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    Process for the preparation of carbonic acid esters of polyester-polyols
    1.
    发明授权
    Process for the preparation of carbonic acid esters of polyester-polyols 失效
    聚酯多元醇碳酸酯的制备方法

    公开(公告)号：US4191705A

    公开(公告)日：1980-03-04

    申请号：US845174

    申请日：1977-10-25

    申请人： Christian Lindner ,  Carlhans Suling ,  Herbert Bartl ,  Manfred Schreckenberg ,  Dieter Freitag ,  Klaus Konig

    发明人： Christian Lindner ,  Carlhans Suling ,  Herbert Bartl ,  Manfred Schreckenberg ,  Dieter Freitag ,  Klaus Konig

    IPC分类号： C08G63/00 ,  C08G63/64 ,  C08G63/91 ,  C07C68/00 ,  C07C69/96

    CPC分类号： C08G63/64 ,  C08G63/916

    摘要： The present invention relates to a process for the preparation of carbonic acid esters of polyester-polyols by transesterifying the polyols with carbonic acid aryl esters at elevated temperatures under vacuum in the presence of a catalyst. The reaction conditions are controlled to avoid the formation of by-products and the chain extension of the polyester-polyols. The present invention is also concerned with the polyester carbonic acid esters so formed, their use in producing polycarbonate block copolymers and the copolymers so produced. The copolymers may be produced by transesterifying the polyester carbonic acid esters with bisphenols and subjecting the bis-hydroxyaryl carbonates so formed to normal polycarbonate synthesis such as interfacial or melt polycondensation.

    摘要翻译： 本发明涉及一种通过在催化剂存在下在真空下在升高的温度下将多元醇与碳酸芳酯酯交换而制备聚酯多元醇的碳酸酯的方法。 控制反应条件以避免副产物的形成和聚酯多元醇的链延长。 本发明还涉及如此形成的聚酯碳酸酯，它们在生产聚碳酸酯嵌段共聚物中的用途以及如此制备的共聚物。 共聚物可以通过将聚酯碳酸酯与双酚酯交换并使如此形成的双羟基芳基碳酸酯进行正常的聚碳酸酯合成如界面或熔融缩聚来制备。

    Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups and their use for the preparation of polyester-diol bis-diphenol carbonates and polyester/polycarbonates
    3.
    发明授权
    Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups and their use for the preparation of polyester-diol bis-diphenol carbonates and polyester/polycarbonates 失效
    通过碳酸酯基延长的聚酯二醇的碳酸芳酯的制备方法及其用于制备聚酯 - 二醇双二酚碳酸酯和聚酯/聚碳酸酯的用途

    公开(公告)号：US4297455A

    公开(公告)日：1981-10-27

    申请号：US910986

    申请日：1978-05-30

    申请人： Christian Lindner ,  Carlhans Suling ,  Herbert Bartl ,  Manfred Schreckenberg ,  Dieter Freitag ,  Klaus Konig

    发明人： Christian Lindner ,  Carlhans Suling ,  Herbert Bartl ,  Manfred Schreckenberg ,  Dieter Freitag ,  Klaus Konig

    IPC分类号： C08G63/64 ,  C08G63/00 ,  C08G63/76

    CPC分类号： C08G63/64

    摘要： The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups obtained according to the instant invention and their use for the preparation of polyester diol bis-diphenol carbonates, lengthened via carbonate groups, characterized in that polyester-diol bis-aryl carbonates are reacted with a diphenol at a temperature of from about 100.degree. to about 200.degree. C. in vacuo below about 35 mm Hg in the presence of a catalyst, wherein more than 1 mol of diphenol is employed per mol of carbonic acid aryl ester groups of the polyester-diol bis-aryl carbonate, lengthened via carbonate groups, and the resulting hydroxyaryl compound is distilled off.The invention finally relates to the polyester-diol bis-diphenol carbonates, lengthened via carbonate groups obtained according to the instant invention and their use for the preparation of polyester/polycarbonates and the polycarbonate/polyesters so prepared.

    摘要翻译： 本发明涉及通过-OCOO-基团延长的聚酯二醇的双碳酸芳基酯的制备方法，其特征在于分子量Mn（数均分子）超过250的聚酯二醇优选超过 600，在约100℃至200℃之间，优选约110℃至180℃之间的温度下，用碳酸双芳基酯加热，真空度低于约35mmHg，优选约25mm 和1mm Hg，在催化剂的存在下，每聚酯二醇的OH基和所形成的羟基芳基化合物使用少于1摩尔的碳酸双芳基酯。 本发明还涉及通过根据本发明获得的-OCOO-基团延长的聚酯二醇的双碳酸芳基酯及其用于制备通过碳酸酯基团延长的聚酯二醇双 - 二酚酚酸酯的用途，其特征在于 在催化剂存在下，聚酯 - 二醇双芳基碳酸酯与二酚在约100至约200℃的温度下在真空下在约35mm Hg下真空反应，其中每次使用多于1mol的二酚 将通过碳酸酯基延长的聚酯 - 二醇双芳基碳酸酯的碳酸芳基酯基和所得羟基芳基化合物蒸馏出。 本发明最终涉及通过根据本发明获得的碳酸酯基团延长的聚酯 - 二醇双 - 二酚碳酸酯及其制备聚酯/聚碳酸酯和如此制备的聚碳酸酯/聚酯的用途。

    Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups
    5.
    发明授权
    Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups 失效
    通过碳酸酯基团延长的聚酯二醇的碳酸芳酯的制备方法

    公开(公告)号：US4217297A

    公开(公告)日：1980-08-12

    申请号：US886212

    申请日：1978-03-13

    申请人： Christian Lindner ,  Carlhans Suling ,  Herbert Bartl ,  Manfred Schreckenberg ,  Dieter Freitag ,  Klaus Konig

    发明人： Christian Lindner ,  Carlhans Suling ,  Herbert Bartl ,  Manfred Schreckenberg ,  Dieter Freitag ,  Klaus Konig

    IPC分类号： C08G63/00 ,  C08G63/64 ,  C08G63/66 ,  C07C68/06 ,  C08G63/62

    CPC分类号： C08G63/64

    摘要： The present invention relates to a process for the preparation of bis-carbonic acid monoaryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per mol of OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups.

    摘要翻译： 本发明涉及通过-OCOO-基团来制备聚酯二醇的双碳酸单芳基酯的方法，其特征在于分子量Mn（数均分子）超过250的聚酯二醇优选超过 600，在约100℃至200℃之间，优选约110℃至180℃之间的温度下，用碳酸双芳基酯加热，真空度低于约35mmHg，优选约25mm 和1mm Hg，在催化剂的存在下，每摩尔聚酯二醇的OH基和所形成的羟基芳基化合物使用少于1摩尔的碳酸双芳基酯。 本发明还涉及通过-OCOO-基团延长的聚酯二醇的双碳酸芳基酯。

    High-molecular weight, segmented, polycarbonate elastomers
    8.
    发明授权
    High-molecular weight, segmented, polycarbonate elastomers 失效
    高分子量，分段，聚碳酸酯弹性体

    公开(公告)号：US4196276A

    公开(公告)日：1980-04-01

    申请号：US869743

    申请日：1978-01-16

    申请人： Manfred Schreckenberg ,  Klaus Konig ,  Dieter Freitag ,  Volker Serini

    发明人： Manfred Schreckenberg ,  Klaus Konig ,  Dieter Freitag ,  Volker Serini

    IPC分类号： C08G63/00 ,  C08G63/64 ,  C08G64/00 ,  C08G64/20 ,  C08G64/22 ,  C08G63/24

    CPC分类号： C08G63/64

    摘要： High-molecular weight polycarbonate elastomers are produced by reacting polymer segments having an average molecular weight (Mn) of more than 600 and carboxyl groups with diphenols and phosgene according to the two-phase boundary polycondensation process at a pH value between about 9 and about 14 and a temperature between about 0.degree. C. and 80.degree. C. and, thereafter, either heat-treating the resulting reaction products at temperatures between about 40.degree. C. and about 100.degree. C. or gelling the resulting reaction products in solution in organic solvents.

    摘要翻译： 高分子量聚碳酸酯弹性体是通过在约9和约14之间的pH值下，使平均分子量（Mn）大于600的聚合物链段和羧基与二酚和光气根据两相边界缩聚方法反应制备的 在约0℃至80℃之间的温度下，然后在约40℃至约100℃的温度下对所得反应产物进行热处理，或将所得反应产物在有机溶液中胶凝 溶剂。

    Process for the preparation of new high-molecular segmented polyester-polycarbonates which can be processed by thermoplastic methods and new polyester-polycarbonates obtained according to the process
    9.
    发明授权
    Process for the preparation of new high-molecular segmented polyester-polycarbonates which can be processed by thermoplastic methods and new polyester-polycarbonates obtained according to the process 失效
    用于制备可通过热塑性方法加工的新型高分子量聚酯多聚碳酸酯的方法和根据该方法获得的新型聚酯多元醇

    公开(公告)号：US4169868A

    公开(公告)日：1979-10-02

    申请号：US816567

    申请日：1977-07-18

    申请人： Manfred Schreckenberg ,  Klaus Konig ,  Dieter Freitag ,  Volker Serini

    发明人： Manfred Schreckenberg ,  Klaus Konig ,  Dieter Freitag ,  Volker Serini

    IPC分类号： C08G63/00 ,  C08G63/64 ,  C08G63/66 ,  C08G63/685 ,  C08G64/06 ,  C08G63/62 ,  C08G63/24

    CPC分类号： C08G63/64 ,  C08G63/66 ,  C08G64/06

    摘要： The subject of the present invention is a process for the preparation of new high-molecular weight polyester-polycarbonates which contain incorporated segments containing carboxyl groups and can be processed by thermoplastic methods, which process is characterized in that segments which contain carboxyl groups and have average molecular weights Mn (number-average of the molecular weight determined via the acid number of the segments containing carboxyl groups) of greater than about 600, preferably of greater than about 800 and in particular of between about 1,000 and 20,000, are reacted with diphenols and phosgene by the known two-phase boundary polycondensation process at a pH value of between about 9 and 14 and at a temperature of between about 0.degree. C. and 80.degree. C. and preferably of between about 15.degree. C. and 40.degree. C. and the resulting reaction products are either subjected to a heat treatment at temperatures of between about 40.degree. C. and 170.degree. C. for between about 5 minutes to 24 hours or are subjected, at temperatures of between about 130.degree. C., and 250.degree. C., to shear forces of between about 720 and 2520 kJ/kg of polymer or are gelled in solution by organic solvents. The invention also relates to the polyester-polycarbonates which are obtainable according to the invention and contain at least 2 phases, resulting from the polycarbonate constituent and the segment fraction which has terminal carboxyl groups.