Process for hydrotreating hydrocarbon oil
    2.
    发明授权
    Process for hydrotreating hydrocarbon oil 失效
    加氢处理烃油的工艺

    公开(公告)号:US06328880B1

    公开(公告)日:2001-12-11

    申请号:US08704773

    申请日:1996-09-23

    CPC classification number: C10G65/12 C10G45/02 C10G65/16

    Abstract: Disclosed herein is a process for efficiently and stably producing high-quality kerosene and gas oil from crude oil or crude oil from which naphtha fraction is removed through the hydrotreatment of the crude oil by using a specific hydrotreatment catalyst; a process capable of prolonging the service life of the catalyst; a process capable of extending the continuous operation period of the process equipment; a process simplifying a petroleum refinery equipment; and the like. There are used, as hydrotreatment catalysts in the hydrotreatment of a hydrocarbon oil, the metals each belonging to any of the groups 6, 8, 9 and 10 of the Periodic Table which metals are supported on a carrier composed of alumina/boria, metal-containing aluminosilicate, alumina/an alkaline earth metal compound, alumina/phosphorus, alumina/titania or alumina/zirconia.

    Abstract translation: 本文公开了一种通过使用特定的加氢处理催化剂通过原油的加氢处理从原油或原油高效稳定地生产高品质煤油和瓦斯油的方法,其中石脑油馏分通过原油的加氢处理被除去; 能延长催化剂使用寿命的方法; 能够延长加工设备的连续运转期间的工序; 简化炼油设备的过程; 等等。 作为烃油加氢处理中的加氢处理催化剂,使用属于元素周期表第6,8,9和10族中的任何一种的金属,金属负载在由氧化铝/氧化硼,金属 - 含铝硅酸盐,氧化铝/碱土金属化合物,氧化铝/磷,氧化铝/二氧化钛或氧化铝/氧化锆。

    Hydrotreating process for residual oil
    5.
    发明授权
    Hydrotreating process for residual oil 失效
    残油加氢处理

    公开(公告)号:US06406615B1

    公开(公告)日:2002-06-18

    申请号:US09463387

    申请日:2000-03-01

    CPC classification number: C10G49/002 C10G45/04 C10G65/04

    Abstract: The invention relates to a method of heavy oil hydrogenation, precisely to a method of heavy oil hydrogenation for which a part of the catalyst to be used is a regenerated catalyst, and concretely to a method of heavy oil denitrification and to a method of heavy of desulfurization. It is characterized in that heavy oil is passed through a layer of a regenerated catalyst or a layer containing a regenerated catalyst. With the specific catalyst disposition employed in the method, heavy oil can be well hydrogenated under the same conditions as those for ordinary heavy oil hydrogenation with fresh catalysts. The method is significantly effective for efficient utilization of used catalysts.

    Abstract translation: 本发明涉及一种重油加氢的方法,精确地涉及一种重油加氢方法,其中所用催化剂的一部分是再生催化剂,具体涉及一种重油脱氮方法, 脱硫。 其特征在于,重油通过再生催化剂层或含有再生催化剂的层。 在该方法中使用的具体催化剂配置中,在与新鲜催化剂的普通重油氢化相同的条件下,重油可以很好地氢化。 该方法对于有效利用所用催化剂是显着有效的。

    Hydrotreating catalyst and processes for hydrotreating hydrocarbon oil with the same
    6.
    发明授权
    Hydrotreating catalyst and processes for hydrotreating hydrocarbon oil with the same 失效
    加氢处理催化剂及其加氢处理烃油

    公开(公告)号:US06267874B1

    公开(公告)日:2001-07-31

    申请号:US09341759

    申请日:1999-09-27

    CPC classification number: B01J23/85 B01J21/12 C10G45/08 C10G49/04

    Abstract: The present invention relates to a hydrotreating catalyst composed of a carrier having a Brønsted acid content of at least 50 &mgr;mol/g such as a silica-alumina carrier or a silica-alumina-third component carrier, in which the silica is dispersed to high degree and a Brønsted acid content is at least 50 &mgr;mol/g, and at least one active component (A) selected from the elements of Group 8 of the Periodic Table and at least one active component (B) selected from the elements of Group 6 of the Periodic Table, supported on said carrier. The present invention also relates to a method for hydrotreating hydrocarbon oils using the same. The hydrotreating catalyst of the present invention provides excellent tolerance to the inhibiting effect of hydrogen sulfide, high desulfurization activity, and exhibits notable effects for deep desulfurization of hydrocarbon oils containing high contents of sulfur, in particular gas oil fractions containing difficult-to-remove sulfur compounds. The hydrotreating catalyst of the present invention is also very effective for hydrodenitrogenation, hydrocracking, hydrodearomatization, hydroisomerization, hydrofining and the like of hydrocarbon oils.

    Abstract translation: 本发明涉及一种由布朗斯台德酸含量至少为50mumol / g的载体组成的加氢处理催化剂,例如二氧化硅 - 氧化铝载体或二氧化硅 - 氧化铝 - 第三成分载体,其中二氧化硅被高分散 布朗斯台德酸含量为至少50莫莫/克,和至少一种选自元素周期表第8族元素的活性组分(A)和至少一种活性组分(B),选自 所述载体支持周期表。 本发明还涉及使用其加氢处理烃油的方法。 本发明的加氢处理催化剂对硫化氢的抑制作用具有优异的耐受性,脱硫活性高,并且对含有高含量硫的烃油,特别是含有难以除去的硫的瓦斯油馏分进行深度脱硫,具有显着的效果 化合物。 本发明的加氢处理催化剂对烃油的加氢脱氮,加氢裂化,加氢脱芳构化,加氢异构化,加氢精制等也是非常有效的。

    Process for effecting deep HDS of hydrocarbon feedstocks
    8.
    发明授权
    Process for effecting deep HDS of hydrocarbon feedstocks 失效
    实现烃原料深度HDS的方法

    公开(公告)号:US06531054B1

    公开(公告)日:2003-03-11

    申请号:US09049938

    申请日:1998-03-30

    CPC classification number: C10G65/04

    Abstract: The invention pertains to a process for reducing the sulphur content of a hydrocarbon feedstock to a value of less than 500 ppm, which process comprises contacting a feedstock with a 95% boiling point of 450° C. or less and a sulphur content of 0.1 wt. % or more in the presence of hydrogen under conditions of elevated temperature and pressure with a first catalyst comprising a Group VI hydrogenation metal component and a Group VIII hydrogenation metal component on an oxidic carrier, after which at least part of the effluent from the first catalyst is led to a second catalyst comprising a Group VI hydrogenation metal component and a Group VIII hydrogenation metal component on an oxidic carrier which comprises 1 to 15 wt. % of silica, calculated on the weight of the catalyst. The use of a silica-containing catalyst in the second bed shows an improvement over the use of a second catalyst with an alumina carrier in the production of products with a sulphur content of less than 500 ppm, preferably less than 350 ppm. An improvement in hydrodenitrogenation activity is also obtained.

    Abstract translation: 本发明涉及一种将烃原料的硫含量降低到小于500ppm的方法,该方法包括使原料与95℃沸点450℃或更低,硫含量为0.1wt 。 在高温和高压条件下,在含有第VI族氢化金属组分和第Ⅷ族加氢金属组分的第一催化剂的氧化载体上,在氢气存在下,还可以含有至少一部分来自第一催化剂 被引入到包含1至15重量%的氧化载体上的第VI族氢化金属组分和第VIII族氢化金属组分的第二种催化剂。 二氧化硅的百分比以催化剂的重量计算。在第二床中使用含二氧化硅的催化剂显示出在使用具有氧化铝载体的第二催化剂用于生产硫含量小于 500ppm,优选小于350ppm。 也可获得加氢脱氮活性的改善。

    Process for converting heavy petroleum fractions in an ebullated bed, with addition of a pre-conditioned catalyst
    9.
    发明授权
    Process for converting heavy petroleum fractions in an ebullated bed, with addition of a pre-conditioned catalyst 有权
    通过加入预调节的催化剂在沸腾床中转化重质石油馏分的方法

    公开(公告)号:US06187174B1

    公开(公告)日:2001-02-13

    申请号:US09233206

    申请日:1999-01-19

    CPC classification number: C10G49/12

    Abstract: A process for converting a heavy hydrocarbon fraction comprises a step a) for treating a hydrocarbon feed in a hydroconversion section in the presence of hydrogen, the section comprising at least one three-phase reactor containing at least one ebullated bed of hydroconversion catalyst operating in riser mode for liquid and for gas, said reactor comprising at least one means for extracting used catalyst from said reactor and at least one means for adding fresh catalyst to said reactor, b) a step for treating fresh catalyst and conditioning the catalyst using a process leading to a gain in the activity of the catalyst during treatment of the feed in said conversion reactor. This process for conditioning the catalyst before adding it to the reactor can comprise a step for impregnating the catalyst with a chemical substance, or a complete sulphurisation step, or a step for adding an additive mixed with the fresh catalyst which is added.

    Abstract translation: 用于转化重质烃馏分的方法包括步骤a)在氢的存在下在加氢转化段中处理烃进料,所述部分包含至少一个三相反应器,其包含至少一个在提升管中操作的加氢转化催化剂沸腾床 所述反应器包括至少一种用于从所述反应器中提取使用的催化剂的装置和用于将新鲜催化剂加入到所述反应器中的至少一种装置,b)用于处理新鲜催化剂并使用过程引导进行调节的步骤 在所述转化反应器中的进料处理期间催化剂的活性增加。 在将催化剂加入到反应器中之前调节催化剂的该方法可以包括用化学物质或完全硫化步骤浸渍催化剂的步骤,或用于加入与添加的新鲜催化剂混合的添加剂的步骤。

    Hydrotreating catalyst for heavy hydrocarbon oil, process for producing the catalyst, and hydrotreating method using the same
    10.
    发明授权
    Hydrotreating catalyst for heavy hydrocarbon oil, process for producing the catalyst, and hydrotreating method using the same 有权
    用于重质烃油的加氢处理催化剂,用于生产催化剂的方法和使用该催化剂的加氢处理方法

    公开(公告)号:US06174432B1

    公开(公告)日:2001-01-16

    申请号:US09331244

    申请日:1999-06-17

    CPC classification number: B01J21/02 B01J23/24 C10G45/04

    Abstract: A hydrotreating catalyst for heavy hydrocarbon oil, which comprises a boron-containing alumina carrier containing from 1 to 12 wt %, in terms of an oxide, of boron based on the catalyst, having supported thereon a metal in the Group VI, wherein the catalyst has an average pore size of from 19 to 25 nm, a pore volume of from 0.65 to 0.8 ml/g, a catalyst strength of 3 lb/mm or more, and a specific surface area of from 70 to 130 m2/g; a process for producing the hydrotreating catalyst; and a method for hydrotreating heavy hydrocarbon oil, which comprises conducting a catalytic reaction of heavy hydrocarbon oil in the presence of the catalyst composition at a temperature of from 300 to 500° C., a pressure of from 3 to 20 MPa, a hydrogen/oil ratio of from 400 to 3000 Nl/l, and LHSV of from 0.1 to 1.5 hr−1.

    Abstract translation: 一种用于重烃油的加氢处理催化剂,其包含含有氧化物1至12重量%的含硼氧化铝载体,基于催化剂的硼,其中载有第VI族中的金属,其中催化剂 平均孔径为19〜25nm,孔体积为0.65〜0.8ml / g,催化剂强度为3lb / mm以上,比表面积为70〜130m2 / g, 加氢处理催化剂的制造方法; 以及加氢处理重质烃油的方法,其包括在催化剂组合物存在下,在300〜500℃,压力为3〜20MPa,氢/ 油比为400至3000Nl / l,LHSV为0.1至1.5hr-1。

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