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    Process for sulphurization of hydrotreating catalysts
    1.
    发明授权
    Process for sulphurization of hydrotreating catalysts 有权
    加氢处理催化剂硫化工艺

    公开(公告)号：US06325920B1

    公开(公告)日：2001-12-04

    申请号：US09553409

    申请日：2000-04-20

    申请人： Claude Brun ,  Thierry Cholley ,  Geoges Fremy

    发明人： Claude Brun ,  Thierry Cholley ,  Geoges Fremy

    IPC分类号： C10G4504

    摘要： The invention relates to a process for the sulphurization of catalysts for the hydrotreating of hydrocarbon feedstocks. According to the invention, a small amount of at least one orthophthalic acid ester is added to the sulphurization agent used to sulphurize the catalyst. The catalysts thus sulphurized prove to be more active than conventionally sulphurized catalysts.

    摘要翻译： 本发明涉及用于加氢处理烃原料的催化剂的硫化方法。 根据本发明，向用于硫化催化剂的硫化剂中加入少量至少一种邻苯二甲酸酯。 因此，如此硫化的催化剂比常规硫化催化剂更具有活性。

    Hydroprocessing catalyst, method for the preparation thereof and use of the same
    2.
    发明授权
    Hydroprocessing catalyst, method for the preparation thereof and use of the same 有权
    加氢处理催化剂，其制备方法及其用途

    公开(公告)号：US07741241B2

    公开(公告)日：2010-06-22

    申请号：US11795519

    申请日：2006-01-19

    申请人： Thierry Cholley ,  Jean-Pierre Dath ,  Claude Brun ,  Georges Fremy ,  Francis Humblot

    发明人： Thierry Cholley ,  Jean-Pierre Dath ,  Claude Brun ,  Georges Fremy ,  Francis Humblot

    IPC分类号： B01J23/88

    CPC分类号： C10G47/12 ,  B01J21/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/94 ,  B01J31/0202 ,  B01J37/0203 ,  B01J37/20 ,  B01J38/52 ,  C10G45/04 ,  C10G45/08 ,  C10G47/06 ,  C10G47/10 ,  C10G2300/1037 ,  C10G2300/301 ,  C10G2300/44 ,  C10G2300/703

    摘要： The invention relates to a hydrocarbon hydroconversion catalyst comprising a carrier based on refractory oxide, a metal of the group VIII, and a metal of the group VIB. Said catalyst is characterised in that it also comprises at least one organic compound selected from the alkene diols of formula (I) wherein R1 represents a C2-10 alkenylene group, preferably C2-4 alkenylene, a C6-18 arylene group, or a C7-18 alkylene-arylene group, and each R2 independently represents a hydrogen atom or a C1-18 alkyl group, a C1-18 alkenyl group, a C6-18 aryl group, a C3-8 cycloalkyl group, or a C7-20 alkylaryl or arylalkyl group, or the two groups R2 together form a divalent C2-18 group, the carbonated chain of the R2 groups containing or carrying at least one heteroatom selected from S, N and O. The invention also relates to a method for preparing one such catalyst, and to the use of said catalyst for hydrotreatment or hydroconversion.

    摘要翻译： 本发明涉及一种烃加氢转化催化剂，其包含基于难熔氧化物的载体，第Ⅷ族金属和VIB族金属。 所述催化剂的特征在于其还包含至少一种选自式（I）的烯烃二醇的有机化合物，其中R 1表示C 2-10亚烯基，优选C 2-4亚烯基，C 6-18亚芳基或C7 -18亚烷基 - 亚芳基，各R2独立地表示氢原子或C1-18烷基，C1-18烯基，C6-18芳基，C3-8环烷基或C7-20烷基芳基 或芳基烷基，或两个基团R2一起形成二价C 21-18基团，R 2基团的碳酸化链含有或携带至少一个选自S，N和O的杂原子。本发明还涉及一种制备一种 这种催化剂，以及所述催化剂用于加氢处理或加氢转化的用途。

    Hydrotreatment catalyst, method for production and use thereof
    3.
    发明授权
    Hydrotreatment catalyst, method for production and use thereof 有权
    加氢处理催化剂，其制备方法及其应用

    公开(公告)号：US08318628B2

    公开(公告)日：2012-11-27

    申请号：US12519971

    申请日：2007-12-14

    申请人： Claude Brun ,  Thierry Cholley ,  Carole Dupuy ,  Georges Fremy ,  Francis Humblot

    发明人： Claude Brun ,  Thierry Cholley ,  Carole Dupuy ,  Georges Fremy ,  Francis Humblot

    IPC分类号： B01J31/02

    CPC分类号： B01J31/28 ,  B01J23/85 ,  B01J23/882 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0208 ,  B01J31/0229 ,  B01J31/34 ,  B01J37/0203 ,  B01J37/20 ,  C10G45/08 ,  C10G47/12 ,  C10G2300/703

    摘要： The invention relates to a catalyst for hydroconversion of hydrocarbons, comprising a support made from at least one refractory oxide, at least one group VIII metal and at least one group VIB metal, characterized in further comprising at least one organic compound with at least two thiol functions separated by at least one oxygenated group of formula (I): HS—CxHyOz—SH (I), where x=1 to 20, preferably 2 to 9 and for example x=6, y=2 to 60, preferably 4 to 12 and z=1 to 10, preferably 1 to 6. The invention further relates to a method for preparation, a method for activation of said catalyst and use of the catalyst for the hydrotreatment and/or hydrocracking of hydrocarbons.

    摘要翻译： 本发明涉及用于加氢转化烃的催化剂，其包括由至少一种难熔氧化物，至少一种第Ⅷ族金属和至少一种VIB族金属制成的载体，其特征在于还包含至少一种有机化合物与至少两种硫醇 由式（I）的至少一个氧化基团分离的功能：HS-CxHyOz-SH（I），其中x = 1至20，优选2至9，例如x = 6，y = 2至60，优选4至 12和z = 1至10，优选1至6.本发明还涉及一种制备方法，一种活化所述催化剂的方法和该催化剂用于烃的加氢处理和/或加氢裂化的用途。

    HYDROTREATMENT CATALYST, METHOD FOR PRODUCTION AND USE THEREOF
    5.
    发明申请
    HYDROTREATMENT CATALYST, METHOD FOR PRODUCTION AND USE THEREOF 有权
    氢化催化剂，生产方法及其用途

    公开(公告)号：US20100044274A1

    公开(公告)日：2010-02-25

    申请号：US12519971

    申请日：2007-12-14

    申请人： Claude Brun ,  Thierry Cholley ,  Carole Dupuy ,  Georges Fremy ,  Francis Humblot

    发明人： Claude Brun ,  Thierry Cholley ,  Carole Dupuy ,  Georges Fremy ,  Francis Humblot

    IPC分类号： B01J31/02 ,  C10G11/04

    CPC分类号： B01J31/28 ,  B01J23/85 ,  B01J23/882 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0208 ,  B01J31/0229 ,  B01J31/34 ,  B01J37/0203 ,  B01J37/20 ,  C10G45/08 ,  C10G47/12 ,  C10G2300/703

    摘要： The invention relates to a catalyst for hydroconversion of hydrocarbons, comprising a support made from at least one refractory oxide, at least one group VIII metal and at least one group VIB metal, characterised in further comprising at least one organic compound with at least two thiol functions separated by at least one oxygenated group of formula (I): HS—CxHyOz-SH (I), where x=1 to 20, preferably 2 to 9 and for example x=6, y=2 to 60, preferably 4 to 12 and z=1 to 10, preferably 1 to 6. The invention further relates to a method for preparation, a method for activation of said catalyst and use of the catalyst for the hydrotreatment and/or hydrocracking of hydrocarbons.

    摘要翻译： 本发明涉及用于加氢转化烃的催化剂，其包括由至少一种难熔氧化物，至少一种第Ⅷ族金属和至少一种VIB族金属制成的载体，其特征在于还包含至少一种有机化合物与至少两种硫醇 由式（I）的至少一个氧化基团分离的功能：HS-CxHyOz-SH（I），其中x = 1至20，优选2至9，例如x = 6，y = 2至60，优选4至 12和z = 1至10，优选1至6.本发明还涉及一种制备方法，一种活化所述催化剂的方法和该催化剂用于烃的加氢处理和/或加氢裂化的用途。

    Hydroprocessing Catalyst, Preparation Method Thereof and Use of Same
    6.
    发明申请
    Hydroprocessing Catalyst, Preparation Method Thereof and Use of Same 有权
    加氢催化剂及其制备方法及用途

    公开(公告)号：US20080194892A1

    公开(公告)日：2008-08-14

    申请号：US11795411

    申请日：2006-01-19

    申请人： Thierry Cholley ,  Jean-Pierre Dath ,  Claude Brun ,  Georges Fremy ,  Francis Humblot

    发明人： Thierry Cholley ,  Jean-Pierre Dath ,  Claude Brun ,  Georges Fremy ,  Francis Humblot

    IPC分类号： B01J31/26 ,  C07C4/06

    CPC分类号： B01J31/0209 ,  B01J21/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/94 ,  B01J37/0203 ,  B01J37/20 ,  B01J38/52 ,  C10G45/04 ,  C10G45/08

    摘要： The invention relates to a hydrocarbon hydroprocessing catalyst comprising a support based on at least one refractory oxide, at least one metal from group VIII and at least one metal from group VIB. The inventive catalyst is characterised in that it also comprises at least one organic compound having formula (I) or (II) in which each R1 represents independently an alkyl group at C1-18, an alkenyl group at C2-18, an aryl group at C6-18, a cycloalkyl group at C3-8, an alkylaryl or arylalkyl group at C7-20, or the two R1 groups together form a divalent group at C2-18, and R2 represents an alkylene group at C1-18, an arylene group at C6-18, a cycloalkylene group at C3-7, or a combination of same. The invention also relates to a method of preparing one such catalyst and to the use thereof for hydroprocessing or hydrocracking.

    摘要翻译： 本发明涉及一种烃加氢处理催化剂，其包含基于至少一种难熔氧化物的载体，至少一种VIII族金属和至少一种VIB族金属。 本发明的催化剂的特征在于其还包含至少一种具有式（I）或（II）的有机化合物，其中每个R 1独立地表示C 1-18上的烷基， C 2〜C 18的链烯基，C 6-18的芳基，C 3〜C 8的环烷基 >，C 7-20的烷基芳基或芳基烷基或两个R 1个基团一起在C 2-18位上形成二价基团， ，R 2表示C 1-18亚烷基，C 6-18亚烷基，C 6-18亚环烷基， SUB> 3-7 ，或其组合。 本发明还涉及制备一种这样的催化剂的方法及其用于加氢处理或加氢裂化的方法。

    Hydroprocessing Catalyst, Method for the Preparation Thereof and Use of the Same
    7.
    发明申请
    Hydroprocessing Catalyst, Method for the Preparation Thereof and Use of the Same 有权
    加氢处理催化剂及其制备方法及其应用

    公开(公告)号：US20080087577A1

    公开(公告)日：2008-04-17

    申请号：US11795519

    申请日：2006-01-19

    申请人： Thierry Cholley ,  Jean-Pierre Dath ,  Claude Brun ,  Georges Fremy ,  Francis Humblot

    发明人： Thierry Cholley ,  Jean-Pierre Dath ,  Claude Brun ,  Georges Fremy ,  Francis Humblot

    IPC分类号： B01J23/88 ,  B01J23/94 ,  B01J37/20 ,  B01J38/52 ,  C10G45/08

    CPC分类号： C10G47/12 ,  B01J21/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/94 ,  B01J31/0202 ,  B01J37/0203 ,  B01J37/20 ,  B01J38/52 ,  C10G45/04 ,  C10G45/08 ,  C10G47/06 ,  C10G47/10 ,  C10G2300/1037 ,  C10G2300/301 ,  C10G2300/44 ,  C10G2300/703

    摘要： The invention relates to a hydrocarbon hydroconversion catalyst comprising a carrier based on refractory oxide, a metal of the group VIII, and a metal of the group VIB. Said catalyst is characterised in that it also comprises at least one organic compound selected from the alkene diols of formula (I) wherein R1 represents a C2-10 alkenylene group, preferably C2-4 alkenylene, a C6-18 arylene group, or a C7-18 alkylene-arylene group, and each R2 independently represents a hydrogen atom or a C1-18 alkyl group, a C1-18 alkenyl group, a C6-18 aryl group, a C3-8 cycloalkyl group, or a C7-20 alkylaryl or arylalkyl group, or the two groups R2 together form a divalent C2-18 group, the carbonated chain of the R2 groups containing or carrying at least one heteroatom selected from S, N and O. The invention also relates to a method for preparing one such catalyst, and to the use of said catalyst for hydrotreatment or hydroconversion.

    摘要翻译： 本发明涉及一种烃加氢转化催化剂，其包含基于难熔氧化物的载体，第Ⅷ族金属和VIB族金属。 所述催化剂的特征在于其还包含至少一种选自式（I）的烯二醇的有机化合物，其中R 1代表C 2〜10亚烯基， 优选C 2-4亚烯基，C 6-18亚芳基或C 7-18亚烷基亚芳基，每个R 独立地表示氢原子或C 1-18烷基，C 1-18链烯基，C 6 -18芳基，C 3-8环烷基或C 7-20烷基芳基或芳基烷基，或两个基团R 1， 2一起形成二价C 2-18基团，含有或携带至少一个选自S，N的杂原子的R 2 2基团的碳酸化链和 本发明还涉及一种制备这种催化剂的方法，以及所述催化剂用于加氢处理或加氢转化的方法。

    Process for polymerization in a gaseous phase using heterogeneous catalysis and a spherical reactor for carrying out the process
    9.
    发明授权
    Process for polymerization in a gaseous phase using heterogeneous catalysis and a spherical reactor for carrying out the process 失效
    使用多相催化在气相中聚合的方法和用于进行该方法的球形反应器

    公开(公告)号：US4467080A

    公开(公告)日：1984-08-21

    申请号：US444872

    申请日：1982-11-29

    申请人： Claude Brun ,  Robert Pelletier

    发明人： Claude Brun ,  Robert Pelletier

    IPC分类号： C08F2/00 ,  B01F7/00 ,  B01F7/18 ,  B01F15/00 ,  B01F15/06 ,  B01J8/10 ,  C08F2/34 ,  C08F10/00

    CPC分类号： B01J8/10 ,  B01F15/00798 ,  B01F7/18 ,  C08F10/00 ,  B01F15/06 ,  B01F7/00208 ,  B01F7/00275 ,  B01J2219/187 ,  B01J2219/1942 ,  Y10S526/901 ,  Y10S526/904

    摘要： The invention relates to a process for polymerizing in an aqueous phase using heterogeneous catalysis and to a spherical reactor for carrying out said process. At least one monomer which is gaseous under the reaction conditions is just in contact with a solid catalyst in an agitated polymerization zone. The polymerization zone is defined by a spherical wall and the agitation is effected by means of a turbine unit having blades driven in rotation. The blades extend alongside the wall on 10 to 60% of its surface. The particles of the catalyst and the growing polymer powder are driven by centrifugal force onto at least a part of the spherical wall and fall back into the central part of the spherical zone, thereby ensuring a thorough and uniform mixing without any dead zone. The invention is useful for prepolymerizing or polymerizing olefins.

    摘要翻译： 本发明涉及使用多相催化在水相中聚合的方法和用于进行所述方法的球形反应器。 至少一种在反应条件下为气态的单体在搅拌聚合区中刚好与固体催化剂接触。 聚合区域由球形壁限定，并且通过具有旋转驱动的叶片的涡轮机单元进行搅拌。 叶片沿壁面延伸10至60％的表面。 催化剂和生长的聚合物粉末的颗粒通过离心力驱动到球形壁的至少一部分上并落回球形区域的中心部分，从而确保彻底均匀的混合而没有任何死区。 本发明可用于预聚合或聚合烯烃。