-
公开(公告)号：US4191705A
公开(公告)日：1980-03-04
申请号：US845174
申请日：1977-10-25
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
CPC分类号： C08G63/64 , C08G63/916
摘要： The present invention relates to a process for the preparation of carbonic acid esters of polyester-polyols by transesterifying the polyols with carbonic acid aryl esters at elevated temperatures under vacuum in the presence of a catalyst. The reaction conditions are controlled to avoid the formation of by-products and the chain extension of the polyester-polyols. The present invention is also concerned with the polyester carbonic acid esters so formed, their use in producing polycarbonate block copolymers and the copolymers so produced. The copolymers may be produced by transesterifying the polyester carbonic acid esters with bisphenols and subjecting the bis-hydroxyaryl carbonates so formed to normal polycarbonate synthesis such as interfacial or melt polycondensation.
摘要翻译： 本发明涉及一种通过在催化剂存在下在真空下在升高的温度下将多元醇与碳酸芳酯酯交换而制备聚酯多元醇的碳酸酯的方法。 控制反应条件以避免副产物的形成和聚酯多元醇的链延长。 本发明还涉及如此形成的聚酯碳酸酯，它们在生产聚碳酸酯嵌段共聚物中的用途以及如此制备的共聚物。 共聚物可以通过将聚酯碳酸酯与双酚酯交换并使如此形成的双羟基芳基碳酸酯进行正常的聚碳酸酯合成如界面或熔融缩聚来制备。
-
2.发明授权Process for the preparation of carbonic acid bis-diphenol esters of polyester-diols and their use for the preparation of high-molecular segmented polyester/polycarbonates which can be processed as thermoplastics 失效制备聚酯二醇的碳酸双二酚酯的方法及其用于制备高分子链段的聚酯/聚碳酸酯的方法，其可加工成热塑性塑料
公开(公告)号：US4216298A
公开(公告)日：1980-08-05
申请号：US909321
申请日：1978-05-24
申请人： Manfred Schreckenberg , Dieter Freitag , Christian Lindner , Carlhans Suling , Herbert Bartl , Klaus Konig
发明人： Manfred Schreckenberg , Dieter Freitag , Christian Lindner , Carlhans Suling , Herbert Bartl , Klaus Konig
CPC分类号： C08G63/916 , C08G63/64
摘要： The present invention relates to the transesterification of the carbonic acid aryl esters prepared according to German Published Patent Specification 2,651,639 (which corresponds to U.S. Patent application Ser. No. 854,174, filed Oct. 25, 1977) with an excess of diphenol for the preparation of polyester-diol bis-diphenol carbonate. The present invention further relates to the polyester-diol bis-diphenol carbonates obtained according to the invention and their use for the preparation of polyester/polycarbonates and to the polyester/polycarbonates so prepared.
摘要翻译： 本发明涉及根据德国公开专利说明书2,651,639（其对应于1977年10月25日提交的美国专利申请序列号854,174）制备的碳酸芳酯与过量的二酚制备的碳酸芳酯的酯交换反应， 聚酯二醇双二酚碳酸酯。 本发明还涉及根据本发明获得的聚酯 - 二醇双 - 二酚碳酸酯及其制备聚酯/聚碳酸酯和如此制备的聚酯/聚碳酸酯的用途。
-
3.发明授权Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups and their use for the preparation of polyester-diol bis-diphenol carbonates and polyester/polycarbonates 失效通过碳酸酯基延长的聚酯二醇的碳酸芳酯的制备方法及其用于制备聚酯 - 二醇双二酚碳酸酯和聚酯/聚碳酸酯的用途
公开(公告)号：US4297455A
公开(公告)日：1981-10-27
申请号：US910986
申请日：1978-05-30
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
CPC分类号： C08G63/64
摘要： The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups obtained according to the instant invention and their use for the preparation of polyester diol bis-diphenol carbonates, lengthened via carbonate groups, characterized in that polyester-diol bis-aryl carbonates are reacted with a diphenol at a temperature of from about 100.degree. to about 200.degree. C. in vacuo below about 35 mm Hg in the presence of a catalyst, wherein more than 1 mol of diphenol is employed per mol of carbonic acid aryl ester groups of the polyester-diol bis-aryl carbonate, lengthened via carbonate groups, and the resulting hydroxyaryl compound is distilled off.The invention finally relates to the polyester-diol bis-diphenol carbonates, lengthened via carbonate groups obtained according to the instant invention and their use for the preparation of polyester/polycarbonates and the polycarbonate/polyesters so prepared.
摘要翻译： 本发明涉及通过-OCOO-基团延长的聚酯二醇的双碳酸芳基酯的制备方法，其特征在于分子量Mn（数均分子）超过250的聚酯二醇优选超过 600，在约100℃至200℃之间，优选约110℃至180℃之间的温度下，用碳酸双芳基酯加热，真空度低于约35mmHg，优选约25mm 和1mm Hg，在催化剂的存在下，每聚酯二醇的OH基和所形成的羟基芳基化合物使用少于1摩尔的碳酸双芳基酯。 本发明还涉及通过根据本发明获得的-OCOO-基团延长的聚酯二醇的双碳酸芳基酯及其用于制备通过碳酸酯基团延长的聚酯二醇双 - 二酚酚酸酯的用途，其特征在于 在催化剂存在下，聚酯 - 二醇双芳基碳酸酯与二酚在约100至约200℃的温度下在真空下在约35mm Hg下真空反应，其中每次使用多于1mol的二酚 将通过碳酸酯基延长的聚酯 - 二醇双芳基碳酸酯的碳酸芳基酯基和所得羟基芳基化合物蒸馏出。 本发明最终涉及通过根据本发明获得的碳酸酯基团延长的聚酯 - 二醇双 - 二酚碳酸酯及其制备聚酯/聚碳酸酯和如此制备的聚碳酸酯/聚酯的用途。
-
4.发明授权Process for the preparation of carbonic acid bis-diphenol esters of polyalkylene oxide-diols lengthened via carbonate groups and their use for the preparation of high-molecular, segmented polyether/polycarbonates which can be processed as thermoplastics 失效通过碳酸酯基加成的聚环氧烷 - 二醇的碳酸双 - 二酚酯的制备方法及其用于制备高分子，分段聚醚/聚碳酸酯的方法，可以加工成热塑性塑料
公开(公告)号：US4217437A
公开(公告)日：1980-08-12
申请号：US913773
申请日：1978-06-08
申请人： Manfred Schreckenberg , Dieter Freitag , Christian Lindner , Carlhans Suling , Herbert Bartl , Klaus Konig
发明人： Manfred Schreckenberg , Dieter Freitag , Christian Lindner , Carlhans Suling , Herbert Bartl , Klaus Konig
IPC分类号： C08G63/00 , B01J31/00 , C07B61/00 , C07C67/00 , C07C69/96 , C07C313/00 , C07C315/04 , C07C317/22 , C07C319/20 , C07C323/20 , C08G64/00 , C08G64/16 , C08G64/18 , C08G64/20 , C08G64/22 , C08G64/24 , C08G64/30 , C08G63/62
CPC分类号： C08G64/183
摘要： The present invention relates to the transesterification of the carbonic acid aryl esters obtainable according to German Published Patent Specification No. 2,650,533 with an excess of diphenol for the preparation of polyalkylene oxide-diol bis-diphenol carbonates lengthened via carbonate groups. The present invention also relates to the polyalkylene oxide-diol bis-diphenol carbonates, lengthened via carbonate groups, obtained according to the invention and their use for the preparation of polyether/polycarbonates. Finally, the present invention relates to the polyether/polycarbonates, obtained according to the invention, with an improved phase separation between the elastomeric segment and hard segment, which leads to better technological properties of the corresponding polycarbonate elastomers.
摘要翻译： 本发明涉及根据德国公开专利说明书2,650,533可得到的碳酸芳基酯与过量的二酚的酯交换反应，用于制备通过碳酸酯基团延长的聚亚烷基氧化物 - 二醇双酚酚碳酸酯。 本发明还涉及根据本发明获得的通过碳酸酯基延长的聚环氧烷 - 二醇双 - 二酚碳酸酯及其在制备聚醚/聚碳酸酯中的用途。 最后，本发明涉及根据本发明获得的聚醚/聚碳酸酯，其在弹性链段和硬链段之间具有改进的相分离，这导致相应的聚碳酸酯弹性体的更好的技术性能。
-
5.发明授权Process for the preparation of carbonic acid aryl esters of polyester-diols lengthened via carbonate groups 失效通过碳酸酯基团延长的聚酯二醇的碳酸芳酯的制备方法
公开(公告)号：US4217297A
公开(公告)日：1980-08-12
申请号：US886212
申请日：1978-03-13
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
CPC分类号： C08G63/64
摘要： The present invention relates to a process for the preparation of bis-carbonic acid monoaryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per mol of OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups.
摘要翻译： 本发明涉及通过-OCOO-基团来制备聚酯二醇的双碳酸单芳基酯的方法，其特征在于分子量Mn（数均分子）超过250的聚酯二醇优选超过 600，在约100℃至200℃之间，优选约110℃至180℃之间的温度下，用碳酸双芳基酯加热，真空度低于约35mmHg，优选约25mm 和1mm Hg，在催化剂的存在下，每摩尔聚酯二醇的OH基和所形成的羟基芳基化合物使用少于1摩尔的碳酸双芳基酯。 本发明还涉及通过-OCOO-基团延长的聚酯二醇的双碳酸芳基酯。
-
6.发明授权
公开(公告)号：US4267303A
公开(公告)日：1981-05-12
申请号：US070072
申请日：1979-08-27
摘要： This disclosure is concerned with a single step process for the production of diphenol terminated polycarbonates by the transesterification of diphenols, bis-aryl carbonates and polymeric diols with aliphatically bound terminal hydroxyl groups. These diols are selected from polyesters, polyethers, polythioethers and polyacetals. The transesterification is carried out at elevated temperatures under vacuum optionally in the presence of a catalyst with the ratios of the reactants being such as to avoid the retention of any terminal aliphatic hydroxyl groups or aryl carbonate groups.
摘要翻译： 本公开涉及通过二酚，双芳基碳酸酯和聚合二醇与脂族结合的末端羟基的酯交换来生产二苯酚封端的聚碳酸酯的单步方法。 这些二醇选自聚酯，聚醚，聚硫醚和聚缩醛。 酯交换反应在真空下在升高的温度下进行，任选地在催化剂存在下进行，其中反应物的比例为避免保留任何末端脂族羟基或芳基碳酸酯基团。
-
7.发明授权
公开(公告)号：US4192940A
公开(公告)日：1980-03-11
申请号：US924708
申请日：1978-07-14
摘要： Polyesters containing carbonate groups and consisting of repeating structural units corresponding to the general formula ##STR1## in which X is the residue of a reaction product of a polyhydric alcohol with a polybasic aliphatic carboxylic acid having a molecular weight of from 800 to 3500,X' has the same meaning as X or represents the residue of an aliphatic polyether having a molecular weight of from 800 to 3500,n=0 or 1 to 10 andm=is a number >20,the intrinsic viscosity in tetrahydrofuran being from 0.8 to 2.5 dl/g.
摘要翻译： 含有碳酸酯基团并由对应于通式（I）的重复结构单元组成的聚酯，其中X是多元醇与分子量为800至3500的多元脂肪族羧酸的反应产物的残基 X'与X相同或表示分子量为800〜3500，n = 0或1〜10的脂肪族聚醚的残基，m = 20以上，四氢呋喃中的特性粘度来自 0.8〜2.5dl / g。
-
公开(公告)号：US4395517A
公开(公告)日：1983-07-26
申请号：US274545
申请日：1981-06-17
IPC分类号： C08F291/00 , C08F255/00 , C08F283/00 , C08F283/02 , C08L75/06 , C08L67/00 , C08L69/00
CPC分类号： C08F283/00 , C08F255/00
摘要： Modified olefine polymers of 20 to 98 parts by weight of an olefine homopolymer or copolymer and 0.5 to 80 parts by weight of a polymer containing aliphatic polyester blocks, which polymers are chemically linked through 0.5 to 40 parts by weight of a polymer of a monomer containing olefinic double bonds, a method for their manufacture, and their employment as moulding compositions.
摘要翻译： 20至98重量份的烯烃均聚物或共聚物的改性烯烃聚合物和0.5至80重量份的含有脂族聚酯嵌段的聚合物，该聚合物通过0.5至40重量份的含有 烯属双键，其制造方法和作为模塑组合物的用途。
-
9.发明授权Cellulose ester-aliphatic polycarbonate thermoplastic moulding compositions 失效纤维素酯 - 脂族聚碳酸酯热塑性成型组合物
公开(公告)号：US4506045A
公开(公告)日：1985-03-19
申请号：US532238
申请日：1983-09-14
CPC分类号： C08L1/10 , C08L69/00 , Y10S525/932
摘要： Thermoplastic moulding compositions consisting of from 1 to 99% by weight of at least one cellulose ester or cellulose mixed ester, from 99 to 1% by weight of an aliphatic polyester or polyether containing carbonate groups and, optionally, standard auxiliaries and additives.
摘要翻译： 由1至99重量％的至少一种纤维素酯或纤维素混合酯，99至1重量％的含有碳酸酯基团的脂族聚酯或聚醚或任选的标准助剂和添加剂组成的热塑性模塑组合物。
-
公开(公告)号：US4272428A
公开(公告)日：1981-06-09
申请号：US41546
申请日：1979-05-23
IPC分类号： C08L27/00 , C08K5/10 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L23/28 , C08L27/06 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L69/00 , C08L101/00 , C08K5/04
CPC分类号： C08L27/06 , C08L69/005 , C08L69/00
摘要： A thermoplastic molding composition contains a mixture of 10 to 95% by weight of a vinyl chloride polymer and 90 to 5% by weight of an adipate/carbonate mixed ester which is the transesterification reaction product of an adipate-diol polyester having terminal hydroxyls and a bifunctional carbonic acid aryl ester. The composition has a favorable combination of physical properties which include good cold fracture behavior coupled with easy processability and good ageing characteristics.
摘要翻译： 热塑性模塑组合物包含10至95重量％的氯乙烯聚合物和90至5重量％的己二酸酯/碳酸酯混合酯的混合物，其为具有末端羟基的己二酸酯 - 二醇聚酯和具有末端羟基的酯交换反应产物 双功能碳酸芳酯。 该组合物具有良好的物理性质的组合，其包括良好的冷断裂行为以及易加工性和良好的老化特性。
-
-
-
-
-
-
-
-
-
搜索结果
79 条记录 (耗时 0.026 秒)
