Method for forming a TiN layer on top of a metal silicide layer in a semiconductor structure and structure formed
    1.
    发明授权
    Method for forming a TiN layer on top of a metal silicide layer in a semiconductor structure and structure formed 有权
    在半导体结构中的金属硅化物层的顶部上形成TiN层的方法和形成的结构

    公开(公告)号:US06436823B1

    公开(公告)日:2002-08-20

    申请号:US09679738

    申请日:2000-10-05

    IPC分类号: H01L2144

    摘要: A method for forming a TiN layer on top of a metal silicide layer in a semiconductor structure without the formation of a thick amorphous layer containing Ti, Co and Si and the structure formed are provided. In the method, after a Ti layer is deposited on top of a metal silidide layer, a dual-step annealing process is conducted in which a low temperature annealing in a forming gas (or ammonia) at a temperature not higher than 500° C. is first conducted for less than 2 hours followed by a high temperature annealing in a nitrogen-containing gas (or ammonia) at a second temperature not lower than 500° for less than 2 hours to form the TiN layer. The present invention method prevents the problem usually caused by a thick amorphous material layer of Ti—Si—Co which produces weakly bonded Ti which reacts with fluorine atoms from WF6 during a subsequent CVD W deposition process and causes liner failure due to a volume expansion of the amorphous material. The maximum thickness of the amorphous material layer formed by the present invention method is less than 5 nm which minimizes the line failure problem.

    摘要翻译: 提供了一种在半导体结构中的金属硅化物层的顶部上形成TiN层的方法,而不形成含有Ti,Co和Si的厚非晶层以及形成的结构。 在该方法中,在金属硅化物层的顶部沉积Ti层之后,进行双相退火工艺,其中在不高于500℃的温度下在成形气体(或氨)中进行低温退火。 首先进行少于2小时,然后在不低于500℃的第二温度下在含氮气体(或氨)中进行低温退火2小时以形成TiN层。 本发明的方法防止了在随后的CVD W沉积过程中由Ti-Si-Co的厚的无定形材料层产生的弱结合的Ti与来自WF6的氟原子反应而产生的弱结合的问题,并导致由于体积膨胀引起的衬管故障 无定形材料。 通过本发明方法形成的非晶材料层的最大厚度小于5nm,这使线路故障问题最小化。