefins 失效
    用于烯烃(共)聚合的取代茂金属催化剂

    公开(公告)号:US5936051A

    公开(公告)日:1999-08-10

    申请号:US802875

    申请日:1997-02-19

    摘要: Metallocene complexes of a metal M selected from titanium, zirconium and hafnium, comprising at least one anionic group A containing an .eta..sup.5 -cyclopentadienyl ring co-ordinated with the metal M, wherein the anionic group is substituted in at least one position of the cyclopentadienyl ring with a radical having the formula:Ph*--(CR.sup.6 R.sup.7).sub.nwherein: R.sup.6 and R.sup.7 are independently hydrogen, halogen or a C.sub.1 -C.sub.4 alkyl group, preferably hydrogen, "n" is 0 or 1, preferably 1, Ph* is a C.sub.6 -C.sub.14 group comprising an aromatic ring linked to --CR.sup.6 R.sup.7 -- or to A and substituted with at least one and up to a maximum of three electron-attractor groups, on the condition that, when A is an .eta..sup.5 -indenyl group and "n" is 0, at least one Ph group is linked to A in position 1 or 3 of indenyl.These complexes can be used in (co)polymerization processes of .alpha.-olefins, possibly in the presence of a suitable co-catalyst, for the production of polyolefins with a very high molecular weight.

    摘要翻译: 选自钛,锆和铪的金属M的茂金属络合物,其包含至少一个阴离子基团A,其含有与金属M配位的η5-环戊二烯基环,其中阴离子基团在至少一个位置的环戊二烯基 具有下式的基团:Ph * - (CR 6 R 7)n其中R 6和R 7独立地是氢,卤素或C 1 -C 4烷基,优选氢,“n”是0或1,优选1,Ph *是 包含与-CR 6 R 7 - 或A连接的芳环的C 6 -C 14基团,并且被A至5个茚基取代,并且被至少一个和最多三个吸电子基团取代, n“为0,至少有一个Ph基与茚基的1位或3位的A连接。 这些络合物可用于α-烯烃的(共)聚合方法中,可能在合适的助催化剂存在下,用于生产具有非常高分子量的聚烯烃。