Process for polymerization in a gaseous phase using heterogeneous
catalysis and a spherical reactor for carrying out the process
    1.
    发明授权
    Process for polymerization in a gaseous phase using heterogeneous catalysis and a spherical reactor for carrying out the process 失效
    使用多相催化在气相中聚合的方法和用于进行该方法的球形反应器

    公开(公告)号:US4467080A

    公开(公告)日:1984-08-21

    申请号:US444872

    申请日:1982-11-29

    摘要: The invention relates to a process for polymerizing in an aqueous phase using heterogeneous catalysis and to a spherical reactor for carrying out said process. At least one monomer which is gaseous under the reaction conditions is just in contact with a solid catalyst in an agitated polymerization zone. The polymerization zone is defined by a spherical wall and the agitation is effected by means of a turbine unit having blades driven in rotation. The blades extend alongside the wall on 10 to 60% of its surface. The particles of the catalyst and the growing polymer powder are driven by centrifugal force onto at least a part of the spherical wall and fall back into the central part of the spherical zone, thereby ensuring a thorough and uniform mixing without any dead zone. The invention is useful for prepolymerizing or polymerizing olefins.

    摘要翻译: 本发明涉及使用多相催化在水相中聚合的方法和用于进行所述方法的球形反应器。 至少一种在反应条件下为气态的单体在搅拌聚合区中刚好与固体催化剂接触。 聚合区域由球形壁限定,并且通过具有旋转驱动的叶片的涡轮机单元进行搅拌。 叶片沿壁面延伸10至60%的表面。 催化剂和生长的聚合物粉末的颗粒通过离心力驱动到球形壁的至少一部分上并落回球形区域的中心部分,从而确保彻底均匀的混合而没有任何死区。 本发明可用于预聚合或聚合烯烃。

    Process for the polymerization of olefins
    3.
    发明授权
    Process for the polymerization of olefins 失效
    烯烃聚合方法

    公开(公告)号:US4611038A

    公开(公告)日:1986-09-09

    申请号:US756812

    申请日:1985-07-18

    摘要: A process is provided for the polymerization of olefins in the gas phase wherein olefins are contacted with a catalyst system consisting of an active solid hydrocarbon having been prepared by forming a pulverulent composition by mixing a transition metal component, a porous organic or inorganic solid support and an organometallic compound of the organo-Al, organo-Mg or organo-Zn type, and polymerizing a controlled amount of one or more C.sub.2 to C.sub.12 olefins in the gas phase in contact with the pulverulent composition with a specific hourly conversion of the olefins to produce the active solid hydrocarbon.

    摘要翻译: 提供了一种在气相中烯烃聚合的方法,其中烯烃与由活性固体烃组成的催化剂体系接触,催化剂体系已经通过将过渡金属组分,多孔有机或无机固体载体和 有机-Al,有机-Mg或有机-Zn型的有机金属化合物,并且在与气相组成的气相中聚合受控量的一种或多种C2〜C12烯烃,以烯烃的特定小时转化为 产生活性固体烃。

    Hydroprocessing catalyst, method for the preparation thereof and use of the same
    4.
    发明授权
    Hydroprocessing catalyst, method for the preparation thereof and use of the same 有权
    加氢处理催化剂,其制备方法及其用途

    公开(公告)号:US07741241B2

    公开(公告)日:2010-06-22

    申请号:US11795519

    申请日:2006-01-19

    IPC分类号: B01J23/88

    摘要: The invention relates to a hydrocarbon hydroconversion catalyst comprising a carrier based on refractory oxide, a metal of the group VIII, and a metal of the group VIB. Said catalyst is characterised in that it also comprises at least one organic compound selected from the alkene diols of formula (I) wherein R1 represents a C2-10 alkenylene group, preferably C2-4 alkenylene, a C6-18 arylene group, or a C7-18 alkylene-arylene group, and each R2 independently represents a hydrogen atom or a C1-18 alkyl group, a C1-18 alkenyl group, a C6-18 aryl group, a C3-8 cycloalkyl group, or a C7-20 alkylaryl or arylalkyl group, or the two groups R2 together form a divalent C2-18 group, the carbonated chain of the R2 groups containing or carrying at least one heteroatom selected from S, N and O. The invention also relates to a method for preparing one such catalyst, and to the use of said catalyst for hydrotreatment or hydroconversion.

    摘要翻译: 本发明涉及一种烃加氢转化催化剂,其包含基于难熔氧化物的载体,第Ⅷ族金属和VIB族金属。 所述催化剂的特征在于其还包含至少一种选自式(I)的烯烃二醇的有机化合物,其中R 1表示C 2-10亚烯基,优选C 2-4亚烯基,C 6-18亚芳基或C7 -18亚烷基 - 亚芳基,各R2独立地表示氢原子或C1-18烷基,C1-18烯基,C6-18芳基,C3-8环烷基或C7-20烷基芳基 或芳基烷基,或两个基团R2一起形成二价C 21-18基团,R 2基团的碳酸化链含有或携带至少一个选自S,N和O的杂原子。本发明还涉及一种制备一种 这种催化剂,以及所述催化剂用于加氢处理或加氢转化的用途。

    Process for sulphurization of hydrotreating catalysts
    6.
    发明授权
    Process for sulphurization of hydrotreating catalysts 有权
    加氢处理催化剂硫化工艺

    公开(公告)号:US06325920B1

    公开(公告)日:2001-12-04

    申请号:US09553409

    申请日:2000-04-20

    IPC分类号: C10G4504

    摘要: The invention relates to a process for the sulphurization of catalysts for the hydrotreating of hydrocarbon feedstocks. According to the invention, a small amount of at least one orthophthalic acid ester is added to the sulphurization agent used to sulphurize the catalyst. The catalysts thus sulphurized prove to be more active than conventionally sulphurized catalysts.

    摘要翻译: 本发明涉及用于加氢处理烃原料的催化剂的硫化方法。 根据本发明,向用于硫化催化剂的硫化剂中加入少量至少一种邻苯二甲酸酯。 因此,如此硫化的催化剂比常规硫化催化剂更具有活性。

    Method for the treatment of a catalytic component on a porous metal
oxide support for the polymerization of olefins in the gas phase and
method of polymerizing olefins
    9.
    发明授权
    Method for the treatment of a catalytic component on a porous metal oxide support for the polymerization of olefins in the gas phase and method of polymerizing olefins 失效
    用于处理气相中烯烃聚合的多孔金属氧化物载体上的催化组分的方法和聚合烯烃的方法

    公开(公告)号:US5399638A

    公开(公告)日:1995-03-21

    申请号:US819182

    申请日:1992-01-10

    摘要: The method of forming a catalytic component for use in the polymerization of ethylene or a copolymer of ethylene and a C.sub.3 to C.sub.12 alpha olefin in a gas-phase comprising impregnating a porous metal oxide support with at least one titanium compound, magnesium compound, and chlorine compound, and prepolymerizing ethylene or a copolymer of ethylene and a C.sub.3 to C.sub.12 alpha olefin, a least partially in suspension, in the presence of said porous metal oxide support and at least one alkylaluminum compound until a degree of prepolymerization is reached which is suitable for the subsequent gas-phase of fluidized bed polymerization, and the method of polymerizing olefins utilizing the catalysts formed by the prepolymerization.

    摘要翻译: 在气相中形成用于聚合乙烯或乙烯和C 3 -C 12α-烯烃的共聚物的催化组分的方法,包括用至少一种钛化合物,镁化合物和氯浸渍多孔金属氧化物载体 化合物,以及在所述多孔金属氧化物载体和至少一种烷基铝化合物的存在下至少部分地悬浮的乙烯或乙烯和C 3 -C 12α-烯烃的共聚物预聚合,直到达到预聚合程度,其适用于 流化床聚合的后续气相,以及利用通过预聚合形成的催化剂使烯烃聚合的方法。

    Asymmetric semipermeable membrane for the treatment of biological fluids
    10.
    发明授权
    Asymmetric semipermeable membrane for the treatment of biological fluids 失效
    用于治疗生物流体的不对称可切割膜

    公开(公告)号:US5145583A

    公开(公告)日:1992-09-08

    申请号:US632388

    申请日:1990-12-21

    摘要: An asymmetric semipermeable membrane and processes for the manufacture thereof are disclosed. The membrane comprises at least one hydrophobic polymer and at least one copolymer based on acrylonitrile, at least one sulphonic monomer which is optionally salified, and optionally at least one non-ionic, ionizable, olefinically unsaturated monomer. The membrane is useful in the treatment of biological fluids such as plasma or blood, especially using plasmapheresis, or with the aid of an artificial kidney using hemodialysis and/or ultrafiltration.

    摘要翻译: 公开了一种不对称半透膜及其制造方法。 该膜包含至少一种疏水性聚合物和至少一种基于丙烯腈的共聚物,至少一种任选盐化的磺酸单体和任选的至少一种非离子的,可离子化的烯属不饱和单体。 该膜可用于治疗生物流体如血浆或血液,特别是使用血浆置换术,或借助于使用血液透析和/或超滤的人造肾。