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公开(公告)号：US5258058A
公开(公告)日：1993-11-02
申请号：US956707
申请日：1992-10-05
CPC分类号： B01D53/02 , B01D53/04 , B01J20/186 , B01D2253/108 , B01D2253/1085 , B01D2256/10 , B01D2257/10 , B01D2257/102 , B01D2259/40062 , B01D53/047 , Y10S423/21 , Y10S95/902
摘要： The present invention is directed to a process for separating nitrogen from gas mixtures containing nitrogen and less strongly adsorbed components such as oxygen, hydrogen, argon or helium by use of an at least binary exchanged X-zeolite having lithium and a divalent cation selected from the group consisting of barium, cobalt, copper, chromium, iron, magnesium, manganese, nickel, zinc and mixtures thereof in a ratio of preferably 5% to 50% of the divalent cation and 50% to 95% lithium.
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公开(公告)号：US5152813A
公开(公告)日：1992-10-06
申请号：US811404
申请日：1991-12-20
CPC分类号： B01D53/02 , B01D53/04 , B01J20/186 , C01B13/027 , C01B21/0466 , B01D2253/108 , B01D2253/1085 , B01D2256/12 , B01D2257/102 , B01D2257/11 , C01B2210/0046 , Y10S95/902
摘要： The present invention is directed to a process for separating nitrogen from gas mixtures containing nitrogen and less strongly adsorbed components such as oxygen, hydrogen, argon or helium by use of an at least binary exchanged X-zeolite having lithium and calcium and/or strontium ions in ratio of preferably 5% to 50% calcium and/or strontium and 50% to 95% lithium.
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公开(公告)号：US5419891A
公开(公告)日：1995-05-30
申请号：US123458
申请日：1993-09-17
CPC分类号： B01D53/02 , B01D53/04 , B01J20/186 , B01D2253/108 , B01D2253/1085 , B01D2256/10 , B01D2257/10 , B01D2257/102 , B01D2259/40062 , B01D53/047 , Y10S423/21 , Y10S95/902
摘要： The present invention is directed to an at least binary exchanged X-zeolite having lithium and zinc cations in a ratio of preferably 5% to 40% zinc and 50% to 95% lithium, wherein the sum of the lithium and zinc ion exchange is at least 65% of the exchangeable ion content. Theses adsorbents are useful in a process for separating nitrogen from gas mixtures containing nitrogen and less strongly adsorbed components such as oxygen, hydrogen, argon or helium.
摘要翻译： 本发明涉及至少二元交换的X沸石，其具有优选5％至40％锌和50％至95％锂的锂和锌阳离子，其中锂和锌离子交换的总和为 至少65％的可交换离子含量。 这些吸附剂可用于从含有氮气和较弱吸附组分如氧气，氩气或氦气的气体混合物中分离氮气的方法。
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公开(公告)号：US5417957A
公开(公告)日：1995-05-23
申请号：US123498
申请日：1993-09-17
CPC分类号： B01D53/02 , B01D53/04 , B01J20/186 , B01D2253/108 , B01D2253/1085 , B01D2256/10 , B01D2257/10 , B01D2257/102 , B01D2259/40062 , B01D53/047 , Y10S423/21 , Y10S95/902
摘要： The present invention is directed to an at least binary exchanged X-zeolite having lithium and a divalent cation selected from the group consisting of cobalt, copper, chromium, iron, manganese, nickel and mixtures thereof in a ratio of preferably 5% to 50% of the divalent cation and 50% to 95% lithium. Theses adsorbents are useful in a process for separating nitrogen from gas mixtures containing nitrogen and less strongly adsorbed components such as oxygen, hydrogen, argon or helium.
摘要翻译： 本发明涉及具有锂和选自钴，铜，铬，铁，锰，镍及其混合物的二价阳离子的至少二元交换的X-沸石，其比例优选为5％至50％ 的二价阳离子和50％至95％的锂。 这些吸附剂可用于从含有氮气和较弱吸附组分如氧气，氩气或氦气的气体混合物中分离氮气的方法。
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公开(公告)号：US4744837A
公开(公告)日：1988-05-17
申请号：US002841
申请日：1987-01-13
摘要： A process for bright annealing of chromium containing alloys such as stainless steels in an atmosphere of nitrogen and hydrogen containing controlled additions of an inhibitor as described in U.S. Pat. No. 4,334,938 wherein at least one element provided at the surface of the article being annealed in an amount such that it is oxidized in preference to the chromium in said article, whereby nitrogen uptake is inhibited and dulling of the metal surface by formation of a film containing chromium oxide is avoided.
摘要翻译： 在氮气和氢气气氛中对含铬合金如不锈钢进行光亮退火的方法，其含有受控添加的抑制剂，如美国专利No. 其中提供在制品表面处的至少一种元素被退火，其量使其优先于所述制品中的铬被氧化，由此通过形成膜来抑制氮吸收并使金属表面变钝 避免了含铬氧化铬。
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公开(公告)号：US4996322A
公开(公告)日：1991-02-26
申请号：US351987
申请日：1989-05-15
申请人： Ronald Pierantozzi , Mildred A. Miller , Mark L. Listemann , Thomas R. Gaffney , Charles G. Coe
发明人： Ronald Pierantozzi , Mildred A. Miller , Mark L. Listemann , Thomas R. Gaffney , Charles G. Coe
IPC分类号： C07C231/24
CPC分类号： C07C231/24
摘要： Amides having different molecular kinetic diameters or heats of adsorption, such as formamide and N-(1-alkoxyethyl)formamide, are separated under mild conditions with a molecular sieve which selectively adsorbs one of the amides, such as formamide. N-vinylformamide can be purified by removing formamide remaining in synthesis process streams using this technique. The adsorbed amide can be desorbed by heating the molecular sieve in either inert or reactive atmospheres. Preferred molecular sieves include the zeolites of types A, X, Y, molecular sieves of the MFI topology, chabazite, and mordenite. Calcium chabazite is particularly versatile and effective.
摘要翻译： 具有不同分子动力学直径或吸附热的酰胺如甲酰胺和N-（1-烷氧基乙基）甲酰胺在温和条件下用选择性吸附一种酰胺如甲酰胺的分子筛分离。 可以使用该技术通过除去残留在合成工艺流中的甲酰胺来纯化N-乙烯基甲酰胺。 吸附的酰胺可以通过在惰性或反应性气氛中加热分子筛来解吸。 优选的分子筛包括MFI拓扑结构类型A，X，Y，分子筛的沸石，菱沸石和丝光沸石。 钙菱沸石是特别多功能和有效的。
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公开(公告)号：US5584912A
公开(公告)日：1996-12-17
申请号：US626814
申请日：1996-04-03
申请人： Hong-Xin Li , Charles G. Coe , Thomas R. Gaffney , Yanliang Xiong , Johan A. Martens , Pierre A. Jacobs
发明人： Hong-Xin Li , Charles G. Coe , Thomas R. Gaffney , Yanliang Xiong , Johan A. Martens , Pierre A. Jacobs
CPC分类号： B01D53/02 , B01J20/18 , C01B13/027 , C01B21/0466 , C01B39/205 , B01D2253/104 , B01D2253/106 , B01D2253/311 , B01D53/047 , C01B2210/0046 , Y10S423/21 , Y10S95/902
摘要： The present invention is a composition, a synthesis of the composition and a method of using the composition for selectively adsorptively separating nitrogen from oxygen wherein the composition is a crystalline EMT with a Si/Al ratio less than 2.0 and a micropore volume determined in the sodium and/or potassium form of at least 0.20 cm.sup.3 /g and a lithium cation exchange of at least 80%, preferably including an intergrowth with a crystalline FAU structure, wherein the pure or intergrowth compositions have the chemical formula:M.sub.2/n O:X.sub.2 O.sub.3 :(2.0 to
摘要翻译： 本发明是一种组合物，该组合物的合成和一种使用该组合物选择性地从氧气中分离氮气的方法，其中该组合物是Si / Al比小于2.0的结晶EMT，在钠中测定的微孔体积 和/或钾形式为至少0.20cm 3 / g和至少80％的锂阳离子交换，优选包括与结晶FAU结构的共生体，其中纯或共生成分具有以下化学式：M2 / nO：X 2 O 3： （2.0至<4.0）SiO 2，其中M =一价或多价的价数为n的金属阳离子，X选自铝，镓和硼，优选铝。
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公开(公告)号：US4713362A
公开(公告)日：1987-12-15
申请号：US866531
申请日：1986-05-22
CPC分类号： C01B23/00 , B01D53/02 , B01J20/18 , C01B13/027 , C01B3/56 , C01B2203/042 , C01B2203/0465 , C01B2203/047 , C01B2203/048 , C01B2210/0082
摘要： A selective zeolitic adsorbent is prepared by activating a zeolitic composition having at least a portion, preferably at least 50%, of the exchangeable ion capacity occupied by a cation having a charge density of 2.0 or greater, preferably a divalent cation with a charge density of 2.0 or greater, such as calcium or magnesium by thoroughly dehydrating the exchanged zeolite. Additionally, separation ability of the zeolitic adsorbent can be further increased by reacting the thoroughly dehydrated zeolite in an oxidizing atmosphere.
摘要翻译： 通过活化沸石组合物制备选择性沸石吸附剂，所述沸石组合物具有至少一部分，优选至少50％的电荷密度为2.0或更大的阳离子所占据的可交换离子能力，优选电荷密度为 2.0或更大，例如通过使交换的沸石彻底脱水来脱离钙或镁。 此外，通过在氧化气氛中使完全脱水的沸石反应，可以进一步提高沸石吸附剂的分离能力。
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9.发明授权Substituted acetylacetonate cobaltic promoters for unsaturated polyester resin 失效用于不饱和聚酯树脂的取代的乙酰丙酮钴助催化剂
公开(公告)号：US4138385A
公开(公告)日：1979-02-06
申请号：US830182
申请日：1977-09-02
IPC分类号： C08F299/04 , C08L67/00 , C08L67/06
CPC分类号： C08F299/0464
摘要： This invention relates to an improvement in a process for curing unsaturated polyester resins, preferably chemically thickened with a Group II metal oxide or hydroxide, and to the resulting product. The improvement resides in the use of an acetylacetonate ligand of cobalt III, which is mono, di, or tri-substituted with an electron withdrawing group, e.g. a nitro, phenyl or halogen atom.
摘要翻译： 本发明涉及用于固化不饱和聚酯树脂，优选用第II族金属氧化物或氢氧化物化学增稠的方法和所得产物的改进。 改进在于使用由吸电子基团单，二或三取代的钴III的乙酰丙酮配体。 硝基，苯基或卤原子。
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公开(公告)号：US5567407A
公开(公告)日：1996-10-22
申请号：US241880
申请日：1994-05-12
申请人： Charles G. Coe , Thomas R. Gaffney , Hong-Xin Li , Yanliang Xiong , Johan A. Martens , Pierre A. Jacobs
发明人： Charles G. Coe , Thomas R. Gaffney , Hong-Xin Li , Yanliang Xiong , Johan A. Martens , Pierre A. Jacobs
IPC分类号： B01D53/34 , B01D53/047 , B01D53/81 , B01J20/18 , B01J20/30 , C01B13/02 , C01B21/04 , C01B39/20
CPC分类号： B01D53/02 , B01D53/047 , B01J20/18 , C01B13/027 , C01B21/0466 , C01B39/205 , B01D2253/108 , B01D2253/30 , B01D2256/12 , B01D2257/102 , B01D2259/402 , C01B2210/0046 , Y10S423/21 , Y10S95/902
摘要： The present invention is a composition, a synthesis of the composition and a method of using the composition for selectively adsorptively separating nitrogen from oxygen wherein the composition is a crystalline EMT with a Si/Al ratio less than 2.0 and a lithium cation exchange of at least 80%, preferably including an intergrowth with a crystalline FAU structure, wherein the pure or intergrowth compositions have the chemical formula:(0.20-0.0)M.sub.2/n O:(0.80-1.0)Li.sub.2 O:X.sub.2 O.sub.3 :(2.0 to
摘要翻译： 本发明是一种组合物，该组合物的合成以及使用该组合物选择性地从氧气中分离氮气的方法，其中该组合物是Si / Al比小于2.0的结晶EMT和至少一种锂阳离子交换 80％，优选包括具有结晶FAU结构的共生体，其中纯或共生成分具有以下化学式：（0.20-0.0）M2 / nO：（0.80-1.0）Li 2 O：X 2 O 3：（2.0至4.0）SiO 2其中 M =具有n价的锂以外的金属阳离子，X选自铝，镓和硼，优选铝。
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