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公开(公告)号:US20090221724A1
公开(公告)日:2009-09-03
申请号:US12355077
申请日:2009-01-16
CPC分类号: B01J37/031 , B01J23/80 , B01J35/002 , B01J35/023 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/03 , C10G2/332
摘要: The present invention relates to a catalyst comprising particles of a cobalt and zinc co-precipitate, having a volume average particle size of less than 150 μm. Another aspect of the invention is the use of such a catalyst in a Fischer-Tropsch process.The present invention further relates to a method for preparing a catalyst comprising cobalt and zinc oxide, wherein an acidic solution comprising zinc ions and cobalt ions and a alkaline solution are contacted and the precipitate is isolated.
摘要翻译: 本发明涉及包含体积平均粒径小于150μm的钴和锌共沉淀物颗粒的催化剂。 本发明的另一方面是在费 - 托方法中使用这种催化剂。 本发明还涉及一种制备包含钴和氧化锌的催化剂的方法,其中包含锌离子和钴离子的酸性溶液和碱性溶液接触并分离沉淀物。
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公开(公告)号:US20090197981A1
公开(公告)日:2009-08-06
申请号:US12268908
申请日:2008-11-11
CPC分类号: B01J23/80 , B01J21/06 , B01J21/066 , B01J23/83 , B01J23/8896 , B01J23/8953 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/03 , C07C1/0435 , C07C29/141 , C07C2523/75 , C10G2/332
摘要: The present invention is directed to a catalyst suitable for catalyzing a Fischer-Tropsch reaction, said catalyst comprising cobalt metal supported on zinc-oxide and having the following particle size distribution by volume:
摘要翻译: 本发明涉及适用于催化费 - 托反应的催化剂,所述催化剂包含负载在氧化锌上的钴金属,并具有以下体积分布的粒径分布:<10%粒径小于1微米,70- 99%具有1至5微米的粒度,和<20%的粒度在5微米以上。
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公开(公告)号:US08778832B2
公开(公告)日:2014-07-15
申请号:US12268908
申请日:2008-11-11
IPC分类号: C07C27/10 , B01J23/80 , B01J23/10 , C07C29/141 , C10G2/00 , B01J35/02 , B01J37/03 , B01J21/06 , B01J35/10 , B01J23/889 , B01J23/89 , B01J23/83
CPC分类号: B01J23/80 , B01J21/06 , B01J21/066 , B01J23/83 , B01J23/8896 , B01J23/8953 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/03 , C07C1/0435 , C07C29/141 , C07C2523/75 , C10G2/332
摘要: The present invention is directed to a catalyst suitable for catalyzing a Fischer-Tropsch reaction, said catalyst comprising cobalt metal supported on zinc-oxide and having the following particle size distribution by volume:
摘要翻译: 本发明涉及适用于催化费 - 托反应的催化剂,所述催化剂包含负载在氧化锌上的钴金属,并具有以下体积分布的粒径分布:<10%粒径小于1微米,70- 99%具有1至5微米的粒度,和<20%的粒度在5微米以上。
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公开(公告)号:US07884139B2
公开(公告)日:2011-02-08
申请号:US12355077
申请日:2009-01-16
CPC分类号: B01J37/031 , B01J23/80 , B01J35/002 , B01J35/023 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/03 , C10G2/332
摘要: The present invention relates to a catalyst comprising particles of a cobalt and zinc co-precipitate, having a volume average particle size of less than 150 μm. Another aspect of the invention is the use of such a catalyst in a Fischer-Tropsch process.The present invention further relates to a method for preparing a catalyst comprising cobalt and zinc oxide, wherein an acidic solution comprising zinc ions and cobalt ions and a alkaline solution are contacted and the precipitate is isolated.
摘要翻译: 本发明涉及包含体积平均粒度小于150μm的钴和锌共沉淀物颗粒的催化剂。 本发明的另一方面是在费 - 托方法中使用这种催化剂。 本发明还涉及一种制备包含钴和氧化锌的催化剂的方法,其中包含锌离子和钴离子的酸性溶液和碱性溶液接触并分离沉淀物。
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公开(公告)号:US07563747B2
公开(公告)日:2009-07-21
申请号:US10512656
申请日:2003-04-22
CPC分类号: B01J37/031 , B01J23/80 , B01J35/002 , B01J35/023 , B01J35/026 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/03 , C10G2/332
摘要: The present invention relates to a catalyst comprising particles of a cobalt and zinc co-precipitate, having a volume average particle size of less than 150 μm. Another aspect of the invention is the use of such a catalyst in a Fischer-Tropsch process. The present invention further relates to a method for preparing a catalyst comprising cobalt and zinc oxide, wherein an acidic solution comprising zinc ions and cobalt ions and a alkaline solution are contacted and the precipitate is isolated.
摘要翻译: 本发明涉及包含体积平均粒径小于150μm的钴和锌共沉淀物颗粒的催化剂。 本发明的另一方面是在费 - 托方法中使用这种催化剂。 本发明还涉及一种制备包含钴和氧化锌的催化剂的方法,其中包含锌离子和钴离子的酸性溶液和碱性溶液接触并分离沉淀物。
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公开(公告)号:US20110021646A1
公开(公告)日:2011-01-27
申请号:US12838793
申请日:2010-07-19
CPC分类号: B01J23/80 , B01J23/002 , B01J35/023 , B01J35/1014 , B01J35/1038 , B01J37/03 , B01J2523/00 , C10G2/332 , B01J2523/27 , B01J2523/31 , B01J2523/845 , B01J2523/48
摘要: The present invention is directed to a catalyst suitable for catalyzing a Fischer-Tropsch reaction, said catalyst comprising cobalt metal supported on zinc-oxide and an amount of zirconium(IV)oxide and/or aluminium oxide of between 0.5 and 2.5 wt. % calculated as metal, based on the weight of the calcined catalyst.
摘要翻译: 本发明涉及适用于催化费 - 托反应的催化剂,所述催化剂包含负载在氧化锌上的钴金属和一定量的氧化锆(Ⅳ)和/或氧化铝,其含量为0.5-2.5wt。 %计算为金属,基于煅烧催化剂的重量。
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公开(公告)号:US20090048353A1
公开(公告)日:2009-02-19
申请号:US12140740
申请日:2008-06-17
IPC分类号: C07C1/00 , C07C211/01
CPC分类号: B01J23/60 , B01J23/80 , B01J35/006 , B01J35/008 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/0221 , B01J37/0242 , C07C209/48 , C10G2/332 , C10G2/333
摘要: The present invention relates to a catalyst comprising a preferably oxidic, core material, a shell of zinc oxide around said core material, and a catalytically active material in or on the shell, based on one or more of the metals cobalt, iron, ruthenium and/or nickel, preferably a Fischer-Tropsch catalyst, to the preparation of such a catalyst and the use thereof in GTL processes.
摘要翻译: 本发明涉及一种催化剂,其基于一种或多种金属钴,铁,钌和/或其中的一种或多种,包括优选氧化物核心材料,围绕所述芯材料的氧化锌壳和壳中或其上的催化活性材料 /或镍,优选费 - 托催化剂,制备这种催化剂及其在GTL方法中的应用。
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公开(公告)号:US07422995B2
公开(公告)日:2008-09-09
申请号:US10836445
申请日:2004-04-30
CPC分类号: B01J23/60 , B01J23/80 , B01J35/008 , B01J37/0221 , B01J37/0242 , C10G2/332 , Y02P20/582
摘要: The present invention relates to a Catalyst comprising a, preferably oxidic, core material, a shell of zinc oxide around said core material, and a catalytically active material in or on the shell, based on one or more of the metals cobalt, iron, ruthenium and/or nickel, preferably a Fischer-Tropsch catalyst, to the preparation of such a catalyst and the use thereof in GTL processes.
摘要翻译: 本发明涉及一种催化剂,其基于一种或多种金属钴,铁,钌,包括优选氧化的芯材料,围绕所述芯材料的氧化锌壳和壳中或其上的催化活性材料 和/或镍,优选费 - 托催化剂,用于制备这种催化剂及其在GTL方法中的应用。
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公开(公告)号:US08476321B2
公开(公告)日:2013-07-02
申请号:US12838793
申请日:2010-07-19
CPC分类号: B01J23/80 , B01J23/002 , B01J35/023 , B01J35/1014 , B01J35/1038 , B01J37/03 , B01J2523/00 , C10G2/332 , B01J2523/27 , B01J2523/31 , B01J2523/845 , B01J2523/48
摘要: The present invention is directed to a catalyst suitable for catalyzing a Fischer-Tropsch reaction, said catalyst comprising cobalt metal supported on zinc-oxide and an amount of zirconium(IV)oxide and/or aluminum oxide of between 0.5 and 2.5 wt. % calculated as metal, based on the weight of the calcined catalyst.
摘要翻译: 本发明涉及适用于催化费 - 托反应的催化剂,所述催化剂包含负载在氧化锌上的钴金属和一定量的氧化锆(Ⅳ)和/或氧化铝,其含量为0.5-2.5wt。 %计算为金属,基于煅烧催化剂的重量。
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公开(公告)号:US07846977B2
公开(公告)日:2010-12-07
申请号:US12140740
申请日:2008-06-17
IPC分类号: C07C1/00 , C07C211/01 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号: B01J23/60 , B01J23/80 , B01J35/006 , B01J35/008 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/0221 , B01J37/0242 , C07C209/48 , C10G2/332 , C10G2/333
摘要: The present invention relates to a catalyst comprising a preferably oxidic, core material, a shell of zinc oxide around said core material, and a catalytically active material in or on the shell, based on one or more of the metals cobalt, iron, ruthenium and/or nickel, preferably a Fischer-Tropsch catalyst, to the preparation of such a catalyst and the use thereof in GTL processes.
摘要翻译: 本发明涉及一种催化剂,其基于一种或多种金属钴,铁,钌和/或其中的一种或多种,包括优选氧化物核心材料,围绕所述芯材料的氧化锌壳和壳中或其上的催化活性材料 /或镍,优选费 - 托催化剂,制备这种催化剂及其在GTL方法中的应用。
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