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公开(公告)号：US5557016A
公开(公告)日：1996-09-17
申请号：US196180
申请日：1994-04-06
申请人： Chihiro Miyazawa , Tomoyuki Mori , Hiroshi Kameo , Shinji Isogai
发明人： Chihiro Miyazawa , Tomoyuki Mori , Hiroshi Kameo , Shinji Isogai
摘要： The disclosure describes a process for producing alkadienols comprising the steps of: reacting a conjugated alkadiene with water in a reaction solvent in the presence of a palladium catalyst; distilling the obtained reaction mixture so as to separate the reaction solvent from the reaction mixture while directly supplying heated water, steam or a mixture thereof as a heating medium to a distillation column, under the condition that the temperature of a bottom liquid in the distillation column is not higher than 120.degree. C.; and phase-separating bottoms discharged from the bottom of the distillation column.
摘要翻译： PCT No.PCT / JP93 / 00891 Sec。 371日期1994年4月6日 102（e）日期1994年4月6日PCT Filed 1993年6月29日PCT Pub。 第WO94 / 00410号公报 日本1994年1月6日本公开内容描述了制备链二烯醇的方法，包括以下步骤：在钯催化剂存在下，使反应溶剂中的共轭链二烯与水反应; 蒸馏得到的反应混合物，以便将反应溶剂从反应混合物中分离出来，同时直接将加热的水，蒸汽或其作为加热介质的混合物供应到蒸馏塔，在蒸馏塔中的底部液体的温度 不高于120℃。 并从蒸馏塔的底部排出的相分离塔底物。
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公开(公告)号：US5696304A
公开(公告)日：1997-12-09
申请号：US570468
申请日：1995-12-11
申请人： Chihiro Miyazawa , Tomoyuki Mori , Hiroshi Kameo , Shinji Isogai
发明人： Chihiro Miyazawa , Tomoyuki Mori , Hiroshi Kameo , Shinji Isogai
摘要： The disclosure describes a process for producing alkadienols comprising the steps of: reacting a conjugated alkadiene with water in a reaction solvent in the presence of a palladium catalyst; distilling the obtained reaction mixture so as to separate the reaction solvent from the reaction mixture while directly supplying heated water, steam or a mixture thereof as a heating medium to a distillation column, under the condition that the temperature of a bottom liquid in the distillation column is not higher than 120.degree. C.; and phase-separating bottoms discharged from the bottom of the distillation column.
摘要翻译： 本公开描述了一种制备链二烯醇的方法，包括以下步骤：在钯催化剂存在下，使反应溶剂中的共轭链二烯与水反应; 蒸馏得到的反应混合物，以便将反应溶剂从反应混合物中分离出来，同时直接将加热的水，蒸汽或其作为加热介质的混合物供应到蒸馏塔，在蒸馏塔中的底部液体的温度 不高于120℃。 并从蒸馏塔的底部排出的相分离塔底物。
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公开(公告)号：US5047561A
公开(公告)日：1991-09-10
申请号：US582158
申请日：1990-09-14
IPC分类号： C07D315/00
CPC分类号： C07D315/00
摘要： A process for producing a lactone by reacting in a hydrogenation reaction zone a dicarboxylic acid, a dicarboxylic acid anhydride and/or a dicarboxylic acid ester with hydrogen in a liquid phase using a solvent in the presence of a catalyst comprising ruthenium and an organic phosphine, which process comprises the following steps (1) to (6):(1) a first step of recovering the liquid phase from the hydrogenation reaction zone,(2) a second step of distilling the liquid phase in a first distillation column to obtain a first distillate and a first residue,(3) a third step of recycling the first residue to the hydrogenation reaction zone,(4) a fourth step of distilling a part of the first residue in a second distillation column to obtain a second distillate and a second residue,(5) a fifth step of recycling the second distillate to the hydrogenation reaction zone or the first distillation column, and(6) a sixth step of recovering a lactone from the first distillate.
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公开(公告)号：US5600034A
公开(公告)日：1997-02-04
申请号：US560637
申请日：1995-11-20
申请人： Tomoyuki Mori , Hiroshi Kameo , Shinji Isogai , Soichiro Saita
发明人： Tomoyuki Mori , Hiroshi Kameo , Shinji Isogai , Soichiro Saita
CPC分类号： C07C29/10
摘要： A method for producing allyl alcohols, which comprises heat-treating diallyl ethers in the presence of a catalyst containing a palladium compound and a phosphorus compound to convert them to allyl alcohols, wherein the heat treatment is conducted under such conversion reaction conditions that the value of function F represented by the following formula is within a range of 0.ltoreq.F
摘要翻译： 一种生产烯丙醇的方法，其包括在含有钯化合物和磷化合物的催化剂存在下将二烯丙基醚热处理以将其转化成烯丙醇，其中热处理在这样的转化反应条件下进行， 由下式表示的官能团F在0
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公开(公告)号：US5583271A
公开(公告)日：1996-12-10
申请号：US576599
申请日：1995-12-21
申请人： Tomoyuki Mori , Hiroshi Kameo , Shinji Isogai , Soichiro Saita
发明人： Tomoyuki Mori , Hiroshi Kameo , Shinji Isogai , Soichiro Saita
IPC分类号： B01J31/24 , C07C29/36 , C07C33/02 , C07C29/04 , C07C33/035
CPC分类号： B01J31/2404 , B01J31/1845 , B01J31/185 , B01J31/24 , C07C29/36 , C07C33/02 , B01J2231/32 , B01J2231/323 , B01J2531/824
摘要： A method for continuously producing alkadienols, which comprises subjecting a conjugated alkadiene and water to a hydration dimerization reaction in a continuous type reactor in the presence of carbon dioxide and a catalyst comprising a palladium compound and a phosphorus compound, wherein a hydrophobic phosphorus compound is used as the phosphorus compound, and the reaction is carried out in the presence of an amine while maintaining the concentration of the conjugated alkadiene in the reaction solution in the reactor within a range of from 0.5 to 4.5 wt %.
摘要翻译： 一种连续生产链二烯醇的方法，其包括在二氧化碳和包含钯化合物和磷化合物的催化剂存在下，在连续型反应器中使共轭二烯和水进行水合二聚反应，其中使用疏水性磷化合物 作为磷化合物，并且在胺的存在下进行反应，同时将反应器中的共轭二烯烃的浓度保持在0.5〜4.5重量％的范围内。
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公开(公告)号：US4410747A
公开(公告)日：1983-10-18
申请号：US276351
申请日：1981-06-11
IPC分类号： C07C17/02
CPC分类号： C07C17/02
摘要： In the technology for producing 1,2-dichloroethane by reacting ethylene with chlorine by a liquid phase reaction at 65.degree. to 160.degree. C. in 1,2-dichloroethane containing a metal chloride catalyst, there is a disadvantage of a side reaction for producing 1,1,2-trichloroethane etc. at a large ratio to cause lower yield of 1,2-dichloroethane. The present invention is to overcome the disadvantage and to produce 1,2-dichloroethane in high yield by reducing the side reaction by incorporating at least one of aromatic compounds selected from the group consisting of benzene type hydrocarbons having the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 respectively represent hydrogen atom, C.sub.1 -C.sub.5 alkyl group and chlorinated derivatives thereof as a side reaction inhibitor at a ratio of at least 0.001 wt. % in the reaction medium.
摘要翻译： PCT No.PCT / JP80 / 00330 Sec。 371日期：1981年6月11日 102（e）日期1981年6月11日PCT提交1980年12月26日PCT公布。 公开号WO82 / 02197 日本1982年7月8日。在通过液相反应在65℃至160℃下使乙烯与氯反应生产1,2-二氯乙烷的技术在含有金属氯化物催化剂的1,2-二氯乙烷中， 产生1,1,2-三氯乙烷等副反应的缺点是产生较大的1,2-二氯乙烷。 本发明克服了这个缺点，并通过并入至少一种选自具有下式的苯型烃的芳族化合物中的至少一种来降低副反应，从而高产率地生产1,2-二氯乙烷：其中R1， R2和R3分别表示作为副反应抑制剂的氢原子，C1-C5烷基及其氯化衍生物，其比例为至少0.001wt。 ％的反应介质。
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