摘要:
The invention relates to the use of polyurethane sealing compounds for the production of light-fast compact or foamed polyurethane bodies or polyurethane urea bodies which have excellent mechanical and optical properties and especially a very high thermostability.
摘要:
The present invention relates to innovative polyisocyanate mixtures comprising cycloaliphatic structural elements and containing exclusively linear-aliphatically attached free isocyanate groups, to a process for preparing them and to their use as a starting component in the production of polyurethane plastics, more particularly as a crosslinker component in polyurethane coating materials and coatings.
摘要:
Storage-stable blocked polyisocyanates prepared by reacting one or more polyisocyanates with one or more biuretizing agents and optionally, catalysts such that in the blocked end product there are 5-45 equivalent percent of biuret groups according to formula (I) based on the sum total of all free and blocked NCO groups; optionally modifying the resulting biuret polyisocyanates with the aid of isocyanate-reactive compounds and/or catalysts, with further reaction of free NCO groups; and subsequently blocking at least 95 mol percent of the remaining free NCO groups with a blocking agent according to the formula R1R2NH, where R1 and R2 independently of one another are aliphatic or cycloaliphatic C1-C12 alkyl radicals. The blocked polyisocyanates can be used to make polyurethane polymers and coating compositions, which can be used to coat substrates.
摘要:
A process for the purification of organic isocyanates or isocyanate mixtures in which the amount of chlorine compound(s) present is reduced by mixing the isocyanate(s) or isocyanate mixtures with a gel-type or macroporous, anion-exchanging organic material having tertiary and/or quaternary amino groups. The process renders possible a purification of the isocyanates from chlorine-containing compounds which is milder than in conventional processes and is therefore particularly suitable for temperature-sensitive isocyanates.
摘要:
The present invention relates to a heat-crosslinkable water-based coating composition containing as bindera) a water-soluble or water-dispersible polyol component andb) a water-soluble or water-dispersible blocked polyisocyanate which has an average NCO functionality of 2.0 to 2.6 and is based on the reaction product ofb1) a polyisocyanate mixture having an average NCO functionality of 2.5 to 3.5 and containing (i) at least 15% by weight of an organic diisocyanate,b2) a blocking agent for isocyanate groups in an amount of 50 to 80 equivalent-%, based on the isocyanate groups of component b1) andb3) an aliphatic monohydroxymonocarboxylic acid in a quantity of 20 to 50 equivalent-%, based on the isocyanate groups of component b1) and the hydroxyl groups of component b3), wherein the equivalent ratio, based on the isocyanate-reactive groups of blocking agent b2) and the hydroxyl groups of component b3) to the isocyanate groups of component b1) is at least 0.9:1.
摘要:
The present invention relates to the use of solvent-free low-monomer polyisocyanates based on araliphatic diisocyanates for the production of light- and weather-resistant polyurethane bodies having a high light refraction and low dispersion.
摘要:
The present invention relates to an improved process for the preparation of polyisocyanates with a biuret structure by continuous reaction of excess amounts of organic diisocyanates having exclusively aliphatically and/or cycloaliphatically bonded isocyanate groups with organic diamines having exclusively aliphatically and/or cycloaliphatically bonded primary amino groups at elevated temperatures by 2-stage addition of the isocyanate component.
摘要:
This invention relates to coating compositions and more particularly to highly productive coating compositions that quickly harden for sanding or buffing by incorporating therein a polyisocyanate adduct mixture into the coating composition as the crosslinking material. Such coatings are particularly useful for refinishing automobiles and trucks.
摘要:
Biuret group-containing polyisocyanates are produced having an isocyanate functionality of at least 4 are prepared by reacting polyisocyanates having a functionality of at least 2.8 with water as the biuretizing agent. Most preferably water is used as the sole biuretizing agent. The preparation is useful as a curing agent in crosslinkable coating compositions. The coating composition can be used as an automotive clearcoat over a conventional pigmented basecoat, or as a basecoat or monocoat or even as a primer or sealer when a suitable amount of pigment is incorporated therein.
摘要:
The present invention relates to aqueous polyurethane dispersions prepared from a polyisocyanate component and one or more isocyanate-reactive compounds wherein at least 5% by weight of polyisocyanate component is a diisocyanate corresponding to formula (I) wherein R is a difunctional, C4 to C18, aliphatic, cycloaliphatic or aromatic hydrocarbon residue obtained by removing the NCO groups from an organic diisocyanate and R′ is a monofunctional, C1 to C18 hydrocarbon radical, which may contain ether oxygen atoms. The present invention also relates to the use of these PUR dispersions for coating any substrates, preferably wood substrates, such as parquet flooring.