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1.发明授权Integrating an air separation unit into an oxygenate-to-olefins reaction system 有权将空气分离单元整合到含氧化合物 - 烯烃反应体系中公开(公告)号：US07479468B2
公开(公告)日：2009-01-20
申请号：US10825569
申请日：2004-04-15
申请人： Cor F. van Egmond , Eric D. Nelson , Lawrence C. Smith , Ronald G. Searle , James H. Beech, Jr. , Michael P. Nicoletti
发明人： Cor F. van Egmond , Eric D. Nelson , Lawrence C. Smith , Ronald G. Searle , James H. Beech, Jr. , Michael P. Nicoletti
IPC分类号： B01J20/34
CPC分类号： B01J38/30 , B01J38/14 , B01J38/32 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/1022 , C10G2300/1025 , C10G2300/207 , C10G2400/20 , F25J3/04157 , F25J3/04412 , F25J3/04527 , F25J3/04539 , F25J3/04563 , F25J3/046 , F25J2200/20 , F25J2205/32 , F25J2215/40 , Y02P30/20
摘要： This invention provides an integrated system and process for forming light olefins and polymers from oxygenates, and optionally from natural gas. The integrated system includes an air separation unit, which separates air components into an oxygen stream and a nitrogen stream, and which also forms a compressed air stream. According to the present invention, the oxygen stream, the nitrogen stream and/or the compressed air stream from the air separation unit may serve as a reactant in syngas generation, as a regeneration medium in the methanol-to-olefins reaction system, as a fluidizing stream, as a blanketing medium, as a stripping medium, as instrument air, and/or as a reactant in a sulfur removal unit.
摘要翻译： 本发明提供了一种用于从含氧化合物和任选地从天然气形成轻质烯烃和聚合物的集成系统和方法。 集成系统包括空气分离单元，其将空气组分分离成氧气流和氮气流，并且还形成压缩空气流。 根据本发明，来自空气分离单元的氧气流，氮气流和/或压缩空气流可用作合成气生成中的反应物，作为甲醇 - 烯烃反应体系中的再生介质，作为 流化流，作为遮盖介质，作为汽提介质，作为仪器空气，和/或作为硫去除单元中的反应物。
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2.发明授权Process for recovering and reusing water in an oxygenate-to-olefin process 有权在含氧化合物至烯烃过程中回收和再利用水的方法公开(公告)号：US07626067B2
公开(公告)日：2009-12-01
申请号：US10870185
申请日：2004-06-17
CPC分类号： C07C1/20 , C07C2529/00 , C07C2529/85 , Y02P30/42 , C07C11/02
摘要： The present invention is a process for cleaning and using byproduct water from an oxygenate to olefin process to satisfy the water requirement of the oxygenate to olefin process.
摘要翻译： 本发明是一种清洁和使用从含氧化合物到烯烃工艺的副产物水以满足含氧化合物对烯烃过程的需水量的方法。
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3.发明授权Treating oxygenate containing feedstreams in the conversion of oxygenates to olefins 有权在含氧化合物转化为烯烃的过程中，处理含氧化合物的进料流公开(公告)号：US07385100B2
公开(公告)日：2008-06-10
申请号：US11787337
申请日：2007-04-16
申请人： James H. Beech, Jr. , Cor F. Van Egmond , Ronald G. Searle , Michael Peter Nicoletti , David Ritchie Lumgair, Jr.
发明人： James H. Beech, Jr. , Cor F. Van Egmond , Ronald G. Searle , Michael Peter Nicoletti , David Ritchie Lumgair, Jr.
CPC分类号： C07C1/20 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42 , C07C11/02
摘要： This invention is directed to removing contaminants from an oxygenate-containing feedstream for an oxygenate to olefin reaction system. Oxygenate feeds used in the conversion of oxygenates to olefins, and which contain contaminants, are heated to form a vapor stream and a liquid stream. The heating is conducted so that a majority of the metalloaluminophosphate molecular sieve catalyst contaminants is contained in the liquid stream. The vapor stream is separated from the liquid stream, and the separated vapor stream is contacted with the metalloaluminophosphate molecular sieve catalyst to form olefin product. The heating of the feedstream and the separation of the vapor stream can be carried out in one or more stages.
摘要翻译： 本发明涉及从用于含氧化合物到烯烃反应体系的含氧化合物的进料流中除去污染物。 用于将含氧化合物转化为烯烃并且含有污染物的氧化物进料被加热以形成蒸汽流和液体流。 进行加热，使得大部分金属铝磷酸盐分子筛催化剂污染物被包含在液体流中。 将蒸汽流与液体流分离，并将分离的蒸汽流与金属铝磷酸盐分子筛催化剂接触以形成烯烃产物。 进料流的加热和蒸汽流的分离可以在一个或多个阶段中进行。
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4.发明授权Treating oxygenate containing feedstreams in the conversion of oxygenates to olefins 有权在含氧化合物转化为烯烃的过程中，处理含氧化合物的进料流公开(公告)号：US07214843B2
公开(公告)日：2007-05-08
申请号：US10686461
申请日：2003-10-14
申请人： James H. Beech, Jr. , Cor. F. Van Egmond , Ronald G. Searle , Michael Peter Nicoletti , David Ritchie Lumgair, Jr.
发明人： James H. Beech, Jr. , Cor. F. Van Egmond , Ronald G. Searle , Michael Peter Nicoletti , David Ritchie Lumgair, Jr.
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42 , C07C11/02
摘要： This invention is directed to removing contaminants from an oxygenate-containing feedstream for an oxygenate to olefin reaction system. Oxygenate feeds used in the conversion of oxygenates to olefins, and which contain contaminants, are heated to form a vapor stream and a liquid stream. The heating is conducted so that a majority of the metalloaluminophosphate molecular sieve catalyst contaminants is contained in the liquid stream. The vapor stream is separated from the liquid stream, and the separated vapor stream is contacted with the metalloaluminophosphate molecular sieve catalyst to form olefin product. The heating of the feedstream and the separation of the vapor stream can be carried out in one or more stages.
摘要翻译： 本发明涉及从用于含氧化合物到烯烃反应体系的含氧化合物的进料流中除去污染物。 用于将含氧化合物转化为烯烃并且含有污染物的氧化物进料被加热以形成蒸汽流和液体流。 进行加热，使得大部分金属铝磷酸盐分子筛催化剂污染物被包含在液体流中。 将蒸汽流与液体流分离，并将分离的蒸汽流与金属铝磷酸盐分子筛催化剂接触以形成烯烃产物。 进料流的加热和蒸汽流的分离可以在一个或多个阶段中进行。
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公开(公告)号：US07404891B2
公开(公告)日：2008-07-29
申请号：US10812142
申请日：2004-03-29
CPC分类号： C10G11/185 , C10G3/49 , C10G3/57 , C10G3/62 , C10G9/00 , C10G2300/4006 , C10G2300/4012 , C10G2300/807 , C10G2400/20 , Y02P30/20 , Y02P30/42
摘要： A technique for recovering heat from a high temperature effluent stream from catalyst regeneration or the like, comprising processes and means for: (a) passing the effluent stream in heat exchange relationship in a steam generator with boiler feed water to produce high pressure steam and partially cool the effluent stream; (b) passing the partially cooled effluent stream from the steam regenerator in heat exchange relationship to preheat high pressure boiler feed water and further cool the effluent stream; and (c) passing the preheated boiler feed water to the steam generator. The apparatus and processes for thermal energy recovery may be used to treat hot regenerator effluent from FCC or OTO-type processes, thereby producing a cooled flue gas stream to discharge to ambient atmosphere.
摘要翻译： 一种用于从催化剂再生等的高温流出物流中回收热量的技术，包括以下步骤和装置的方法和装置：（a）将蒸汽发生器中的热交换关系的流出物流与锅炉给水通过以产生高压蒸汽和部分 冷却流出物流; （b）将来自蒸汽再生器的部分冷却的流出物与热交换关系传递到预热的高压锅炉给水中，并进一步冷却流出物流; 和（c）将预热的锅炉给水送到蒸汽发生器。 用于热能回收的装置和方法可以用于处理来自FCC或OTO型方法的热再生器流出物，从而产生冷却的烟气流以排放到环境大气中。
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公开(公告)号：US06965057B2
公开(公告)日：2005-11-15
申请号：US10807818
申请日：2004-03-24
CPC分类号： C07C1/20 , B01J38/30 , B01J38/32 , C10G3/49 , C10G3/62 , C10G2300/4093 , C10G2300/708 , C10G2300/802 , C10G2300/805 , C10G2400/20 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The invention relates to a process for converting an oxygenate feedstock into an olefin product stream comprising (a) contacting an oxygenate feedstock with a molecular sieve catalyst in a reactor under conditions effective to convert the feedstock into an olefin product stream and to form carbonaceous deposits on the catalyst; (b) contacting at least a portion of the catalyst having said carbonaceous deposits with an oxygen containing gas under conditions effective to obtain a regenerated catalyst having a reduced carbonaceous deposit level and having an increased molecular oxygen content; (c) removing at least 60% by volume of said molecular oxygen from the regenerated catalyst based upon the total volume of molecular oxygen; (d) returning said regenerated catalyst to said reactor; and (e) repeating steps (a)–(d).
摘要翻译： 本发明涉及一种将含氧化合物原料转化成烯烃产物流的方法，该方法包括（a）在有效将原料转化成烯烃产物流并形成碳质沉积物的条件下，使反应器中的含氧化合物原料与分子筛催化剂接触 催化剂; （b）在有效获得具有降低的碳沉积物水平并且具有增加的分子氧含量的再生催化剂的条件下使至少一部分具有所述碳质沉积物的催化剂与含氧气体接触; （c）基于分子氧的总体积从再生催化剂中除去至少60体积％的所述分子氧; （d）将所述再生催化剂返回到所述反应器; 和（e）重复步骤（a） - （d）。
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公开(公告)号：US07816575B2
公开(公告)日：2010-10-19
申请号：US11651815
申请日：2007-01-10
IPC分类号： C07C1/00
CPC分类号： B01J8/0075 , B01J8/0055 , B01J8/228 , B01J2208/00265 , B01J2219/00006 , B03C3/017 , B03C3/41 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/805 , C10G2400/20 , Y02P30/20 , Y10S585/91 , C07C11/02
摘要： This invention provides a process for limiting the loss of catalyst particles through olefin product streams and regenerator flue gas streams exiting the reaction system. In particular, this invention provides for removing catalyst particles from the reactor using a water stream and from the regenerator using a two step separation process. The two step process involves the use of a catalyst fine separation unit.
摘要翻译： 本发明提供了一种通过离开反应体系的烯烃产物流和再生器烟气流来限制催化剂颗粒的损失的方法。 特别地，本发明提供使用水流和使用两步分离方法从再生器从反应器中除去催化剂颗粒。 两步法包括使用催化剂精细分离单元。
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8.发明授权Method and apparatus for regenerating catalyst during oxygenates to olefins reaction 有权在含氧化合物到烯烃反应过程中再生催化剂的方法和装置公开(公告)号：US08178741B2
公开(公告)日：2012-05-15
申请号：US12793340
申请日：2010-06-03
申请人： Chunshe J. Cao , James H. Beech, Jr. , Michael P. Nicoletti , Thomas H. Colle , Teng Xu , Stephen N. Vaughn
发明人： Chunshe J. Cao , James H. Beech, Jr. , Michael P. Nicoletti , Thomas H. Colle , Teng Xu , Stephen N. Vaughn
CPC分类号： B01J38/02 , B01J29/90 , B01J38/32 , C07C1/20 , C07C2529/85 , Y02P20/584 , C07C11/02
摘要： Disclosed herein is a method of recovery of the activity of a molecular sieve catalyst following use of the catalyst in an OTO conversion process. This is achieved by a regeneration apparatus and a method of regenerating a molecular sieve catalyst, comprising two stages. In a pretreatment stage, the catalyst is pretreated under pretreatment conditions by heating the catalyst to a temperature of between 320° C. to 700° C. in an oxygen depleted medium for a residence time of between 1 minute to two hours; and, in a regeneration stage, the catalyst is regenerated under regeneration conditions by heating the catalyst at a temperature of between 200° C. to 700° C. in an oxidizing medium for a residence time of between 1 to 60 minutes.
摘要翻译： 本文公开了在OTO转化方法中使用催化剂后回收分子筛催化剂的活性的方法。 这是通过再生装置和再生分子筛催化剂的方法实现的，包括两个阶段。 在预处理阶段，催化剂在预处理条件下通过将催化剂在耗氧贫乏的介质中在320℃至700℃之间的温度下进行预处理，停留时间为1分钟至2小时; 并且在再生阶段，催化剂在再生条件下通过在氧化介质中在200℃至700℃的温度下加热催化剂，停留时间为1至60分钟而再生。
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公开(公告)号：US07989669B2
公开(公告)日：2011-08-02
申请号：US12034425
申请日：2008-02-20
IPC分类号： C07C2/02
摘要： This invention is directed to a process for producing one or more olefins from an oxygenate feed. According to the invention, an oxygenate stream is provided and a recycle stream is added to the oxygenate stream to form a feed stream to an oxygenate-to-olefin conversion system. The recycle stream comprises (i.e., contains) propane and dimethyl ether.
摘要翻译： 本发明涉及从含氧化合物原料生产一种或多种烯烃的方法。 根据本发明，提供含氧化合物流，并将再循环物流加入到含氧化合物物流中以形成向含氧化合物至烯烃转化体系的进料流。 回收料流包含（即含有）丙烷和二甲醚。
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10.发明授权Method of circulating catalyst between a catalyst regenerator and an external catalyst cooler 有权在催化剂再生器和外部催化剂冷却器之间循环催化剂的方法公开(公告)号：US07906697B2
公开(公告)日：2011-03-15
申请号：US12059717
申请日：2008-03-31
申请人： James H. Beech, Jr. , Chunshe Cao , Michael P. Nicoletti , James R. Lattner , Jesse F. Goellner , Rutton D. Patel , Timothy M. Healy
发明人： James H. Beech, Jr. , Chunshe Cao , Michael P. Nicoletti , James R. Lattner , Jesse F. Goellner , Rutton D. Patel , Timothy M. Healy
IPC分类号： C07C2/04
CPC分类号： C07C1/20 , B01J29/90 , B01J38/30 , B01J38/32 , C07C2529/40 , C07C2529/70 , C07C2529/83 , C07C2529/85 , C10G3/49 , C10G3/62 , C10G2300/802 , C10G2400/20 , Y02P20/584 , Y02P30/20 , C07C11/02
摘要： This invention relates to efficiently regenerating catalyst particles by minimizing the formation of localized “hot spots” and “cold spots” in a regeneration zone. Specifically this invention relates to a method for controlling regenerator temperature in an oxygenates-to-olefins system, comprising the steps of: contacting an oxygenate feed in a reactor with a catalytically effective amount of molecular sieve-containing catalyst under conditions effective for converting said oxygenate to a product containing light olefins and forming a coked catalyst; contacting a portion of the coked catalyst in a regenerator, having a catalyst bed height (Hc), an inlet height (Hi), and an outlet height (Ho), with an oxygen-containing regeneration medium under conditions effective to at least partially regenerate the coked catalyst; and conducting a portion of the catalyst from the regenerator to a catalyst cooler to form a cooled catalyst portion, wherein Ho is greater than Hi.
摘要翻译： 本发明涉及通过最小化再生区中局部“热点”和“冷点”的形成来有效地再生催化剂颗粒。 具体地说，本发明涉及一种用于控制含氧化合物至烯烃体系中的再生器温度的方法，其包括以下步骤：在有效转化所述含氧化合物的条件下使反应器中的含氧化合物进料与催化有效量的含分子筛催化剂接触 涉及含有轻质烯烃并形成焦化催化剂的产品; 在具有催化剂床高度（Hc），入口高度（Hi）和出口高度（Ho））的再生器中使一部分焦化催化剂与含氧再生介质在有效至少部分再生的条件下接触 焦化催化剂; 并将催化剂的一部分从再生器导入催化剂冷却器以形成冷却的催化剂部分，其中Ho大于Hi。
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