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公开(公告)号：US20110142747A1
公开(公告)日：2011-06-16
申请号：US12637301
申请日：2009-12-14
申请人： Gary J. Nagl , Anthony A. Barnette , Myron Reicher
发明人： Gary J. Nagl , Anthony A. Barnette , Myron Reicher
IPC分类号： C01B17/033 , G05D9/00
CPC分类号： B01D17/0214 , B01D17/0208 , B01D19/0063 , C01B17/0205
摘要： A liquid separator system having a gas phase zone, an aqueous phase zone and a denser liquid zone is used to separate mixtures of fluids. The separator can be used for separating molten sulfur from liquid redox solution or reslurry water. The system includes a vessel with a top part and a bottom part. The vessel has a larger diameter at the top part than at the bottom part. The system also includes an inlet for introducing a redox solution or reslurry water and molten sulfur, which is denser than redox solution or reslurry water, into the vessel. An outlet near the bottom part of the vessel allows a flow of the molten sulfur from the vessel. An interface control structure senses an interface level between the redox solution or reslurry water and the molten sulfur, and the interface control structure controls the flow of molten sulfur from the outlet. The interface control structure is adjusted to optimally alter the vertical height of the interface level within the vessel so that the residence time of the molten sulfur in the vessel does not decrease as the sulfur production throughput decreases, and so that the interface area of the molten sulfur and the redox solution is reduced as the sulfur throughput decreases. A pressure controller monitors the pressure in the vessel and adds or removes gas from a gas phase zone in the vessel to maintain a predetermined pressure regardless of the vertical height of the interface.
摘要翻译： 使用具有气相区，水相区和更稠密的液体区的液体分离器系统来分离流体的混合物。 分离器可用于从液态氧化还原溶液或再次水中分离熔融硫。 该系统包括具有顶部和底部的容器。 容器在顶部具有比底部更大的直径。 该系统还包括用于将氧化还原溶液或重新混合的水和熔融硫（其比氧化还原溶液或再浆化水更致密）引入到容器中的入口。 容器底部附近的出口允许来自容器的熔融硫流。 界面控制结构感测氧化还原溶液或再浆水与熔融硫之间的界面水平，并且界面控制结构控制熔融硫从出口流出。 调整界面控制结构以最佳地改变容器内的界面水平的垂直高度，使得熔融硫在容器中的停留时间不会随着硫生产量的降低而降低，并且使得熔融的 硫和氧化还原溶液随着硫吞吐量的降低而降低。 压力控制器监测容器中的压力，并且在容器中的气相区域中添加或除去气体，以保持预定的压力，而与接口的垂直高度无关。
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2.发明授权公开(公告)号：US07297651B2
公开(公告)日：2007-11-20
申请号：US11446021
申请日：2006-06-01
CPC分类号： B01D53/8612 , B01J31/4015 , B01J31/403 , B01J38/70 , B01J2531/842 , C01B17/0205 , C01B17/05 , C02F1/24 , C02F1/54 , C02F1/72 , C02F2101/101 , C02F2103/18 , C02F2301/022 , C02F2303/12 , Y02P20/584
摘要： The invention relates to a process for removing sulfur particles from an aqueous catalyst solution used to remove hydrogen sulfide from a gas stream (1, 5), comprising the steps of directing a flow of a suspension (12) comprising reduced catalyst solution and sulfur particles to an oxidizer zone (20), where the catalyst solution is regenerated by contacting said suspension with a gas (22) containing oxygen; and removing sulfur from said suspension at least by gravity sedimentation at a bottom (21) of said oxidizer zone (20). According to the invention a flow deflecting means (34) is disposed at least at an outlet (35) for the oxidized catalyst solution leaving said oxidizer zone (20) such as to prevent any turbulent state caused at least by a stream of oxidized catalyst solution leaving said oxidizer zone (20).
摘要翻译： 本发明涉及从用于从气流（1,5）中除去硫化氢的催化剂水溶液中除去硫颗粒的方法，包括以下步骤：引导包含还原催化剂溶液和硫颗粒的悬浮液（12）的流动 通过使所述悬浮液与含氧气体（22）接触来再生所述催化剂溶液的氧化剂区域（20） 以及至少通过在所述氧化剂区（20）的底部（21）处的重力沉降从所述悬浮液中除去硫。 根据本发明，流动偏转装置（34）至少设置在离开所述氧化剂区（20）的氧化催化剂溶液的出口（35）处，以防止至少由氧化催化剂溶液流引起的任何湍流状态 离开所述氧化剂区（20）。
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3.发明授权公开(公告)号：US06413488B1
公开(公告)日：2002-07-02
申请号：US09355067
申请日：2000-06-19
申请人： David Smith , David Benayoun , Claude Dezael
发明人： David Smith , David Benayoun , Claude Dezael
IPC分类号： B01D5350
CPC分类号： B01D53/523 , C01B17/0205 , C01B17/0456 , C01B17/05
摘要： A process and an apparatus are described for treatment of a gas containing hydrogen sulphide and sulphur dioxide, for example a Claus plant tail gas, in which the gas is brought into contact with an organic solvent (1) e.g. polyethylene glycol 400, containing a catalyst e.g. sodium salicylate, in at least one gas-liquid reactor-contactor (2) and a gas (20) substantially no longer containing hydrogen sulphide and sulphur dioxide is recovered. A single-phase solution (4) of solvent and sulphur is extracted from the reactor-contactor and a portion is cooled in at least one cooling zone (8) to obtain a suspension of sulphur crystals in the solvent, the crystallised sulphur is separated from the solvent in a separation zone (10), the sulphur-depleted solvent (14, 15) is recovered and recycled at least in part to the reactor-contactor (2), and the sulphur (13) is recovered.
摘要翻译： 描述了一种用于处理含有硫化氢和二氧化硫的气体的方法和装置，例如克劳斯植物尾气，其中气体与有机溶剂（1）接触。 聚乙二醇400，含有催化剂 在至少一个气液反应器 - 接触器（2）和基本上不再含有硫化氢和二氧化硫的气体（20）中回收水杨酸钠。 从反应器 - 接触器中提取溶剂和硫的单相溶液（4），并在至少一个冷却区（8）中冷却一部分，以获得溶剂中硫结晶的悬浮液，将结晶的硫从 分离区（10）中的溶剂，贫硫溶剂（14,15）被回收并至少部分地再循环到反应器 - 接触器（2）中，并回收硫（13）。
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公开(公告)号：US5389351A
公开(公告)日：1995-02-14
申请号：US970695
申请日：1992-11-04
申请人： Nobuyasu Hasebe , Nobukatsu Hasebe
发明人： Nobuyasu Hasebe , Nobukatsu Hasebe
CPC分类号： B01D53/1468 , B01D53/1493 , B01D53/523 , B01D53/8615 , C01B17/0205 , C01B17/05
摘要： A foul gas containing H.sub.2 S is brought into the presence of SO.sub.2 in a first stage to permit the reaction between SO.sub.2 and H.sub.2 S to form water and elemental sulfur. The SO.sub.2 is solubilized in an absorbent composition which includes a solvent for both SO.sub.2 and H.sub.2 S so that the H.sub.2 S in the foul gas is first solubilized in the absorbent composition where it is then brought into contact with the solubilized SO.sub.2 for reaction between a major portion of the H.sub.2 S and the solubilized SO.sub.2 to form elemental sulfur. The gas is then passed to a second stage where any remaining H.sub.2 S is removed by aqueous catalytic reaction of the type conventional in the prior art. The apparatus utilized to carry out the present invention preferably includes a two stage column in which the first stage provides the absorbent material containing solubilized SO.sub.2 for reaction with the H.sub.2 S of the foul gas. During the SO.sub.2 extraction stage the major portion of the H.sub.2 S is removed from the foul gas. The gas is then conveyed from the first stage to a second stage which comprises a conventional aqueous catalytic scrubbing operation where the remainder of the H.sub.2 S is removed. The absorbent composition utilized in the process comprises solvents that dissolve SO.sub.2 and/or H.sub.2 S which can be heated to a temperature above the melting point of sulfur without detrimentally affecting the solvent so that it may be recycled through the system.
摘要翻译： 含有H 2 S的恶臭气体在第一阶段进入SO 2存在，以允许SO 2和H 2 S之间的反应形成水和元素硫。 SO 2溶解在包含SO 2和H 2 S的溶剂的吸收剂组合物中，使得臭气中的H 2 S首先溶解在吸收剂组合物中，然后与溶解的SO 2接触，以便在大部分 H2S和溶解的SO2形成元素硫。 然后将气体通入第二阶段，其中通过现有技术中常规类型的水性催化反应除去任何剩余的H 2 S. 用于实施本发明的装置优选包括两级塔，其中第一级提供含有溶解的SO 2的吸收材料，用于与恶劣气体的H 2 S反应。 在SO2萃取阶段，H2S的主要部分被从气体中除去。 然后将气体从第一阶段输送到第二阶段，其包括常规的水性催化洗涤操作，其中除去剩余的H 2 S. 在该方法中使用的吸收剂组合物包括溶解SO 2和/或H 2 S的溶剂，其可以被加热到高于硫的熔点的温度，而不会有害地影响溶剂，使得其可以通过系统再循环。
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公开(公告)号：US4304570A
公开(公告)日：1981-12-08
申请号：US120106
申请日：1980-02-08
申请人： Ulrich Kleeberg , Werner Stehning
发明人： Ulrich Kleeberg , Werner Stehning
CPC分类号： C01B17/0205
摘要： A suspension of sulfur in a scrubbing liquid is preheated with steam to a temperature above the melting point of the sulfur so that the latter spontaneously melts in the suspension which is introduced into a separating chamber in a sealed vessel. The scrubbing liquid is decanted over a weir into a second chamber while the molten sulfur is drawn out at the bottom into a third chamber. The separating chamber is maintained at a pressure and temperature, by a vapor cushion above the liquid, such that evaporation of the incoming liquid does not occur, i.e. the separation pressure is the saturation pressure of the cushion. To prevent vapor condensation on the molten sulfur, the latter is maintained at a temperature higher than that of the liquid in the adjacent separating chamber.
摘要翻译： 将洗涤液中的硫的悬浮液用蒸汽预热到高于硫的熔点的温度，使得后者在引入密封容器中的分离室中的悬浮液中自发熔化。 将洗涤液在堰上倾倒到第二室中，同时熔融的硫在底部被抽出到第三室中。 分离室通过液体上方的蒸气垫保持在压力和温度，使得不会发生进入的液体的蒸发，即分离压力是衬垫的饱和压力。 为了防止熔融硫上的蒸汽冷凝，后者保持在比相邻分离室中的液体高的温度。
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公开(公告)号：US2750000A
公开(公告)日：1956-06-12
申请号：US25564651
申请日：1951-11-09
申请人： FREEPORT SULPHUR CO
CPC分类号： E21B43/34 , C01B17/0205
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公开(公告)号：US06521201B1
公开(公告)日：2003-02-18
申请号：US09782230
申请日：2001-02-14
IPC分类号： C01B1704
CPC分类号： C12P3/00 , C01B17/0205 , C01P2004/61 , Y10S423/17
摘要： High quality hydrophilic sulfur is recovered from a biologial conversion zone in which a sulfur containing compound such as a sulfide is converted to elemental sulfur. The sulfur is rendered hydrophilic due to the fine particle size and attachment of biomass to the particles. The sulfur is recovered as an undamaged agglomerate powder after being processed in at least two stages of purification.
摘要翻译： 从其中含硫化合物如硫化物转化为元素硫的生物转化区回收高质量亲水性硫。 由于细颗粒尺寸和生物质附着在颗粒上，使硫变得亲水。 在至少两个阶段的纯化中处理后，将硫作为未损坏的附聚物粉末回收。
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8.发明授权Method and device for processing a gas containing hydrogen sulfide and sulfur dioxide, comprising a stage of removal of solid by-products 有权用于处理含有硫化氢和二氧化硫的气体的方法和装置，包括除去固体副产物的阶段公开(公告)号：US06277352B1
公开(公告)日：2001-08-21
申请号：US09413889
申请日：1999-10-07
IPC分类号： B01D5350
CPC分类号： B01D53/523 , B01D53/8615 , C01B17/0205 , C01B17/033 , C01B17/05
摘要： A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent, such as polyethylene glycol, containing at least one catalyst, such as sodium salicylate, in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products such as alkali metal or alkaline earth metal sulfates or thiosulfates, resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F, comprising most of the solid by-products and a stream F2 mostly comprising solvent nearly free of the solid by-products from the processing stage.
摘要翻译： 至少包含硫化氢（H 2 S）和至少二氧化硫（SO 2）的气体的处理方法包括以下阶段：将气体与液体溶剂如聚乙二醇接触，所述液体溶剂含有至少一种催化剂，例如钠 水杨酸盐在接触阶段回收基本上不含硫化氢和二氧化硫的气态流出物，以及含有液体硫，液体溶剂和固体副产物如碱金属或碱土金属硫酸盐或硫代硫酸盐的混合物，由 催化剂降解，在倾析区中将液态硫与液体溶剂分离，从倾析区内的液体溶剂和液态硫之间的层中提取至少含有固体副产物的液体馏分F，将液体 馏分F到与接触阶段不同的处理阶段，并且回收至少一个流F，其包含大部分固体副产物和流浆 m F2主要包括几乎不含处理阶段固体副产物的溶剂。
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公开(公告)号：US4647287A
公开(公告)日：1987-03-03
申请号：US676995
申请日：1984-11-30
申请人： Costandi A. Audeh
发明人： Costandi A. Audeh
IPC分类号： C01B17/027 , C01B17/02 , C01B17/05 , C02F1/52
CPC分类号： C01B17/0205 , C01B17/05
摘要： A sour gas obtained from an enhanced oil recovery is converted to sulfur slurry which is concentrated for easy filtration, or for direct disposal, by the addition of substantially small amounts of a solid flocculating agent e.g. clay, optionally in combination with selected suitable conventional liquid polymer flocculants. For this purpose, bentonite has been shown to be a particularly effective solid flocculating agent.
摘要翻译： 从增强的油采收率获得的酸性气体转化为硫浆料，其通过添加基本上少量的固体絮凝剂，例如浓缩而浓缩以便于过滤或直接处理。 粘土，任选地与选定的合适的常规液体聚合物絮凝剂组合。 为此，膨润土已被证明是特别有效的固体絮凝剂。
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公开(公告)号：US4631068A
公开(公告)日：1986-12-23
申请号：US756156
申请日：1985-07-18
IPC分类号： C01B17/02 , C01B17/027
CPC分类号： C01B17/0205 , Y10S210/05
摘要： There is disclosed a process for the removal of sulfur from an aqueous sulfur-containing suspension through sulfur coalescence. Sulfur coalescence is initiated by passing the aqueous sulfur-containing suspension through a multi-passage filtering media. In one embodiment of the present invention, the aqueous sulfur-containing suspension is passed through a filtering media comprised of randomly oriented fibrous filter material. In another embodiment of the present invention, the aqueous sulfur containing suspension is passed through sintered metal filters. Optionally, downstream polishing, or filtration, steps using either the above enumerated filters or combinations of the above filters can also be used.
摘要翻译： 公开了一种通过硫聚合从含硫悬浮液中除去硫的方法。 通过使含水的含水悬浮液通过多通道过滤介质来引发硫合并。 在本发明的一个实施方案中，含水的含水悬浮液通过由随机取向的纤维过滤材料组成的过滤介质。 在本发明的另一个实施方案中，含硫的悬浮液通过烧结金属过滤器。 任选地，也可以使用下列抛光或过滤，使用上述列举的过滤器或上述过滤器的组合的步骤。
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