公开(公告)号：US11633707B2

公开(公告)日：2023-04-25

申请号：US17568957

申请日：2022-01-05

申请人： Chevron Phillips Chemical Company LP

发明人： Vincent D. McGahee ,  Cameron M. Crager ,  William D. Treleaven

IPC分类号： B01J8/02 ,  B01J8/04 ,  B01J29/60 ,  B01J37/02

摘要： A bi-modal radial flow reactor comprising a cylindrical outer housing surrounding at least five cylindrical, concentric zones, including at least three annulus vapor zones and at least two catalyst zones. The at least two catalyst zones comprise an outer catalyst zone and an inner catalyst zone. The at least three annulus vapor zones comprise an outer annulus vapor zone, a middle annulus vapor zone, and a central annulus vapor zone, wherein the central annulus vapor zone extends along a centerline of the bi-modal radial flow reactor. The outer catalyst zone is intercalated with the outer annulus vapor zone and the middle annulus vapor zone, and the inner catalyst zone is intercalated with the middle annulus vapor zone and the central annulus vapor zone. A removable head cover can be fixably coupled to a top of the cylindrical outer housing to seal a top of the bi-modal radial flow reactor.

公开(公告)号：US11554359B2

公开(公告)日：2023-01-17

申请号：US16644019

申请日：2018-09-05

申请人： Jonas Hedlund ,  Allan Holmgren ,  Liang Yu

发明人： Jonas Hedlund ,  Allan Holmgren ,  Liang Yu

IPC分类号： B01J35/06 ,  B01J20/18 ,  B01D63/06 ,  B01D67/00 ,  B01D69/10 ,  B01D71/02 ,  B01J20/28 ,  B01J29/035 ,  B01J29/70 ,  B01J29/06 ,  B01J29/85 ,  B01J29/18 ,  B01J29/65 ,  B01J29/40 ,  B01J29/04 ,  B01J29/60 ,  B01J29/08 ,  B01J37/02 ,  B01J35/00

摘要： A method for producing a crystalline film comprising zeolite and/or zeolite-like crystals on a porous substrate is described. The method has the steps of: providing a porous support; modifying at least a surface of the top-layer of said porous support by treatment with a composition having one or more cationic polymer(s); rendering at least the outer surface of said porous support hydrophobic by treatment with a composition having one or more hydrophobic agent(s); subjecting said treated porous support to a composition having zeolite and/or zeolite-like crystals thereby depositing and attaching zeolite and/or zeolite-like crystals on said treated porous support, and growing a crystalline film of zeolite and/or zeolite-like crystals on said treated porous support and calcination. Crystalline films find use in a variety of fields such as in the production of membranes, catalysts etc.

公开(公告)号：US20210115341A1

公开(公告)日：2021-04-22

申请号：US17076471

申请日：2020-10-21

申请人： CHEVRON U.S.A. INC

发明人： Vijay R. Sampath

IPC分类号： C10G35/085 ,  B01J23/42 ,  B01J29/60 ,  B01J35/02 ,  B01J8/06 ,  B01J8/00

摘要： The present invention pertains to improved processes and catalysts for aromatization. The processes generally contacting a feed stream comprising a naphtha fraction having a C6 to C8 content with a catalyst pellet composition to form aromatic hydrocarbons. The catalyst pellet composition generally comprises a plurality of cylindrical pellets each pellet comprising a Group VIII metal on a zeolite. The pellets may have (a) a plurality of holes passing through the length of the cylindrical pellets, (b) a dome-shaped top and bottom, and (c) a plurality of semi-circular grooves along the length of the exterior of the cylinder.

公开(公告)号：US20180223711A1

公开(公告)日：2018-08-09

申请号：US15771999

申请日：2015-10-29

申请人： VOLVO TRUCK CORPORATION ,  Centre national de la recherche scientifique ,  Université Claude Bernard Lyon 1

发明人： Anne GIROIR-FENDLER ,  Sonia GIL VILLARINO ,  Eduard Emil IOJOIU

IPC分类号： F01N3/035 ,  B01D53/94 ,  B01J29/40 ,  B01J29/70 ,  B01J29/08 ,  B01J29/60 ,  B01J35/04 ,  B01J35/10 ,  B01J37/02 ,  B01J29/85 ,  B01J35/02 ,  F01N3/20 ,  F01N3/28

CPC分类号： F01N3/035 ,  B01D53/9418 ,  B01D53/944 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9155 ,  B01D2255/9202 ,  B01D2255/9205 ,  B01J29/08 ,  B01J29/10 ,  B01J29/40 ,  B01J29/42 ,  B01J29/60 ,  B01J29/61 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7207 ,  B01J29/7215 ,  B01J29/723 ,  B01J29/85 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/04 ,  B01J35/10 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0215 ,  B01J37/10 ,  B01J2229/64 ,  B01J2229/66 ,  F01N3/2066 ,  F01N3/2828 ,  F01N2330/06 ,  F01N2330/30 ,  F01N2370/04 ,  F01N2510/063 ,  Y02A50/2325 ,  Y02C20/10 ,  Y02T10/24

摘要： Disclosed is a reactive filter, that is a selective catalytic reduction filter or an oxidative reaction filter, including a porous substrate including internal pores having their inner surface, totally or partially, directly coated with a catalytic zeolite material resulting from an in situ hydrothermal synthesis. Also disclosed is a process for preparing such a reactive filter and the use thereof in an engine exhaust depolluting system.

公开(公告)号：US10011537B2

公开(公告)日：2018-07-03

申请号：US15383502

申请日：2016-12-19

申请人： Total Research & Technology Feluy

发明人： Nikolai Nesterenko ,  Walter Vermeiren ,  Sander Van Donk

IPC分类号： C07C1/20 ,  C07C1/26 ,  C07C1/32 ,  C07C4/06 ,  B01J29/65 ,  B01J29/70 ,  B01J29/60 ,  C08F10/06 ,  B01J23/00 ,  B01J27/16 ,  B01J29/40 ,  B01J29/06 ,  B01J21/16 ,  B01J37/28 ,  B01J29/08 ,  B01J37/10

CPC分类号： C07C1/20 ,  B01J21/16 ,  B01J23/00 ,  B01J27/16 ,  B01J29/06 ,  B01J29/08 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/7007 ,  B01J29/7026 ,  B01J29/7038 ,  B01J29/7046 ,  B01J37/10 ,  B01J37/28 ,  B01J2029/081 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/42 ,  C07C4/06 ,  C07C2529/40 ,  C08F10/06 ,  Y02P30/42 ,  C07C11/02

摘要： A process for obtaining a catalyst composite comprising the following steps: a). selecting a molecular sieve having pores of 10- or more-membered rings b). contacting the molecular sieve with a metal silicate different from said molecular sieve comprising at least one alkaline earth metal and one or more of the following metals: Ga, Al, Ce, In, Cs, Sc, Sn, Li, Zn, Co, Mo, Mn, Ni, Fe, Cu, Cr, Ti and V, such that the composite comprises at least 0.1 wt % of silicate.

公开(公告)号：US09446960B2

公开(公告)日：2016-09-20

申请号：US13679054

申请日：2012-11-16

申请人： BASF SE

发明人： Hermann Luyken ,  William Todd Owens

IPC分类号： C01B39/02 ,  B01J37/06 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/50 ,  B01J29/60 ,  B01J29/70 ,  B01J37/00 ,  C10G11/05 ,  B01J29/06

CPC分类号： C01B39/026 ,  B01J29/061 ,  B01J29/087 ,  B01J29/088 ,  B01J29/185 ,  B01J29/405 ,  B01J29/505 ,  B01J29/605 ,  B01J29/7053 ,  B01J29/7065 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/06 ,  B01J2229/186 ,  B01J2229/38 ,  B01J2229/42 ,  C10G11/05

摘要： Aspects of the present invention relate to an improved process for exchanging sodium ions in zeolites comprising sodium ions and rare earth metal ions for ammonium ions. For this exchange, aqueous solutions of ammonium salts, for example ammonium sulfate, ammonium nitrate or ammonium chloride, are currently being used. The resulting “ammonium zeolites” are calcined to convert them, with release of ammonia, to the H form of the zeolites suitable as a catalyst. The use of ammonium carbonate also minimizes the amount of rare earth metal ions which are leached out of the zeolites comprising rare earth metal ions.

摘要翻译： 本发明的方面涉及一种用于在包含钠离子和用于铵离子的稀土金属离子的沸石中交换钠离子的改进方法。 对于这种交换，目前正在使用铵盐的水溶液，例如硫酸铵，硝酸铵或氯化铵。 将所得的“铵沸石”煅烧以将其转化为氨释放到适合作为催化剂的沸石的H形式。 使用碳酸铵还使从稀土金属离子的沸石中浸出的稀土金属离子的量最小化。

公开(公告)号：US20160059225A1

公开(公告)日：2016-03-03

申请号：US14505308

申请日：2014-10-02

申请人： Dan XIE ,  Stacey Ian ZONES ,  Robert James SAXTON

发明人： Dan XIE ,  Stacey Ian ZONES ,  Robert James SAXTON

IPC分类号： B01J29/60 ,  C01B39/46 ,  B01J35/02 ,  B01J37/03 ,  B01J37/10 ,  C01B39/02 ,  B01J37/04

CPC分类号： B01J29/60 ,  B01J35/023 ,  B01J37/038 ,  B01J37/04 ,  B01J37/10 ,  B01J2229/10 ,  B01J2229/38 ,  C01B39/026 ,  C01B39/32 ,  C01B39/46 ,  C01P2004/32 ,  C01P2004/38 ,  C01P2004/45 ,  C01P2004/62

摘要： Small crystal LTL framework type zeolites, characterized as polycrystalline aggregates, each of the aggregates comprising a plurality of spherical or cube-like crystallites and wherein each crystallite has an average crystallite size of from 10 to 50 nm, are disclosed. Such zeolites can be prepared by hydrothermal conversion of FAU framework type zeolites at low H2O/SiO2 mole ratios.

摘要翻译： 小晶体LTL骨架型沸石，其特征在于多晶聚集体，每个聚集体包含多个球形或立方体微晶，并且其中每个微晶具有10至50nm的平均微晶尺寸。 这种沸石可以通过以低H 2 O / SiO 2摩尔比的FAU骨架型沸石的水热转化来制备。

公开(公告)号：US20090291826A1

公开(公告)日：2009-11-26

申请号：US12368551

申请日：2009-02-10

申请人： Kazushige Ohno ,  Masafumi Kunieda ,  Takahiko Ido

发明人： Kazushige Ohno ,  Masafumi Kunieda ,  Takahiko Ido

IPC分类号： B01J29/04 ,  B01J29/06 ,  B01J29/072 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60

CPC分类号： B01D46/247 ,  B01D46/2451 ,  B01D46/2455 ,  B01D46/2459 ,  B01D46/2466 ,  B01D53/9418 ,  B01D53/9477 ,  B01D2046/2481 ,  B01D2046/2496 ,  B01D2251/2067 ,  B01D2255/104 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2258/012 ,  B01J29/06 ,  B01J29/072 ,  B01J29/7615 ,  B01J35/002 ,  B01J35/04 ,  B01J35/06 ,  B01J37/0009 ,  B01J2229/186 ,  C04B35/18 ,  C04B35/803 ,  C04B38/0009 ,  C04B2111/00198 ,  C04B2111/00793 ,  C04B2111/0081 ,  F01N3/0222 ,  F01N3/2066 ,  F01N3/2828 ,  F01N2330/30 ,  F01N2340/00 ,  Y02T10/20 ,  C04B38/0016 ,  C04B38/0074

摘要： A honeycomb structure includes at least one honeycomb unit. The at least one honeycomb unit includes zeolite, inorganic binder, and cell walls extending from a first end face to a second end face along a longitudinal direction of the at least one honeycomb unit to define cells. The at least one honeycomb unit includes a cross-sectional surface orthogonal to the longitudinal direction having a substantially square shape. An aperture ratio of the at least one honeycomb unit is in a range from about 50% to about 65%. A formula 12.5V+50

摘要翻译： 蜂窝结构体包括至少一个蜂窝单元。 所述至少一个蜂窝单元包括沿所述至少一个蜂窝单元的纵向方向从第一端面延伸到第二端面的沸石，无机粘结剂和细胞壁，以限定细胞。 所述至少一个蜂窝单元包括与所述纵向方向正交的截面，所述横截面具有大致正方形的形状。 所述至少一个蜂窝单元的开口率在约50％至约65％的范围内。 满足公式12.5V + 50

公开(公告)号：US6084145A

公开(公告)日：2000-07-04

申请号：US56238

申请日：1998-04-07

申请人： An-Hsiang Wu ,  Charles A. Drake

发明人： An-Hsiang Wu ,  Charles A. Drake

IPC分类号： B01J23/26 ,  B01J29/60 ,  B01J29/64 ,  B01J37/00 ,  C07C5/32 ,  C07C5/333

CPC分类号： C07C5/322 ,  B01J23/26 ,  B01J29/60 ,  B01J29/64 ,  B01J37/0009 ,  C07C5/3332 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2521/04 ,  C07C2523/26 ,  C07C2529/60

摘要： A dehydrogenation catalyst is produced by a process comprising the steps of: mixing an L-zeolite, chromium(VI) oxide, a binder, and an acid to form a mixture; and calcining the mixture at a temperature of about 200-800.degree. C. A paraffin having 2-7 carbon atoms per molecule can be contacted with the above-described catalyst under dehydrogenation conditions to produce olefins having the same number of carbon atoms per molecule as the paraffin.

摘要翻译： 通过包括以下步骤的方法制备脱氢催化剂：将L-沸石，氧化铬（VI），粘合剂和酸混合以形成混合物; 并在大约200-800℃的温度下煅烧混合物。每个分子具有2-7个碳原子的链烷烃可以在脱氢条件下与上述催化剂接触，以产生每分子碳原子数相同的烯烃 石蜡。

公开(公告)号：US6066251A

公开(公告)日：2000-05-23

申请号：US211789

申请日：1998-12-15

申请人： Qianjun Chen ,  Paula L. Bogdan

发明人： Qianjun Chen ,  Paula L. Bogdan

IPC分类号： B01J21/02 ,  B01J29/06 ,  B01J29/068 ,  B01J29/60 ,  B01J29/62 ,  B01J35/00 ,  C10G35/095

CPC分类号： C10G35/095 ,  B01J21/02 ,  B01J29/06 ,  B01J29/60 ,  B01J29/62 ,  B01J35/0006

摘要： A catalyst system comprising a physical mixture of particles of a non-acidic large-pore zeolite containing a platinum-group metal and particles comprising a refractory inorganic oxide which is metal-free is effective for the reforming of a hydrocarbon feedstock. Reforming of paraffinic feedstocks to effect aromatization, particularly of a raffinate from aromatics extraction, provides improved activity in producing gasoline-range products when using the catalyst system of the invention.

摘要翻译： 包含含有铂族金属的非酸性大孔沸石的颗粒和包含无金属的耐火无机氧化物的颗粒的物理混合物的催化剂体系对于烃原料的重整是有效的。 改进石蜡原料以实现芳构化，特别是芳族化合物萃取的萃余液，在使用本发明的催化剂体系时提供改进的生产汽油范围产物的活性。