摘要:
Adhesives may include a base polymer composition, optionally a tackifying resin, optionally a wax, and optionally additives (e.g., plasticizers, fillers, antioxidants, and the like, and combinations thereof), where the base polymer comprises a highly plasticized cellulose ester and optionally polymers traditionally used in pressure sensitive adhesives, hot melt pressure sensitive adhesives, or hot melt adhesives (e.g., ethylene vinyl acetate copolymers, polysiloxanes, and polyurethanes).
摘要:
Wood laminates may comprise a plurality of wood substrates and an adhesive disposed between at least a portion of at least two of the wood substrates, the adhesive comprising a substituted cellulose ester that comprises a cellulose polymer backbone having an organic ester substituent and an inorganic ester substituent that comprises an inorganic, nonmetal atom selected from the group consisting of sulfur, phosphorus, boron, and chlorine. In some instances the adhesive may be substantially formaldehyde-free.
摘要:
Wood laminates may comprise a plurality of wood substrates and an adhesive disposed between at least a portion of at least two of the wood substrates, the adhesive comprising a substituted cellulose ester that comprises a cellulose polymer backbone having an organic ester substituent and an inorganic ester substituent that comprises an inorganic, nonmetal atom selected from the group consisting of sulfur, phosphorus, boron, and chlorine. In some instances the adhesive may be substantially formaldehyde-free.
摘要:
Cellulose ester plastics may be formulated to have a depressed melt processing temperatures, improved heat resistance, increased mechanical stability, or some combination thereof. For example, in some instances, a cellulose ester plastic comprising: a cellulose ester at about 20% to about 90% by weight of the cellulose ester plastic; and a plasticizer that comprises a carbonate ester, a polyol benzoate, or both, wherein the plasticizer is at about 2% to about 40% by weight of the cellulose ester plastic, wherein the cellulose ester plastic is melt processable.
摘要:
In some instances, an adhesive may include a plasticizer in an amount of about 15% or greater by weight of the adhesive; and a cellulose acetate having a relationship between an acetyl value and an intrinsic viscosity according to Equation 1 of about 2.80 to about 3.85 (or about 2.80 to about 3.20): AV 2 + IV 2 1000 . Equation 1
摘要:
In some instances, adhesives may include a cellulose ester and a plasticizer in an amount of about 15% or greater by weight of the adhesive, wherein the plasticizer comprises a nonionic surfactant. In some instances, adhesives may include a cellulose ester and a mixture of two or more plasticizers in an amount of about 15% or greater by weight of the adhesive, wherein a melt flow index of the adhesive melt is greater than comparable adhesive melts that comprise the cellulose ester and only one of the plasticizers at the same amount.
摘要:
Hot melt and pressure-sensitive adhesives may comprise highly-plasticized cellulose esters, e.g., a cellulose ester and a plasticizer, the plasticizer included in an amount of about 30% to about 60% by weight of the cellulose ester. A highly-plasticized cellulose ester adhesive that is non-tacky at room temperature may be utilized by heating an adhesive to yield an adhesive melt, the adhesive comprising a cellulose ester and a plasticizer, the plasticizer included in an amount of about 15% to about 60% by weight of the adhesive; applying the adhesive melt to a first surface; and adhering a second surface to the first surface with the adhesive.
摘要:
Fibrous substrates may be adhered to other substrates utilizing substituted cellulose ester adhesives that comprises a cellulose polymer backbone having an organic ester substituent and an inorganic ester substituent that comprises an inorganic, nonmetal atom selected from the group consisting of sulfur, phosphorus, boron, and chlorine.
摘要:
Engineered wood may be produced with substituted cellulose ester adhesives. For example, an engineered wood may comprise a plurality of wood substrates that independently comprise a lignin-containing material (e.g., wood dust, wood particles, wood chips, and the like), the plurality of wood substrates being adhered together with an adhesive that comprises a substituted cellulose ester that comprises a cellulose polymer backbone having an organic ester substituent and an inorganic ester substituent that comprises an inorganic, nonmetal atom selected from the group consisting of sulfur, phosphorus, boron, and chlorine.
摘要:
A substituted cellulose ester having a cellulose backbone with an organic ester substituent and an inorganic ester substituent derived from the inorganic ester oxoacid catalyst may be utilized in adhesive compositions and articles produced therewith. Producing a substituted cellulose ester may, in some embodiments, involve providing a cellulose ester mixture that comprises a cellulose ester and a solvent; and hydrolyzing a mixture that comprises the cellulose ester mixture, water, and an inorganic ester oxoacid catalyst so as to yield a substituted cellulose ester having a cellulose backbone with an organic ester substituent and an inorganic ester substituent derived from the inorganic ester oxoacid catalyst.