摘要:
Aminosiloxanes bearing 4-amino-3,3-dialkylbutyl substituents are prepared by a multistep process including addition of 2,2-dialkylacetonitrile to vinylic siloxanes, hydrogenation of the nitrile adducts so formed to yield 4-amino-3,3-dialkylbutyl siloxanes, and optional equilibration of the latter with other siloxane sources, to form aminosiloxanes, which are useful for the treatment of textiles and fabrics and for the preparation of siloxane-containing block copolymers.
摘要:
Aminopolysiloxanes of the following structure Q.sub.2 RSiO-- (SiR.sub.2 O).sub.x -(SiRR.sup.1 O).sub.y -SiRQ.sub.2 wherein R is a monovalent hydrocarbon group having 1 to 10 carbon atoms including alkyl, aryl and aralkyl groups; R.sup.1 is CH.sub.2 --CH.sub.2 --C--(CH.sub.3).sub.2 --CH.sub.2 --NHR.sup.2, R.sup.2 is hydrogen, an alkyl of C.sub.1 -C.sub.6, an alkyl amine of C.sub.1 -C.sub.6, or an alkanolamine of C.sub.1 -C.sub.6 ; Q is R, R.sup.1, hydroxyl, or an alkoxy of C.sub.1 -C.sub.4. x can be zero or integer; y is an integer, with x+y being less than 1,100, for use in various applications, including softening textiles.
摘要:
Polyether modified fluoroalkylsiloxanes having the general structure of Formula (I), Formula (II) or Formula (III): ##STR1## wherein x is about 0 to 500, y is about 1 to 50, z is about 1 to 50, R=C.sub.p H.sub.2p --(OC.sub.2 H.sub.4).sub.n --(OC.sub.3 H.sub.6).sub.n).sub.m --OR' in which p is about 2 to 5, n is about 0 to 50, N is about 0 to 50, and one of n or m must be >0, and R'=H, an alkyl group with 1-4 carbons, or an acetyl group and R.sub.f =C.sub.a H.sub.2a --O.sub.b --C.sub.c H.sub.2c --C.sub.d F.sub.2d+1 in which a is 3 or 4, b is 0 or 1, c is 0 or 2-4 and d is 4-12 with the provisos that if b=0, then c=0, and that if b=1, then c=2-4; z.sub.1 is about 0 to 50 and y.sub.1 is about 0 to 50, are useful to reduce the coefficient of friction and to increase mar resistance of coatings, to increase spreadability and wettability of coating formulations, and as foam control agents.
摘要:
Linear alkylsilicone compounds of the formula ##STR1## wherein x=0 to 20, preferably 0 to 10, most preferably 0 to 1; y=1 to 10, preferably 1 to 5, most preferably 1; and R is an alkyl or alkyl ester group containing 6 to 16 carbons, or cyclic alkylsilicone compounds of the formula ##STR2## where m is 0 to 4, preferably 0 to 2, most preferably 0, and n is 1 to 5, preferably 3 to 5, most preferably 4, provided that m+n=3 to 5, are adjuvants for agricultural applications of oil-containing compositions. Especially preferred alkylsilicone compounds have a degree of polymerization of .ltoreq.6 and an alkyl content of .ltoreq.50% by weight. The compounds potentiate spreading of mineral or vegetable oils or oil-containing emulsions in dormant spray oils, crop oil concentrates, pesticides, and the like on difficult-to wet surfaces such as waxy leaf cuticles and arthropod exoskeletons.
摘要翻译:其中x = 0至20,优选0至10,最优选0至1的直链烷基硅氧烷化合物。 y = 1〜10,优选1〜5,最优选1; 和R为含有6至16个碳原子的烷基或烷基酯基,或式“IMAGE”的环烷基硅氧烷化合物,其中m为0至4,优选0至2,最优选0,n为1至5,优选3 至5,最优选4,条件是m + n = 3至5,是用于含油组合物的农业应用的佐剂。 特别优选的烷基硅氧烷化合物的聚合度为&lt; 6&gt;烷基含量为<50重量%。 这些化合物加强了在难以湿润的表面如蜡状叶片角质层和节肢动物外骨骼上的休眠喷雾油,作物油浓缩物,农药等中的矿物油或植物油或含油乳剂的铺展。
摘要:
Novel compositions of silicone/polyether block copolymers are provided which are useful as surfactants in several classes of polyurethane foam production. While conventional copolymers have a polysiloxane backbone with pendant polyethers, the surfactants of the present invention are the reverse with siloxane pendants on a polyether chain. These novel non-hydrolyzable polysiloxane polyoxyalkylene copolymers which are characterized by an "inverted" structure, i.e., polyoxyalkylene backbones with lateral and/or terminally pendant polysiloxanes, represent species that are of a narrow molecular weight and compositional distribution and are free of unreacted polyether or non-modified silicone oil diluent. These surfactants are useful in various urethan foam systems and can also display aqueous wetting properties.
摘要:
There is provided herein, in one specific embodiment, silicone composition(s) comprising unique combination(s) of silicone polymer and alkyltrisiloxane(s) which can produce silicone composition(s) with lower solids content than silicone compositions that use other than alkyltrisiloxane(s); while still maintaining a desirable viscosity.
摘要:
The present invention teaches polyhydric organosilicones and their use, a preferred of which is as adjuvants for pesticides. The polyhydric organosilicone have siloxane backbones with pendant, terminal or intermediate polyhydric groups. The polyhydric groups or the silioxane may be functionalized further with amine, alkyl and/or alkyleneoxide groups.
摘要:
Oligomeric fluoroalkylsiloxanes corresponding to the formula: ##STR1## wherein x is 0 to 3, y is 0, 1, or 2; z is 0 or 1; x+y>0, and R has the formula --C.sub.a H.sub.2a --O.sub.b --C.sub.d H.sub.2c --C.sub.d F.sub.2d+1 in which a is 2-4, b is 0 or 1, c is 0-8 and d is 4-12, and compositions thereof with an oil, are useful as spreading agents and in agricultural applications.
摘要翻译:对应于下式的低聚氟代烷基硅氧烷:其中x为0至3,y为0,1或2; z为0或1; x + y> 0,R具有式-CaH2a-Ob-CdH2c-CdF2d + 1,其中a为2-4,b为0或1,c为0-8且d为4-12,其组成为 有油,可用作扩散剂和农业应用。
摘要:
A process for preparation of a urethane foam which comprises reacting an aromatic polyisocyanate with a polyol in the presence of a blowing agent and a catalytic amount of a compound of the formula(CH.sub.3).sub.2 NCH.sub.2 CH.sub.2 (CH.sub.2).sub.n CH.sub.2 CH.sub.2 N(CH.sub.3).sub.2wherein n is 4, 3, 2, 1, or 0.