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1.发明授权Conversion of mononitro aromatic compounds to amino compounds by hydrogen sulfide 失效通过硫化氢将单硝基芳族化合物转化为氨基化合物
公开(公告)号：US4326081A
公开(公告)日：1982-04-20
申请号：US237326
申请日：1981-02-23
IPC分类号： C07C85/11
CPC分类号： C07C213/02 , C07C209/365
摘要： Hydrogenation of mononitroaromatic compounds, particularly nitrobenzene, nitrotoluene and their monochloro and monohydroxy ring substitution products, using hydrogen sulfide as reducing agent and a titanium dioxide catalyst at 200.degree.-400.degree. C. and atmospheric pressure.
摘要翻译： 在200°-400℃和大气压下，使用硫化氢作为还原剂和二氧化钛催化剂氢化单硝基芳族化合物，特别是硝基苯，硝基甲苯及其一氯和单羟基环取代产物。
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公开(公告)号：US4668825A
公开(公告)日：1987-05-26
申请号：US625957
申请日：1984-06-29
IPC分类号： C07C149/06 , C07C149/10
CPC分类号： C07C321/00
摘要： Methanethiol is produced from a gaseous feed comprising a mixture of H.sub.2 S and CO by contacting said feed with a catalyst comprising rutile titania at a temperature of at least about 225.degree. C.
摘要翻译： 通过在至少约225℃的温度下使所述进料与包含金红石二氧化钛的催化剂接触，由包含H 2 S和CO的混合物的气态进料产生甲硫醇。
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公开(公告)号：US4287128A
公开(公告)日：1981-09-01
申请号：US141550
申请日：1980-04-18
申请人： Charles T. Ratcliffe
发明人： Charles T. Ratcliffe
IPC分类号： C07C291/02 , C07D273/00 , C07D273/01 , C07D303/08 , C07D303/48 , C07D301/03
CPC分类号： C07D301/14 , C07C291/02 , C07D273/00 , C07D303/48
摘要： A new process for preparing haloalkyl epoxides and oxaziranes is described in which a mixture of an perhalo alkene or alkyl imine and chlorine gas is contacted with a Group IA, IIA metal oxide, carbonate or bicarbonate under mild conditions of temperature and pressure. The process, using perhalo alkenes or perhalo alkyl imines as starting material, represents a new economical, facil preparation of the monomer hexafluoropropylene oxide, such monomer is capable of polymerizaton or copolymerization to thermally stable and inert polymers.
摘要翻译： 描述了制备卤代烷基环氧化物和恶唑烷的新方法，其中在温和的温度和压力条件下，全卤代烯烃或烷基亚胺和氯气的混合物与IA，IIA金属氧化物，碳酸盐或碳酸氢钠接触。 使用全卤代烯烃或全卤代烷基亚胺作为起始原料的方法代表单体六氟环氧丙烷的新型经济，方便的制备方法，该单体能够聚合或共聚至热稳定和惰性的聚合物。
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4.发明授权Alkylation process using a catalyst having an increased selectivity for monoalkylation 失效使用具有增加的单烷基化选择性的催化剂的烷基化方法
公开(公告)号：US4876408A
公开(公告)日：1989-10-24
申请号：US251752
申请日：1988-10-03
申请人： Charles T. Ratcliffe , John W. Ward
发明人： Charles T. Ratcliffe , John W. Ward
CPC分类号： B01J37/0018 , B01J21/18 , B01J29/084 , C07C2/66 , B01J2229/123 , B01J2229/34 , C07C2521/04 , C07C2529/08 , C07C2529/60 , C07C2529/70
摘要： A process for treating a molecular sieve-containing alkylation catalyst to increase its selectivity for monoalkylation in which the alkylation catalyst is contacted with a feedstock comprising at least one organic compound under conditions such that a sufficient amount of carbonaceous material evenly deposits on the alkylation catalyst to substantially suppress its alkylation activity. The carbon-containing catalyst particles are then subjected to combustion by contacting them with a gaseous oxidizing agent at an elevated temperature to remove at least a portion of the carbonaceous material, preferably substantially all of the carbonaceous material, thereby increasing the selectivity of the catalyst for monoalkylation by at least about 1.0 percentage point. The resulting alkylation catalyst an be used to alkylate benzene and other aromatic compounds with ethylene, propylene or other olefins to produce high yields of ethylbenzene, cumene and other alkylated products. Preferably, the alkylation catalyst contains an ammonium-exchanged and steam stabilized Y zeolite.
摘要翻译： 一种用于处理含分子筛的烷基化催化剂以提高其对单烷基化的选择性的方法，其中烷基化催化剂与包含至少一种有机化合物的原料接触，条件是使足够量的碳质材料均匀沉积在烷基化催化剂上， 基本上抑制其烷基化活性。 然后使含碳催化剂颗粒在高温下与气态氧化剂接触使其燃烧，以除去至少一部分含碳材料，优选基本上所有的碳质材料，从而提高催化剂对于 单烷基化至少约1.0个百分点。 所得到的烷基化催化剂用于使苯和其它芳族化合物与乙烯，丙烯或其它烯烃烷基化，以产生高产率的乙苯，枯烯和其它烷基化产物。 优选地，烷基化催化剂含有铵交换和蒸汽稳定的Y沸石。
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公开(公告)号：US4570020A
公开(公告)日：1986-02-11
申请号：US626065
申请日：1984-06-29
IPC分类号： C07C149/06 , C07C149/10
CPC分类号： C07C321/00
摘要： Methanethiol is produced from a gaseous feed comprising a mixture of H.sub.2 S and CO by contacting said feed, at a temperature of at least about 225.degree. C., with a catalyst comprising an oxide of a metal selected from the group consisting of V, Nb, and Ta and mixtures thereof, preferably V, supported on titania and wherein at least a portion, and preferably at least about 25 wt. %, of said supported oxide is in a non-crystalline form.
摘要翻译： 通过在至少约225℃的温度下使所述进料与包含选自V，Nb，Nb的金属的氧化物的催化剂接触，由包含H 2 S和CO的混合物的气态进料生产甲硫醇， 和Ta及其混合物，优选V，负载在二氧化钛上，并且其中至少一部分，优选至少约25wt。 所述负载型氧化物的％为非晶态。
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公开(公告)号：US4071606A
公开(公告)日：1978-01-31
申请号：US750044
申请日：1976-12-13
申请人： Charles T. Ratcliffe , Geza Pap
发明人： Charles T. Ratcliffe , Geza Pap
CPC分类号： B01J8/24 , B01D53/508 , C01B17/0456 , C01B17/0482 , Y10S48/04
摘要： A process is described for producing sulfur by the reaction of sulfur dioxide with agglomerating coal. The purity of the product gases is improved and the tendency of the coal to agglomerate is reduced by employing coal particles having a particle size below 500 microns.
摘要翻译： 描述了通过二氧化硫与附聚煤的反应来生产硫的方法。 通过使用粒度小于500微米的煤颗粒，提高了产物气体的纯度，并且降低了煤团聚的倾向。
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7.发明授权Process for increasing the selectivity of an alkylation catalyst for monoalkylation 失效提高烷基化催化剂用于单烷基化的选择性的方法
公开(公告)号：US4798816A
公开(公告)日：1989-01-17
申请号：US943911
申请日：1986-12-19
申请人： Charles T. Ratcliffe , John W. Ward
发明人： Charles T. Ratcliffe , John W. Ward
IPC分类号： B01J29/04 , B01J21/18 , B01J29/035 , B01J29/08 , B01J29/50 , B01J29/60 , B01J29/83 , B01J29/90 , B01J37/00 , C07B61/00 , C07C1/00 , C07C2/66 , C07C15/02 , C07C15/085 , C07C67/00 , B01J29/06 , B01J29/02
CPC分类号： B01J21/18 , B01J29/084 , B01J37/0018 , C07C2/66 , B01J2229/123 , B01J2229/34 , C07C2521/04 , C07C2529/08 , C07C2529/60 , C07C2529/70
摘要： A process for treating a molecular sieve-containing alkylation catalyst to increase its selectivity for monoalkylation in which the alkylation catalyst is contacted with a feedstock comprising at least one organic compound under conditions such that a sufficient amount of carbonaceous material evenly deposits on the alkylation catalyst to substantially suppress its alkylation activity. The carbon-containing catalyst particles are then subjected to combustion by contacting them with a gaseous oxidizing agent at an elevated temperature to remove at least a portion of the carbonaceous material, preferably substantially all of the carbonaceous material, thereby increasing the selectivity of the catalyst for monoalkylation by at least about 1.0 percentage point. The resulting alkylation catalyst can be used to alkylate benzene and other aromatic compounds with ethylene, propylene or other olefins to produce high yields of ethylbenzene, cumene and other alkylated products. Preferably, the alkylation catalyst contains an ammonium-exchanged and steam stabilized Y zeolite.
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公开(公告)号：US4235699A
公开(公告)日：1980-11-25
申请号：US17514
申请日：1979-03-05
CPC分类号： C10G1/06 , Y10S208/951
摘要： Conversion of coal to products soluble in common solvents and conversion of coal tar to products of lower molecular weight, effected in liquid or fused reaction medium using a hydrogenating reactant, are carried out employing hydrogen sulfide and carbon monoxide as the sole or major hydrogenating reactant, without need of elemental hydrogen or a hydrogen donor solvent.
摘要翻译： 使用硫化氢和一氧化碳作为唯一或主要的氢化反应物，将煤转化为可溶于常用溶剂的产物和煤焦油转化为低分子量产物，使用氢化反应物在液体或熔融反应介质中进行， 而不需要元素氢或氢供体溶剂。
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9.发明授权Catalytic reduction of aromatic sulfonyl halides with hydrogen sulfide to yield aromatic thiols 失效用硫化氢催化还原芳族磺酰卤，得到芳族硫醇
公开(公告)号：US4128586A
公开(公告)日：1978-12-05
申请号：US881952
申请日：1978-02-27
申请人： Charles T. Ratcliffe
发明人： Charles T. Ratcliffe
IPC分类号： C07C149/28
CPC分类号： C07C319/02
摘要： A process for reducing aromatic sulfonyl halides with hydrogen sulfide. Hydrogen sulfide is contacted with sulfonyl halides preferably in the presence of a solvent and of a catalyst. The reaction forms thiols and proceeds in the range of between about 50.degree. and 300.degree. C. There is little formation of disulfide and no cleavage of the thiol group.
摘要翻译： 用硫化氢还原芳族磺酰卤的方法。 硫化氢优选在溶剂和催化剂存在下与磺酰卤接触。 该反应形成硫醇，并且在约50℃至300℃的范围内进行。二硫化物几乎没有形成，而硫醇基团没有裂解。
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公开(公告)号：US4761162A
公开(公告)日：1988-08-02
申请号：US916866
申请日：1986-10-09
摘要： Solid carbonaceous fuel is dried to a desired moisture content, cooled, and stored in an atmosphere having a controlled humidity and oxygen content to prevent heat generation which causes spontaneous combustion. A suitable atmosphere is produced by displacing air in a storage enclosure with dehumidified combustion gases.
摘要翻译： 将固体碳质燃料干燥至期望的含水量，冷却并储存在具有受控湿度和氧含量的气氛中，以防止引起自发燃烧的发热。 通过用除湿的燃烧气体置换存储外壳中的空气来产生合适的气氛。
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