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    Process and unit for hydrotreating a petroleum feedstock that comprises the cracking of ammonia and the recycling of hydrogen in the unit
    1.
    发明授权
    Process and unit for hydrotreating a petroleum feedstock that comprises the cracking of ammonia and the recycling of hydrogen in the unit 失效
    用于加氢处理石油原料的方法和单元，其包括氨的裂解和氢气在单元中的再循环

    公开(公告)号：US6096195A

    公开(公告)日：2000-08-01

    申请号：US138547

    申请日：1998-08-24

    申请人： Christian Streicher ,  Fabrice Lecomte ,  Christian Busson

    发明人： Christian Streicher ,  Fabrice Lecomte ,  Christian Busson

    IPC分类号： C10G49/00 ,  C10G49/22 ,  C10G45/02

    CPC分类号： C10G49/007 ,  C10G49/22

    摘要： Described in a process for hydrotreating (HDT) a petroleum feedstock (1) that contains sulfur and nitrogen are the catalytic cracking of the ammonia, produced by the hydrotreating process, in a catalytic cracking furnace (F), the cooling (E2) and separating of the cracking effluent to produce an H.sub.2 S containing gas phase, the extraction of the hydrogen sulfide from said gas phase and from the hydrotreating purge gas in an amine washing unit (20), and the separation (SM) of the hydrogen from the resultant effluent. The recovered hydrogen is recycled to hydrotreating unit (HDT) via a pipe (17).

    摘要翻译： 在加氢处理（HDT）的方法中，含有硫和氮的石油原料（1）是在催化裂化炉（F），冷却（E2）和分离中由加氢处理方法产生的氨的催化裂化 的裂解流出物以产生含H 2 S的气相，从胺洗涤单元（20）中从所述气相和加氢处理净化气体中提取硫化氢以及从所得流出物中分离（SM）氢 。 回收的氢气通过管道（17）再循环到加氢处理装置（HDT）中。

    Method and device for processing a gas containing hydrogen sulfide and sulfur dioxide comprising a stage of removal of by-products
    2.
    发明授权
    Method and device for processing a gas containing hydrogen sulfide and sulfur dioxide comprising a stage of removal of by-products 失效
    用于处理含有硫化氢和二氧化硫的气体的方法和装置，包括除去副产物的阶段

    公开(公告)号：US06872368B2

    公开(公告)日：2005-03-29

    申请号：US09902104

    申请日：2001-07-11

    申请人： Fabrice Lecomte ,  Christian Streicher ,  Cécile Barrere-Tricca

    发明人： Fabrice Lecomte ,  Christian Streicher ,  Cécile Barrere-Tricca

    IPC分类号： C01B17/04 ,  B01D53/86 ,  C01B17/05 ,  B01J8/00

    CPC分类号： B01D53/8615 ,  C01B17/05

    摘要： A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone downstream of the contacting stage. In order to remove by-products resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from after the contacting stage. The liquid fraction F is sent to a processing stage distinct from the contacting stage where the liquid fraction F is heated to a temperature at least partially crystallizing the by-products, and the at least partially crystallized by-products separated from the rest of the liquid fraction F containing at least solvent. At least a stream F1 comprising solvent, catalyst and sulfur and substantially free of the by-products and a stream F2 mostly comprising the by-products are recovered.

    摘要翻译： 一种用于处理至少包含硫化氢（H 2 S）和至少二氧化硫（SO 2）的气体的方法，包括以下步骤：在接触阶段使气体与含有至少一种催化剂的液体溶剂接触，回收基本上不含 硫化氢和来自接触阶段的二氧化硫，并且在接触阶段下游的倾析区中将液体硫与液体溶剂分离。 为了除去由催化剂的降解引起的副产物，从接触阶段后提取至少含有溶剂，催化剂，硫和由催化剂降解引起的固体副产物的液体馏分F. 液体馏分F被送至不同于液体馏分F被加热至至少部分使副产物结晶的温度的接触阶段的处理阶段，并且至少部分结晶的副产物与其余液体分离 含有至少溶剂的馏分F. 回收至少包含溶剂，催化剂和硫并基本上不含副产物的流F1和主要包含副产物的料流F2。

    Removal of by-products in method for processing a gas containing hydrogen sulfide and sulfur dioxide
    3.
    发明授权
    Removal of by-products in method for processing a gas containing hydrogen sulfide and sulfur dioxide 有权
    在含有硫化氢和二氧化硫的气体的处理方法中除去副产物

    公开(公告)号：US06280698B1

    公开(公告)日：2001-08-28

    申请号：US09444847

    申请日：1999-11-22

    申请人： Fabrice Lecomte ,  Christian Streicher ,  Cécile Barrere-Tricca

    发明人： Fabrice Lecomte ,  Christian Streicher ,  Cécile Barrere-Tricca

    IPC分类号： C01B1704

    CPC分类号： B01D53/8615 ,  C01B17/05

    摘要： A method for processing a gas, such as a Claus tail gas, containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent, such as polyethylene glycol, containing at least one catalyst, such as sodium salicylate, in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone beneath the contacting stage. In order to remove by-products, such as sulfate and thiosulfate salts, resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from the contacting stage and sent to a processing stage distinct from the contacting stage where the liquid fraction F is heated to a temperature sufficient to at least partially crystallize the by-products, and the crystallized by-products are separated from the rest of the liquid fraction F containing at least solvent. At least a stream F1 comprising solvent, catalyst and sulfur and substantially free of the by-products and a stream F2 mostly comprising the by-products are recovered.

    摘要翻译： 至少含有硫化氢（H2S）和至少二氧化硫（SO2）的克劳斯尾气处理气体的方法包括以下步骤：使气体与液体溶剂如聚乙二醇接触， 至少一种催化剂，如水杨酸钠，在接触阶段，从接触阶段回收基本上不含硫化氢并且不含二氧化硫的气态流出物，以及在接触阶段下方的倾析区域中将液体硫与液体溶剂分离。 为了除去由催化剂降解而产生的副产物如硫酸盐和硫代硫酸盐，至少含有溶剂，催化剂，硫和由催化剂降解引起的固体副产物的液体馏分F从 接触阶段并送到与将液体馏分F加热至足以至少部分地使副产物结晶的温度的接触阶段不同的处理阶段，并且将结晶的副产物与液体馏分F的其余部分分离 至少含有溶剂。 回收至少包含溶剂，催化剂和硫并基本上不含副产物的流F1和主要包含副产物的料流F2。

    Method and device for processing a gas containing hydrogen sulfide and sulfur dioxide, comprising a stage of removal of solid by-products
    4.
    发明授权
    Method and device for processing a gas containing hydrogen sulfide and sulfur dioxide, comprising a stage of removal of solid by-products 有权
    用于处理含有硫化氢和二氧化硫的气体的方法和装置，包括除去固体副产物的阶段

    公开(公告)号：US06277352B1

    公开(公告)日：2001-08-21

    申请号：US09413889

    申请日：1999-10-07

    申请人： Fabrice Lecomte ,  Christian Streicher ,  Daniel Benayoun ,  Cecile Barrere-Tricca

    发明人： Fabrice Lecomte ,  Christian Streicher ,  Daniel Benayoun ,  Cecile Barrere-Tricca

    IPC分类号： B01D5350

    CPC分类号： B01D53/523 ,  B01D53/8615 ,  C01B17/0205 ,  C01B17/033 ,  C01B17/05

    摘要： A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent, such as polyethylene glycol, containing at least one catalyst, such as sodium salicylate, in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products such as alkali metal or alkaline earth metal sulfates or thiosulfates, resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F, comprising most of the solid by-products and a stream F2 mostly comprising solvent nearly free of the solid by-products from the processing stage.

    摘要翻译： 至少包含硫化氢（H 2 S）和至少二氧化硫（SO 2）的气体的处理方法包括以下阶段：将气体与液体溶剂如聚乙二醇接触，所述液体溶剂含有至少一种催化剂，例如钠 水杨酸盐在接触阶段回收基本上不含硫化氢和二氧化硫的气态流出物，以及含有液体硫，液体溶剂和固体副产物如碱金属或碱土金属硫酸盐或硫代硫酸盐的混合物，由 催化剂降解，在倾析区中将液态硫与液体溶剂分离，从倾析区内的液体溶剂和液态硫之间的层中提取至少含有固体副产物的液体馏分F，将液体 馏分F到与接触阶段不同的处理阶段，并且回收至少一个流F，其包含大部分固体副产物和流浆 m F2主要包括几乎不含处理阶段固体副产物的溶剂。

    Method and device for processing a gas containing hydrogen sulfide and sulfut dioxide comprising a stage of removal of solid by-products
    5.
    发明授权
    Method and device for processing a gas containing hydrogen sulfide and sulfut dioxide comprising a stage of removal of solid by-products 失效
    包含硫化氢和二氧化硫的气体的处理方法和装置，包括除去固体副产物的阶段

    公开(公告)号：US06872367B2

    公开(公告)日：2005-03-29

    申请号：US09897464

    申请日：2001-07-03

    申请人： Fabrice Lecomte ,  Christian Streicher ,  Daniel Benayoun ,  Cécile Barrere-Tricca

    发明人： Fabrice Lecomte ,  Christian Streicher ,  Daniel Benayoun ,  Cécile Barrere-Tricca

    IPC分类号： B01D53/50 ,  B01D53/52 ,  B01D53/77 ,  B01D53/86 ,  C01B17/02 ,  C01B17/033 ,  C01B17/04 ,  C01B17/05 ,  B01J8/00

    CPC分类号： B01D53/523 ,  B01D53/8615 ,  C01B17/0205 ,  C01B17/033 ,  C01B17/05

    摘要： A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F1 comprising most of the solid by-products and a stream F2 mostly comprising solvent nearly free of the solid by-products from the processing stage.

    摘要翻译： 一种用于处理至少包含硫化氢（H 2 S）和至少二氧化硫（SO 2）的气体的方法包括以下阶段：在接触阶段使气体与含有至少一种催化剂的液体溶剂接触，基本上回收气态流出物 不含硫化氢和不含二氧化硫的混合物，以及含有液体硫，液体溶剂和由催化剂降解而产生的固体副产物的混合物的混合物，在倾析区中将液体硫与液体溶剂分离，提取含有 至少来自液体溶剂和倾析区中的液体硫之间的层的固体副产物，将液体馏分F送至与接触阶段不同的处理阶段，并回收至少一种包含大部分固体的流F1 副产物和主要包含来自处理阶段的几乎不含固体副产物的溶剂的流F2。

    Method for processing a natural gas with extraction of the solvent contained in the acid gases
    7.
    发明授权
    Method for processing a natural gas with extraction of the solvent contained in the acid gases 失效
    通过萃取酸性气体中所含的溶剂来处理天然气的方法

    公开(公告)号：US07459011B2

    公开(公告)日：2008-12-02

    申请号：US11057011

    申请日：2005-02-14

    申请人： Renaud Cadours ,  Fabrice Lecomte ,  Lionel Magna ,  Cécile Barrere-Tricca

    发明人： Renaud Cadours ,  Fabrice Lecomte ,  Lionel Magna ,  Cécile Barrere-Tricca

    IPC分类号： B01D53/14

    CPC分类号： C10L3/10

    摘要： The natural gas arriving through pipe 1 is deacidified by being brought into contact with a solvent in zone C. The solvent charged with acid compounds is regenerated in zone R. The acid gases, released into pipe 5 upon regeneration, include a quantity of solvent. The method enables the solvent contained in the acid gases to be extracted. In zone ZA, the acid gases are brought into contact with a non-aqueous ionic liquid whose general formula is Q+ A−, where Q+ designates an ammonium, phosphonium, and/or sulfonium cation, and A− designates an anion able to form a liquid salt. The solvent is removed from the acid gases evacuated through pipe 6. The ionic liquid charged with solvent is regenerated by heating in an evaporator DE. The ionic liquid regenerated is recycled through pipes 8 and 9 to zone ZA. The solvent is evacuated through pipe 13.

    摘要翻译： 通过管道1到达的天然气通过与区域C中的溶剂接触而脱酸。在酸性化合物中加入的溶剂在区域R中再生。再生时释放到管道5中的酸性气体包括一定量的溶剂。 该方法能够提取酸性气体中所含的溶剂。 在区域ZA中，酸性气体与通式为Q + A-的非水性离子液体接触，其中Q +表示铵，鏻和/或锍阳离子，A-表示能形成 液体盐 从通过管道6排出的酸性气体中除去溶剂。加入溶剂的离子液体通过在蒸发器DE中加热而再生。 再生的离子液体通过管道8和9循环到区域ZA。 溶剂通过管13排出。

    Method of collecting mercaptans contained in a gaseous feed
    10.
    发明授权
    Method of collecting mercaptans contained in a gaseous feed 有权
    收集气态饲料中所含硫醇的方法

    公开(公告)号：US07192565B2

    公开(公告)日：2007-03-20

    申请号：US11194557

    申请日：2005-08-02

    申请人： Patrick Briot ,  Renaud Cadours ,  Sophie Drozdz ,  Fabrice Lecomte

    发明人： Patrick Briot ,  Renaud Cadours ,  Sophie Drozdz ,  Fabrice Lecomte

    IPC分类号： B01D53/48 ,  C01B17/20

    CPC分类号： C10L3/10

    摘要： The gaseous feed flowing in through line 1 is contacted in contacting zone ZA with a liquid solvent flowing in through line 2. The solvent comprises between 0.001% and 100% by weight of a liquid olefin. Contacting in zone ZA is carried out in the presence of an acid catalyst. The purified gaseous feed is discharged from zone ZA through line 3. The sulfide-laden solvent is discharged through line 4, then regenerated in unit RE. The regenerated solvent is recycled through lines 7 and 2 to zone ZA.

    摘要翻译： 通过管线1流动的气态进料在接触区ZA中与通过管线2流动的液体溶剂接触。溶剂包含0.001至100重量％的液体烯烃。 ZA区在酸催化剂存在下进行接触。 纯化的气体进料通过管线3从区域ZA排出。含硫化物的溶剂通过管线4排出，然后在单元RE中再生。 再生的溶剂通过管线7和2再循环到区域ZA。