摘要:
Polymeric foams having nanocellular morphology are formed from a polymeric material having structural units derived from 2-hydrocarbyl-3,3-bis(hydroxyphenyl)phthalimidine compound. The foams include a plurality of cells having an average diameter of less than 1 micron. Processes for forming the foams include melting a polymeric material having structural units derived from 2-hydrocarbyl-3,3-bis(hydroxyphenyl)phthalimidine compounds; diffusing a blowing agent into the polymeric material to form a mixture; nucleating bubbles in the mixture is at a sufficient temperature and pressure to enable the production of cells having an average diameter of less than 1 micron; stabilizing the cells; and forming the mixture into a desired shape.
摘要:
Polymeric foams having nanocellular morphology are formed from a polymeric material having structural units derived from 2-hydrocarbyl-3,3-bis(hydroxyphenyl)phthalimidine compound. The foams include a plurality of cells having an average diameter of less than 1 micron. Processes for forming the foams include melting a polymeric material having structural units derived from 2-hydrocarbyl-3,3-bis(hydroxyphenyl)phthalimidine compounds; diffusing a blowing agent into the polymeric material to form a mixture; nucleating bubbles in the mixture is at a sufficient temperature and pressure to enable the production of cells having an average diameter of less than 1 micron; stabilizing the cells; and forming the mixture into a desired shape.
摘要:
A foamable polymeric composition can comprise a polymer, a blowing agent cage material, and a blowing agent. The blowing agent cage material is selected from the group consisting of zeolite imidazolate framework, metal organic framework, carbon cage structure, and combinations comprising at least one of the foregoing. In one embodiment, the composition can be formed by mixing the polymer with the blowing agent cage material to form a mixture, introducing a blowing agent to the mixture, and forming the mixture into pellets.
摘要:
A foamable polymeric composition can comprise a polymer, a blowing agent cage material, and a blowing agent. The blowing agent cage material is selected from the group consisting of zeolite imidazolate framework, metal organic framework, carbon cage structure, and combinations comprising at least one of the foregoing. In one embodiment, the composition can be formed by mixing the polymer with the blowing agent cage material to form a mixture, introducing a blowing agent to the mixture, and forming the mixture into pellets.
摘要:
Disclosed herein is a foam that includes a polysiloxane block copolymer; the polysiloxane block copolymer including a first block that comprises a polysiloxane block and a second block that includes an organic polymer; the second block not containing a polysiloxane; the polysiloxane block being about 5 to about 45 repeat units; the foam having average pore sizes of less than or equal to about 100 nanometers.
摘要:
A multiwall sheet can comprise walls, wherein the walls include: a first wall; a second wall; and a transverse wall, wherein the first wall, the second wall, and the transverse wall extend longitudinally; and a rib extending between adjacent walls, wherein a layer is formed by two adjacent walls; wherein the layer is filled with a nanoporous foam material; and wherein the multiwall sheet comprises a normalized thermal conductivity value of less than or equal to 1.00 W·m/kg·K. A method of making a multiwall sheet can comprise coextruding the multiwall sheet described above with a nanoporous foam material; wherein the layer is filled with a nanoporous foam material during coextrusion.
摘要:
Disclosed herein is a foam that includes a polysiloxane block copolymer; the polysiloxane block copolymer including a first block that comprises a polysiloxane block and a second block that includes an organic polymer; the second block not containing a polysiloxane; the polysiloxane block being about 5 to about 45 repeat units; the foam having average pore sizes of less than or equal to about 100 nanometers.
摘要:
In one embodiment, the method for making a polymer article comprises: orienting polymer chains in one direction more than any other direction to form an oriented article, contacting the oriented article with a foaming agent, and foaming the material to form the reflective polymer article comprising planar cell structures having a length “l” and a thickness “t”.
摘要:
A method of making a reflective polymer article comprising: (a) contacting a polymer material with a foaming agent; (b) foaming in the material under conditions sufficient to form reflective polymer article having gas cells and polymer gas interfaces between the cells; wherein the reflective polymer article has a metallic or reflective property.
摘要:
A nano-cellular polymer foam is disclosed, which has an average pore size from about 10 nanometers to about 500 nanometers; and a foam density that is from about 1 percent to about 50 percent of the bulk density of the material of the nano-cellular foam.