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公开(公告)号：US09856422B2
公开(公告)日：2018-01-02
申请号：US13989154
申请日：2011-11-23
CPC分类号： C10G21/16 , C07C51/48 , C07C211/63 , C10G19/02 , C10G21/27 , C10G21/28 , C10G2300/1033 , C10G2300/104 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/203 , Y02P20/582 , C07C63/36
摘要： The present invention relates to a process for the removal of naphthenic acids from crude oils and crude oil distillates by use of supported basic ionic liquids.
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2.发明申请公开(公告)号：US20140091008A1
公开(公告)日：2014-04-03
申请号：US13989154
申请日：2011-11-23
IPC分类号： C10G21/16
CPC分类号： C10G21/16 , C07C51/48 , C07C211/63 , C10G19/02 , C10G21/27 , C10G21/28 , C10G2300/1033 , C10G2300/104 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/203 , Y02P20/582 , C07C63/36
摘要： The present invention relates to a process for the removal of naphthenic acids from crude oils and crude oil distillates by use of supported basic ionic liquids.
摘要翻译： 本发明涉及一种通过使用负载的碱性离子液体从原油和原油馏出物中除去环烷酸的方法。
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公开(公告)号：US20100056782A1
公开(公告)日：2010-03-04
申请号：US12612149
申请日：2009-11-04
IPC分类号： C07D473/00
CPC分类号： C07D473/00 , C07B35/02 , C07B41/02 , C07C5/08 , C07C29/141 , C07C29/17 , C07C29/175 , C07C45/62 , C07C67/303 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/18 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2527/053 , C07C2527/232 , C07C2601/16 , C07C49/213 , C07C47/32 , C07C47/228 , C07C49/203 , C07C69/24 , C07C33/32 , C07C33/20 , C07C31/125 , C07C31/10 , C07C33/14 , C07C33/38 , C07C33/02 , C07C33/025
摘要： Disclosed are heterogeneous processes (i) for the hydrogenation of a compound containing at least one unsaturated carbon-carbon bond, and (ii) for the hydro-dehalogenation of a compound containing at least one C—Cl, C—Br or C—I bond. The processes comprise reacting said compound with a hydrogenating agent and a heterogeneous hydrogenation catalyst in the presence of an ionic liquid.
摘要翻译： 公开了用于氢化含有至少一个不饱和碳 - 碳键的化合物的非均相方法（i）和（ⅱ）含有至少一个C-Cl，C-Br或C-I的化合物的氢化脱卤 键。 所述方法包括在离子液体存在下使所述化合物与氢化剂和多相氢化催化剂反应。
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公开(公告)号：US07803974B2
公开(公告)日：2010-09-28
申请号：US12612149
申请日：2009-11-04
IPC分类号： C07C17/23
CPC分类号： C07D473/00 , C07B35/02 , C07B41/02 , C07C5/08 , C07C29/141 , C07C29/17 , C07C29/175 , C07C45/62 , C07C67/303 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/18 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2527/053 , C07C2527/232 , C07C2601/16 , C07C49/213 , C07C47/32 , C07C47/228 , C07C49/203 , C07C69/24 , C07C33/32 , C07C33/20 , C07C31/125 , C07C31/10 , C07C33/14 , C07C33/38 , C07C33/02 , C07C33/025
摘要： Disclosed are heterogeneous processes (i) for the hydrogenation of a compound containing at least one unsaturated carbon-carbon bond, and (ii) for the hydro-dehalogenation of a compound containing at least one C—Cl, C—Br or C—I bond. The processes comprise reacting said compound with a hydrogenating agent and a heterogeneous hydrogenation catalyst in the presence of an ionic liquid.
摘要翻译： 公开了用于氢化含有至少一个不饱和碳 - 碳键的化合物的非均相方法（i）和（ⅱ）含有至少一个C-Cl，C-Br或C-I的化合物的氢化脱卤 键。 所述方法包括在离子液体存在下使所述化合物与氢化剂和多相氢化催化剂反应。
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公开(公告)号：US07667058B2
公开(公告)日：2010-02-23
申请号：US10478039
申请日：2002-05-17
IPC分类号： C07C51/36
CPC分类号： C07D473/00 , C07B35/02 , C07B41/02 , C07C5/08 , C07C29/141 , C07C29/17 , C07C29/175 , C07C45/62 , C07C67/303 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/18 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2527/053 , C07C2527/232 , C07C2601/16 , C07C49/213 , C07C47/32 , C07C47/228 , C07C49/203 , C07C69/24 , C07C33/32 , C07C33/20 , C07C31/125 , C07C31/10 , C07C33/14 , C07C33/38 , C07C33/02 , C07C33/025
摘要： Disclosed are heterogeneous processes (i) for the hydrogenation of a compound containing at least one unsaturated carbon-carbon bond, and (ii) for the hydro-dehalogenation of a compound containing at least one C—Cl, C—Br or C—I bond. The processes comprise reacting said compound with a hydrogenating agent and a heterogeneous hydrogenation catalyst in the presence of an ionic liquid.
摘要翻译： 公开了用于氢化含有至少一个不饱和碳 - 碳键的化合物的非均相方法（i）和（ⅱ）含有至少一个C-Cl，C-Br或C-I的化合物的氢化脱卤 键。 所述方法包括在离子液体存在下使所述化合物与氢化剂和多相氢化催化剂反应。
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公开(公告)号：US20170022447A1
公开(公告)日：2017-01-26
申请号：US15039168
申请日：2014-11-28
申请人： Martin Atkins , Fergal Coleman , Peter Goodrich
发明人： Martin Atkins , Fergal Coleman , Peter Goodrich
摘要： The present invention relates to deacidification of glyceride oils. The present invention provides a process for removing free fatty acids from glyceride oil, preferably palm oil, containing free fatty acids, said process comprising the steps of: (i) contacting the glyceride oil containing free fatty acids with the basic ionic liquid; wherein the basic ionic liquid has a basic anion selected from hydroxide, alkoxide, alkylcarbonate, hydrogen carbonate, serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate; and a cation selected from: [N(Ra)(Rb)(Rc)(Rd)]+, wherein: Ra, Rb, Rc and Rd are each independently selected from hydrogen, a C1 to C8, straight chain or branched alkyl group or a C3 to C6 cycloalkyl group, wherein said alkyl or cycloalkyl groups are unsubstituted or may be substituted by one to three groups selected from: C1 to C4 alkoxy, C2 to C8 alkoxyalkoxy, C3 to C6 cycloalkyl, —OH, —SH, —CO2(C1 to C6)alkyl, —OC(O)(C1 to C6)alkyl, or any two of Ra, Rb, Rc and Rd combine to form an alkylene chain —(CH2)q— wherein q is from 3 to 6; and (ii) obtaining a treated glyceride oil having a reduced content of free fatty acid compared to the glyceride oil feed of step (i).
摘要翻译： 本发明涉及甘油酯油的脱酸。 本发明提供了一种从含有游离脂肪酸的甘油酯油，优选棕榈油中除去游离脂肪酸的方法，所述方法包括以下步骤：（i）使含有游离脂肪酸的甘油酯油与碱性离子液体接触; 其中所述碱性离子液体具有选自氢氧化物，醇盐，烷基碳酸盐，碳酸氢盐，丝氨酸盐，脯氨酸盐，组氨酸盐，苏氨酸盐，缬氨酸盐，天冬酰胺酸盐，牛磺酸盐和赖氨酸盐的碱性阴离子; 和选自：[N（Ra）（Rb）（Rc）（Rd）] +的阳离子，其中：Ra，Rb，Rc和Rd各自独立地选自氢，C1至C8，直链或支链烷基 或C 3至C 6环烷基，其中所述烷基或环烷基是未取代的或可被一至三个选自以下的基团取代：C 1至C 4烷氧基，C 2至C 8烷氧基烷氧基，C 3至C 6环烷基，-OH，-SH， CO 2（C 1至C 6）烷基，-OC（O）（C 1至C 6）烷基或R a，R b，R c和R d中的任何两个结合形成亚烷基链 - （CH 2）q-，其中q为3至6 ; 和（ii）与步骤（i）的甘油酯油进料相比，获得游离脂肪酸含量降低的经处理的甘油酯油。
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公开(公告)号：US20180187122A1
公开(公告)日：2018-07-05
申请号：US15577112
申请日：2016-05-27
申请人： Peter Goodrich , Eoghain O'Hara , Martin P. Atkins
发明人： Peter Goodrich , Eoghain O'Hara , Martin P. Atkins
摘要： The present invention relates to a process for the removal of free fatty acids from glyceride oils, especially palm oil. In particular, the present invention is directed to a process wherein specific ionic liquids are utilised for removing free fatty acids contained in glyceride oils, preferably palm oil, such that a glyceride oil, having a reduced content of free fatty acids may be obtained. The invention also relates to treated glyceride oil compositions, preferably treated palm oil compositions, comprising certainionic quids to prevent build-up of free fatty acids in stored oil.
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8.发明授权公开(公告)号：US09279086B2
公开(公告)日：2016-03-08
申请号：US13322470
申请日：2010-03-30
申请人： Chris Hardacre , Peter Goodrich , Kris Anderson
发明人： Chris Hardacre , Peter Goodrich , Kris Anderson
CPC分类号： C10G21/27 , C10G21/28 , C10G25/003 , C10G2300/104 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/1062 , C10G2300/203 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , Y02P20/582
摘要： The present invention relates to a process for the removal of organic acids, particularly naphthenic acids, from crude oils and crude oil distillates by use of a supported basic ionic liquid in a mass ratio of crude oil and/or crude oil distillate and ionic liquid of from greater than 40:1, the basic ionic liquid comprises a basic anion selected from serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate.
摘要翻译： 本发明涉及从原油和原油馏出物中除去有机酸，特别是环烷酸的方法，其中使用负载的碱性离子液体，原油和/或原油馏出物与离子液体的质量比为 从大于40:1，碱性离子液体包含选自丝氨酸，脯氨酸，组氨酸，苏氨酸，缬氨酸，天冬酰胺酸，牛磺酸和赖氨酸的碱性阴离子。
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9.发明申请公开(公告)号：US20120132564A1
公开(公告)日：2012-05-31
申请号：US13322470
申请日：2010-03-30
申请人： Chris Hardacre , Peter Goodrich , Kris Anderson
发明人： Chris Hardacre , Peter Goodrich , Kris Anderson
IPC分类号： C10G29/20 , C07C303/44 , C07D207/16 , C10G99/00 , C07C227/40
CPC分类号： C10G21/27 , C10G21/28 , C10G25/003 , C10G2300/104 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/1062 , C10G2300/203 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , Y02P20/582
摘要： The present invention relates to a process for the removal of organic acids, particularly naphthenic acids, from crude oils and crude oil distillates by use of a supported basic ionic liquid in a mass ratio of crude oil and/or crude oil distillate and ionic liquid of from greater than 40:1, the basic ionic liquid comprises a basic anion selected from serinate, prolinate, histidinate, threoninate, valinate, asparaginate, taurinate and lysinate.
摘要翻译： 本发明涉及从原油和原油馏出物中除去有机酸，特别是环烷酸的方法，其中使用负载的碱性离子液体，原油和/或原油馏出物与离子液体的质量比为 从大于40:1，碱性离子液体包含选自丝氨酸，脯氨酸，组氨酸，苏氨酸，缬氨酸，天冬酰胺酸，牛磺酸和赖氨酸的碱性阴离子。
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公开(公告)号：US10526561B2
公开(公告)日：2020-01-07
申请号：US15577112
申请日：2016-05-27
申请人： Peter Goodrich , Eoghain O'Hara , Martin P. Atkins
发明人： Peter Goodrich , Eoghain O'Hara , Martin P. Atkins
摘要： The present invention relates to a process for the removal of free fatty acids from glyceride oils, especially palm oil. In particular, the present invention is directed to a process wherein specific ionic liquids are utilised for removing free fatty acids contained in glyceride oils, preferably palm oil, such that a glyceride oil, having a reduced content of free fatty acids may be obtained. The invention also relates to treated glyceride oil compositions, preferably treated palm oil compositions, comprising certain ionic liquids to prevent build-up of free fatty acids in stored oil.
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