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公开(公告)号：US20090156755A1
公开(公告)日：2009-06-18
申请号：US12328795
申请日：2008-12-05
CPC分类号： C08G77/50 , C08L83/04 , C08L83/14 , C09D183/04 , C09D183/14 , C08L83/00
摘要： Crosslinkable silicone coating compositions are prepared from (1) organopolysiloxanes containing alkenyl groups and containing per molecule at least one unit O3-n/2RnSi—Y(SiRnO3-n/2)a (I), at least 2 units R1RbSiO(3-b)/2 (II), and units RcSiO(4-c)/2 (III), where R is a monovalent, SiC-bonded organic radical having 1 to 30 C atoms free from aliphatic carbon-carbon multiple bonds, R1 is an alkenyl radical having 2 to 4 C atoms, and Y is a divalent or trivalent organic radical having 1 to 30 C atoms, with the proviso that the organopolysiloxanes (1) contain units (II) in amounts wherein the concentration of alkenyl radicals R1 is less than 2 meq/g, (2) organopolysiloxanes containing Si-bonded hydrogen atoms, (3) a hydrosilylation catalyst, and (4) optionally, inhibitors. The compositions cure rapidly with few extractables and are very useful in preparing release coatings.
摘要翻译： 可交联的硅氧烷涂料组合物由（1）含烯基的有机聚硅氧烷制备，每分子含有至少一个单位<？在线式描述=“在线式”末端=“铅”→O 3 -n / Y（SiRnO3-n / 2）a（I），<？in-line-formula description =“In-line formula”end =“tail”？>至少2个单位<？in-line-formula description =“In 线性公式“end =”lead“？> R1RbSiO（3-b）/ 2（II），<？in-line-formula description =”In-line Formulas“end =”tail“？> and units < -line-formula description =“In-line Formulas”end =“lead”？> RcSiO（4-c）/ 2（III），<？in-line-formula description =“In-line Formulas”end =“tail 其中R是不含脂肪碳 - 碳多重键的1至30个碳原子的一价SiC键合有机基团，R 1是具有2至4个C原子的烯基，Y是二价或三价有机基团 具有1至30个C原子，条件是有机聚硅氧烷（1）含有单元（II），其中烯基的浓度 R1小于2meq / g，（2）含有Si键合氢原子的有机聚硅氧烷，（3）氢化硅烷化催化剂和（4）任选的抑制剂。 组合物用很少的可萃取物快速固化，并且在制备脱模涂层中非常有用。
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公开(公告)号：US20100137544A1
公开(公告)日：2010-06-03
申请号：US12063312
申请日：2006-08-09
CPC分类号： C08G77/50
摘要： The invention relates to organopolysiloxane compounds containing per-molecule at least one structural unit of general formula (I) O3-a/2RaSi—Y(SiRaO3-a/2)b, wherein R can be identical or different and represents an organic monovalent SiC-bonded group which comprises from 1 to 30 carbon atoms and can contain one or several O atoms, a is 0 or 1 and b is an integer number ranging from 1 to 11.
摘要翻译： 本发明涉及含有每分子至少一个通式（I）O 3-a / 2RaSi-Y（SiRaO 3-a / 2）b的结构单元的有机聚硅氧烷化合物，其中R可以相同或不同，表示有机单价SiC 包含1至30个碳原子并且可以含有一个或几个O原子的键合基团，a是0或1，b是1至11的整数。
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3.发明授权公开(公告)号：US06764717B2
公开(公告)日：2004-07-20
申请号：US10298715
申请日：2002-11-18
IPC分类号： B05D102
CPC分类号： C08G77/50 , C09D183/04 , Y10T428/31663 , C08L83/00
摘要： Antimisting additives are used in crosslinkable silicone coating compositions for reducing aerosol formation, the antimisting additives being alkenyl-functional siloxane copolymers prepared by reacting a hydrocarbon containing at least three aliphatic double bonds, and with an organosiloxane (2) having terminal Si-bonded hydrogen atoms in the presence of a hydrosilylation catalyst (3) at a ratio of Si-bonded hydrogen to aliphatic double bonds of from 1.3 to 10, and subsequently reacting the resulting SiH-containing hydrocarbon-siloxane copolymer with an &agr;,&ohgr;-dialkenylsiloxane polymer (4) in the presence of a hydrosilylation catalyst (3) at a ratio of aliphatic double bonds to Si-bonded hydrogen of from 1.2 to 10, and optionally, in another step, equilibrating the resulting alkenyl-functional siloxane copolymers with an organopolysiloxane (5).
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4.发明授权Use of siloxane copolymers comprising alkenyl groups as antimisting additives in cross-linkable silicone coating compositions 失效在可交联硅氧烷涂料组合物中使用包含烯基作为防粘剂的硅氧烷共聚物公开(公告)号：US07153912B2
公开(公告)日：2006-12-26
申请号：US10506657
申请日：2003-02-20
IPC分类号： C08L83/04
CPC分类号： C08L83/14 , C08G77/12 , C08G77/18 , C08G77/20 , C08G77/50 , C08L83/04 , Y10T428/31663 , C08L83/00
摘要： Branched, alkenyl-functional organopolysiloxanes prepared by reacting an organic compound having at least two aliphatic double bonds with an organopolysiloxane having more than one Si-bonded hydrogen atom, in the presence of a hydrosilylation catalyst, and in a stoichiometric ratio of aliphatic double bonds to Si-bonded hydrogen such that an alkenyl-functional product is obtained, function as highly effective antimisting additives in the high speed coating of substrates with crosslinkable silicone compositions.
摘要翻译： 通过使具有至少两个脂族双键的有机化合物与具有多于一个Si键合的氢原子的有机聚硅氧烷在氢化硅烷化催化剂的存在下反应制备的支链烯基官能的有机聚硅氧烷，并且以化学计量比的脂族双键与 Si键合的氢，使得得到烯基官能产物，在具有可交联的有机硅组合物的基材的高速涂布中起到高效的防雾添加剂的作用。
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5.发明申请Use of siloxane copolymers comprising alkenyl groups as antimisting additives in cross-linkable silicone coating compositions 失效在可交联硅氧烷涂料组合物中使用包含烯基作为防粘剂的硅氧烷共聚物公开(公告)号：US20050208311A1
公开(公告)日：2005-09-22
申请号：US10506657
申请日：2003-02-20
IPC分类号： C08K5/00 , C08G77/20 , C08G77/50 , C08L83/04 , C08L83/05 , C08L83/07 , C08L83/14 , C09D183/04 , C09D183/05 , C09D183/07 , B32B9/04
CPC分类号： C08L83/14 , C08G77/12 , C08G77/18 , C08G77/20 , C08G77/50 , C08L83/04 , Y10T428/31663 , C08L83/00
摘要： Branched, alkenyl-functional organopolysiloxanes prepared by reacting an organic compound having at least two aliphatic double bonds with an organopolysiloxane having more than one Si-bonded hydrogen atom, in the presence of a hydrosilylation catalyst, and in a stoichiometric ratio of aliphatic double bonds to Si-bonded hydrogen such that an alkenyl-functional product is obtained, function as highly effective antimisting additives in the high speed coating of substrates with crosslinkable silicone compositions.
摘要翻译： 通过使具有至少两个脂族双键的有机化合物与具有多于一个Si键合的氢原子的有机聚硅氧烷在氢化硅烷化催化剂的存在下反应制备的支链烯基官能的有机聚硅氧烷，并且以化学计量比的脂族双键与 Si键合的氢，使得得到烯基官能产物，在具有可交联的有机硅组合物的基材的高速涂布中起到高效的防雾添加剂的作用。
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6.发明申请Branched organosilicon compounds as antimisting additives for silicone coating compositions 失效支链有机硅化合物作为有机硅涂料组合物的防霉添加剂公开(公告)号：US20050106399A1
公开(公告)日：2005-05-19
申请号：US10506656
申请日：2003-02-20
IPC分类号： B32B25/20 , C08G77/38 , C08L83/04 , C09D7/47 , C09D183/04
CPC分类号： C09D183/14 , Y10T428/31663
摘要： Branched organosilicon compounds bearing aliphatic multiple bonds, prepared by reacting a branched organosilicon compound having Si-bonded hydrogen atoms with an organosiloxane or organopolysiloxane having terminal aliphatic multiple bonds and optionally equilibrating with further organopolysiloxanes are useful as antimisting additives in the high speed coating of substrates with crosslinkable silicone compositions.
摘要翻译： 通过使具有Si键合氢原子的支链有机硅化合物与具有末端脂族多重键的有机硅氧烷或有机聚硅氧烷进一步与其它有机聚硅氧烷平衡而制备的带有脂肪族多键的支链有机硅化合物可用作基材高速涂层中的抗吸附添加剂， 可交联硅氧烷组合物。
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公开(公告)号：US07888446B2
公开(公告)日：2011-02-15
申请号：US12063312
申请日：2006-08-09
IPC分类号： C08G77/00
CPC分类号： C08G77/50
摘要： An organopolysiloxane compound containing per molecule at least one structural unit of the general formula O3-a/2RaSi—Y(SiRaO3-a/2)b (I) where R can be identical or different and denotes a monovalent SiC-bonded organic radical which has 1 to 30 C atoms and may contain one or more N and/or O atoms, Y is a divalent to dodecavalent organic radical which has 1 to 30 C atoms and may contain one or more O atoms, a is 0 or 1, and b is an integer from 1 to 11.
摘要翻译： 每分子含有至少一个通式O 3-a / 2RaSi-Y（SiRaO 3 -a / 2）b（I）的结构单元的有机聚硅氧烷化合物，其中R可以相同或不同，表示一价SiC键合的有机基团， 具有1至30个C原子并且可以含有一个或多个N和/或O原子，Y是具有1至30个C原子并且可以含有一个或多个O原子的二价至十价有机基团，a为0或1，以及 b为1〜11的整数。
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8.发明授权Branched organosilicon compounds as antimisting additives for silicone coating compositions 失效支链有机硅化合物作为有机硅涂料组合物的防霉添加剂公开(公告)号：US07135513B2
公开(公告)日：2006-11-14
申请号：US10506656
申请日：2003-02-20
IPC分类号： C08K5/5419
CPC分类号： C09D183/14 , Y10T428/31663
摘要： Branched organosilicon compounds bearing aliphatic multiple bonds, prepared by reacting a branched organosilicon compound having Si-bonded hydrogen atoms with an organosiloxane or organopolysiloxane having terminal aliphatic multiple bonds and optionally equilibrating with further organopolysiloxanes are useful as antimisting additives in the high speed coating of substrates with crosslinkable silicone compositions.
摘要翻译： 通过使具有Si键合氢原子的支链有机硅化合物与具有末端脂族多重键的有机硅氧烷或有机聚硅氧烷进一步与其它有机聚硅氧烷平衡而制备的带有脂肪族多键的支链有机硅化合物可用作基材高速涂层中的抗吸附添加剂， 可交联硅氧烷组合物。
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9.发明授权Alkenyl-functional siloxane copolymers as antimisting additives for silicone coating compositions 失效烯基官能硅氧烷共聚物作为有机硅涂料组合物的防霉添加剂公开(公告)号：US06956096B2
公开(公告)日：2005-10-18
申请号：US10797987
申请日：2004-03-11
IPC分类号： B05D7/24 , C08G77/50 , C09D183/04 , C09D183/05 , C09D183/07 , C09K3/18 , C08G77/04
CPC分类号： C08G77/50 , C09D183/04 , Y10T428/31663 , C08L83/00
摘要： Antimisting additives are used in crosslinkable silicone coating compositions for reducing aerosol formation, the antimisting additives being alkenyl-functional siloxane copolymers prepared by reacting a hydrocarbon containing at least three aliphatic double bonds, and with an organosiloxane (2) having terminal Si-bonded hydrogen atoms in the presence of a hydrosilylation catalyst (3) at a ratio of Si-bonded hydrogen to aliphatic double bonds of from 1.3 to 10, and subsequently reacting the resulting SiH-containing hydrocarbon-siloxane copolymer with an α,ω-dialkenylsiloxane polymer (4) in the presence of a hydrosilylation catalyst (3) at a ratio of aliphatic double bonds to Si-bonded hydrogen of from 1.2 to 10, and optionally, in another step, equilibrating the resulting alkenyl-functional siloxane copolymers with an organopolysiloxane (5).
摘要翻译： 抗变性添加剂用于可还原气溶胶形成的可交联硅氧烷涂料组合物中，抗反应添加剂是通过使含有至少三个脂族双键的烃反应制备的烯基官能硅氧烷共聚物和与具有末端Si键合的氢原子的有机硅氧烷（2） 在硅键合氢与脂族双键的比例为1.3至10的情况下，在氢化硅烷化催化剂（3）存在下，随后使所得含SiH的烃 - 硅氧烷共聚物与α，ω-二烯基硅氧烷聚合物（4 ）在氢化硅烷化催化剂（3）存在下，脂族双键与Si键合氢的比例为1.2至10，并且任选地，在另一步骤中，使所得烯基官能硅氧烷共聚物与有机聚硅氧烷（5）平衡， 。
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公开(公告)号：US20060058486A1
公开(公告)日：2006-03-16
申请号：US11219900
申请日：2005-09-06
申请人： Hans Lautenschlager
发明人： Hans Lautenschlager
CPC分类号： C08G77/20 , C09D183/04 , C08L83/00
摘要： Crosslinkable compositions prepared from (A) organopolysiloxanes containing alkenyl groups, of the general formula MVia Tb Dc DVid Me (I) where Mvi is a unit of the formula R1R2SiO1/2, T is a unit of the formula RSiO3/2, D is a unit of the formula R2SiO, Dvi is a unit of the formula R1RSiO, and M is a unit of the formula R3SiO1/2, R are monovalent, SiC-bonded, optionally substituted C1-18 hydrocarbon radicals free from aliphatic unsaturation, and R1 are monovalent, SiC-bonded C2-8 hydrocarbon radicals having a terminal aliphatic carbon-carbon double bond, a is on average 2.5 to 8, b is on average a-2, c is on average 41 to 1000, d is on average 0 to 4, and e is on average 0 to 2, with the proviso that a-2 Mvi units are attached directly to T units, (B) organosilicon compounds having Si-bonded hydrogen atoms, and (C) catalysts which promote the addition of Si-bonded hydrogen to aliphatic double bonds, have exceptional utility as abhesive coatings.
摘要翻译： 由（A）含有一般形式的烯基的有机聚硅氧烷制备的可交联的组合物
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