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    Supported catalyst and method of preparing the same
    1.
    发明申请
    Supported catalyst and method of preparing the same 有权
    负载催化剂及其制备方法

    公开(公告)号：US20060159980A1

    公开(公告)日：2006-07-20

    申请号：US11334472

    申请日：2006-01-19

    申请人： Chan-Ho Pak ,  Hyuk Chang ,  Dae-Jong Yoo ,  Seol Lee ,  Gongguan Sun ,  Luhua Jian ,  Qin Xin

    发明人： Chan-Ho Pak ,  Hyuk Chang ,  Dae-Jong Yoo ,  Seol Lee ,  Gongguan Sun ,  Luhua Jian ,  Qin Xin

    IPC分类号： H01M4/86 ,  B01J21/04 ,  B01J23/02 ,  B01J31/00 ,  B01J21/18

    CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J37/035 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

    摘要： A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

    摘要翻译： 制备负载型催化剂的方法包括将阳离子交换聚合物溶解在醇中以制备含有阳离子交换聚合物的溶液; 将含阳离子交换聚合物的溶液与催化金属前体或含有催化金属前体的溶液混合; 将其pH调节至预定范围后加热混合物; 向所得物中加入还原剂并搅拌溶液以还原催化金属前体; 将所得物与催化剂载体混合; 向所得物中加入沉淀剂形成析出物; 并过滤并干燥沉淀物。 制备负载型催化剂的方法可以提供高分散的载体催化剂，其含有平均尺寸较小的催化金属颗粒，而不管催化剂载体的类型如何，这在催化金属的相同负载量下提供比常规催化剂更好的催化活性。

    Mesoporous carbon molecular sieve and supported catalyst employing the same
    4.
    发明授权
    Mesoporous carbon molecular sieve and supported catalyst employing the same 有权
    介孔碳分子筛和采用其的负载型催化剂

    公开(公告)号：US07402544B2

    公开(公告)日：2008-07-22

    申请号：US11688537

    申请日：2007-03-20

    申请人： Chan-Ho Pak ,  Hyuk Chang ,  Ji-Man Kim

    发明人： Chan-Ho Pak ,  Hyuk Chang ,  Ji-Man Kim

    IPC分类号： B01J29/00 ,  B01J27/20 ,  H01M4/02

    CPC分类号： B01J35/1061 ,  B01J21/18 ,  B01J23/42 ,  B01J29/0308 ,  B01J37/06 ,  B01J37/084 ,  C01B32/00 ,  H01M4/9083 ,  H01M4/926

    摘要： The present invention is related to a mesoporous carbon molecular sieve, which can be used as a catalyst carrier capable of improving the activity of a supported catalyst and a method of preparing the same. Additionally, the invention is related to a supported catalyst employing the mesoporous carbon molecular sieve as a carrier, and a fuel cell employing the supported catalyst. The mesoporous carbon molecular sieve has an average primary particle size of less than about 500 nm, an average mesopore size in the range of about 3 nm to about 6 nm, and a surface area in the range of about 500 m2/g to about 2000 m2/g.

    摘要翻译： 本发明涉及可用作能够提高负载型催化剂的活性的催化剂载体的介孔碳分子筛及其制备方法。 另外，本发明涉及使用中孔碳分子筛作为载体的负载催化剂和使用负载型催化剂的燃料电池。 介孔碳分子筛的平均一次粒径小于约500nm，平均中孔尺寸在约3nm至约6nm的范围内，表面积在约500μm2范围内， /约至约2000m 2 / g。

    Composite electrolyte membrane and fuel cell containing the same
    6.
    发明申请
    Composite electrolyte membrane and fuel cell containing the same 有权
    复合电解质膜和含有它的燃料电池

    公开(公告)号：US20050175880A1

    公开(公告)日：2005-08-11

    申请号：US10627705

    申请日：2003-07-28

    申请人： Ju-Hee Cho ,  Chan-Ho Pak

    发明人： Ju-Hee Cho ,  Chan-Ho Pak

    IPC分类号： H01B1/06 ,  C08J5/22 ,  H01B1/12 ,  H01M8/02 ,  H01M8/10 ,  H01M10/40

    CPC分类号： C08J5/2281 ,  C08J2327/12 ,  C08J2383/02 ,  H01B1/122 ,  H01M8/0289 ,  H01M8/1007 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1037 ,  H01M8/1039 ,  H01M8/1044 ,  H01M8/1048 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02E60/523

    摘要： A composite electrolyte membrane for decreasing the crossover of polar organic fuel and a fuel cell employing the membrane are provided. The composite electrolyte membrane includes a modified silica in which silicon atoms have substituents as represented by formula 1 and formula 2; and an cation exchange group-containing polymer: —R1—SO3X  Formula 1 —R2—S—S—R3—  Formula 2 wherein, R1 is an alkylene group with 2-7 carbon atoms, X is a hydrogen atom or an alkali metal, R2 and R3 are each independently an alkylene group with 2-7 carbon atoms.

    摘要翻译： 提供了用于减少极性有机燃料的交叉的复合电解质膜和使用该膜的燃料电池。 复合电解质膜包括其中硅原子具有由式1和式2表示的取代基的改性二氧化硅; 和含阳离子交换基团的聚合物：<？in-line-formula description =“In-line Formulas”end =“lead”→R 1→3 X Formula 1 <？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> - R 式2式中，α-in-line-formula description =“In-line formula”end =“tail”？>其中，R 1 是具有2-7个碳原子的亚烷基，X是氢原子或碱金属，R 2和R 3各自独立地是亚烷基 具有2-7个碳原子。

    Supported catalyst and method for preparing the same
    7.
    发明授权
    Supported catalyst and method for preparing the same 失效
    负载催化剂及其制备方法

    公开(公告)号：US07691773B2

    公开(公告)日：2010-04-06

    申请号：US11747009

    申请日：2007-05-10

    申请人： Sang-Hyuk Suh ,  Chan-Ho Pak ,  Hae-Kyoung Kim

    发明人： Sang-Hyuk Suh ,  Chan-Ho Pak ,  Hae-Kyoung Kim

    IPC分类号： H01M4/88 ,  B01J31/00 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

    CPC分类号： H01M4/92 ,  B01J31/08 ,  B01J31/28 ,  B01J2231/42 ,  B01J2231/52 ,  B01J2231/70 ,  B82Y30/00 ,  H01M4/926

    摘要： The invention provides and a highly-dispersed supported catalyst that has a reduced average particle size of catalytic metal particles and is also supported by a porous support material. A method of preparing a supported catalyst that can reduce the average particle size of catalytic metal particles supported by a support material includes first mixing a charged support material with a solution containing a polymer electrolyte having a charge opposite to that of the support material to adsorb the polymer electrolyte on the support material. Next, the support material having the polymer electrolyte adsorbed thereon is mixed with a solution containing a catalytic metal precursor ion having a charge opposite to that of the polymer electrolyte to adsorb the catalytic metal precursor ion on the support material having the polymer electrolyte adsorbed on it. Finally, the catalytic metal precursor ion adsorbed on the support material having the polymer electrolyte adsorbed thereon is reduced to a catalytic metal in a reducing solution.

    摘要翻译： 本发明提供了一种具有降低的催化金属颗粒的平均粒度的高度分散的负载型催化剂，并且还由多孔载体材料支撑。 制备能够降低由载体材料负载的催化金属颗粒的平均粒径的负载催化剂的方法包括首先将带电荷的载体材料与含有与载体材料相反的电荷的聚合物电解质的溶液混合以吸附 聚合物电解质在支撑材料上。 接着，将其上吸附有聚合物电解质的载体材料与含有与聚合物电解质相反的电荷的催化金属前体离子的溶液混合，以将催化金属前体离子吸附在吸附有聚合物电解质的载体材料上 。 最后，吸附在其上吸附有聚合物电解质的载体材料上的催化金属前体离子被还原为还原溶液中的催化金属。