PROCESS FOR PRODUCING A CHLORINATED C3-6 ALKANE
    5.
    发明申请
    PROCESS FOR PRODUCING A CHLORINATED C3-6 ALKANE 有权
    生产氯化C3-6烷烃的方法

    公开(公告)号:US20160107955A1

    公开(公告)日:2016-04-21

    申请号:US14882492

    申请日:2015-10-14

    IPC分类号: C07C17/02 C07C19/01

    摘要: Disclosed is a process for producing a chlorinated C3-6 alkane comprising providing a reaction mixture comprising an alkene and carbon tetrachloride in a principal alkylation zone to produce chlorinated C3-6 alkane in the reaction mixture, and extracting a portion of the reaction mixture from the principal alkylation zone, wherein: a) the concentration of the chlorinated C3-6 alkane in the reaction mixture in the principal alkylation zone is maintained at a level such that the molar ratio of chlorinated C3-6 alkane:carbon tetrachloride in the reaction mixture extracted from the alkylation zone does not exceed 95:5 when the principal alkylation zone is in continuous operation; and/or b) the reaction mixture extracted from the principal alkylation zone additionally comprises alkene and the reaction mixture is subjected to a dealkenation step in which at least about 50% or more by weight of the alkene present in the reaction mixture is extracted therefrom and at least about 50% of the extracted alkene is fed back into the reaction mixture provided in the principal alkylation zone; and/or c) the reaction mixture present in the principal alkylation zone and extracted from the principal alkylation zone additionally comprises a catalyst, and the reaction mixture extracted from the principal alkylation zone is subjected to an aqueous treatment step in which the reaction mixture is contacted with an aqueous medium in an aqueous treatment zone, a biphasic mixture is formed and an organic phase comprising catalyst is extracted from the biphasic mixture.

    摘要翻译: 公开了一种生产氯化C3-6烷烃的方法,包括在主要烷基化区提供包含烯烃和四氯化碳的反应混合物,以在反应混合物中产生氯化的C 3-6烷烃,并从反应混合物中提取一部分反应混合物 主要烷基化区,其中:a)主烷基化区中反应混合物中氯化C3-6烷烃的浓度维持在使得反应混合物中氯化C 3-6烷烃:四氯化碳的摩尔比提取 当主烷基化区连续运行时,烷基化区不超过95:5; 和/或b)从主要烷基化区提取的反应混合物另外包含烯烃,并且将反应混合物进行脱烯烃化步骤,其中提取反应混合物中存在的烯烃的至少约50重量%或更多, 将提取的烯烃的至少约50%反馈到主烷基化区提供的反应混合物中; 和/或c)主要烷基化区中存在并从主要烷基化区提取的反应混合物另外包含催化剂,并且从主烷基化区提取的反应混合物经受水处理步骤,其中反应混合物接触 与含水介质在水处理区中形成双相混合物,从双相混合物中提取含有催化剂的有机相。

    CATALYST AND PROCESS FOR OXYCHLORINATION OF ETHYLENE TO DICHLOROETHANE
    6.
    发明申请
    CATALYST AND PROCESS FOR OXYCHLORINATION OF ETHYLENE TO DICHLOROETHANE 审中-公开
    乙烯氧化二氯乙烯的催化剂和工艺

    公开(公告)号:US20160023191A1

    公开(公告)日:2016-01-28

    申请号:US14776819

    申请日:2014-03-17

    申请人: OXY VINYLS, LP

    发明人: Keith KRAMER

    摘要: In an oxychlorination process of the type where ethylene is converted to 1,2-dichloroethane in the presence of a supported copper catalyst, the improvement comprising: the use of a supported catalyst prepared by (i) impregnating, within a first step, an alumina support with a first aqueous solution including copper, an alkaline earth metal, and an alkali metal to thereby form a first catalyst component; and (ii) impregnating, within a subsequent step, the first catalyst component with a second aqueous solution including copper and alkaline earth metal, where the second aqueous solution is substantially devoid of alkali metal, to thereby form the supported catalyst.

    摘要翻译: 在负载型铜催化剂存在下将乙烯转化为1,2-二氯乙烷的类型的氧氯化方法中,改进包括:使用由(i)在第一步骤中浸渍氧化铝 用包含铜,碱土金属和碱金属的第一水溶液进行支撑,从而形成第一催化剂组分; 和(ii)在随后的步骤中,用包含铜和碱土金属的第二水溶液浸渍第一催化剂组分,其中第二水溶液基本上不含碱金属,从而形成负载型催化剂。

    PREPARATION METHOD FOR EDGE-FLUORINATED GRAPHITE VIA MECHANIC-CHEMICAL PROCESS
    9.
    发明申请
    PREPARATION METHOD FOR EDGE-FLUORINATED GRAPHITE VIA MECHANIC-CHEMICAL PROCESS 有权
    通过机械化学工艺制备边缘氟化石墨的制备方法

    公开(公告)号:US20150210616A1

    公开(公告)日:2015-07-30

    申请号:US14605716

    申请日:2015-01-26

    IPC分类号: C07C17/02

    摘要: Disclosed is & melted for producing edge-functionalized graphite or graphene with fluoro groups. According to the method, graphite is pulverized into smaller pieces and is then, allowed to react with a surrounding material containing fluorine or a fluorocarbon compound. The method enables the production of graphite or grapheme functionalized with fluoro groups, which could not be achieved by conventional mechanochemical methods. In addition, the method is carried out in a very simple and economical manner and is suitable for large-scale production.

    摘要翻译: 公开并熔化用于生产具有氟基团的边缘官能化石墨或石墨烯。 根据该方法,将石墨粉碎成较小的块,然后与包含氟或氟碳化合物的周围材料反应。 该方法能够生产用氟基官能化的石墨或石墨,这是通过常规的机械化学方法无法实现的。 此外,该方法以非常简单和经济的方式进行,并且适合于大规模生产。

    PARTIALLY HALOGENATED, HYDROXYLATED FULLERENE AND ALLERGEN ADSORBENT USING THE SAME
    10.
    发明申请
    PARTIALLY HALOGENATED, HYDROXYLATED FULLERENE AND ALLERGEN ADSORBENT USING THE SAME 审中-公开
    部分羟基化,羟基富勒烯和过敏吸附剂

    公开(公告)号:US20150011802A1

    公开(公告)日:2015-01-08

    申请号:US14495438

    申请日:2014-09-24

    IPC分类号: B01J20/22 C07C35/52

    摘要: Provided are a novel fullerene derivative which can adsorb quickly and efficiently an allergen which may cause a pollen allergy without releasing the allergen again, does not contain a metal or the like which may cause a harmful effect to a human body, and is easily applicable, impregnable, or chemically bondable onto surface of various materials: and a process for producing the same. The fullerene derivative is characterized in that a halogen group and many hydroxyl groups are bonded directly to a fullerene nucleus. In the case that the halogen group is chlorine, the fullerene derivative can be synthesized by a partial hydroxylation of a chlorinated fullerene or a partial chlorination of a hydroxylated fullerene.

    摘要翻译: 提供一种新颖的富勒烯衍生物,其可以快速且有效地吸附可能引起花粉过敏的过敏原,而不会再次释放过敏原,不含可能对人体产生有害影响的金属等,并且易于应用, 可浸渍或化学粘合到各种材料的表面上的方法及其制备方法。 富勒烯衍生物的特征在于卤素基团和许多羟基直接键合到富勒烯核上。 在卤素基团为氯的情况下,富勒烯衍生物可以通过氯化富勒烯的部分羟基化或羟基化富勒烯的部分氯化来合成。