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公开(公告)号：US10396399B2
公开(公告)日：2019-08-27
申请号：US15323761
申请日：2015-07-07
IPC分类号： H01M10/0567 , C07F9/00 , C07F9/02 , H01G11/58 , C07F9/09 , H01G11/54 , H01G11/64 , H01M10/0525 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01G11/60 , H01G11/62
摘要： An electrolyte solution capable of providing electrochemical devices whose internal resistance is less likely to increase even after repeated charge and discharge and whose cycle capacity retention ratio is high. The electrolyte solution contains a solvent, an electrolyte salt, and a phosphate in an amount of 0.001 to 15 mass % relative to the solvent and represented by the formula (1): (R11O)(R12O)PO2M, where R11, R12 and M are as defined herein.
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公开(公告)号：US10297865B2
公开(公告)日：2019-05-21
申请号：US15124761
申请日：2015-03-24
IPC分类号： H01M10/0569 , H01M10/0567 , H01M10/0525 , H01G11/06 , H01G11/60 , H01G11/62 , H01G11/64 , H01M10/052 , H01M10/0568 , H01G11/52 , H01M10/42 , H01M10/056
摘要： The present invention provides an electrolyte solution that is capable of dealing with an increased voltage of an electrochemical device, improving the high-temperature storage characteristics, and restraining an increase in resistance, and an electrochemical device. The electrolyte solution includes a solvent containing a fluorinated acyclic carbonate having a fluorine content of 33 to 70 mass %, a borate, and an electrolyte salt other than the borate.
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公开(公告)号：US09509016B2
公开(公告)日：2016-11-29
申请号：US14347539
申请日：2012-10-03
发明人： Meiten Koh , Aoi Nakazono , Hitomi Miyawaki , Hideo Sakata
IPC分类号： H01M10/0567 , H01M4/485 , H01M4/505 , H01M10/052 , H01M10/26 , H01M10/0525 , H01M4/02 , H01M4/525 , H01M10/0569 , H01M4/58
CPC分类号： H01M10/0567 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M10/052 , H01M10/0525 , H01M10/0569 , H01M10/26 , H01M2004/028 , H01M2300/0034 , Y02E60/122 , Y02T10/7011
摘要： An object of the present invention is to provide a battery having excellent durability at high temperature and high voltage. The present invention is a battery including a positive electrode, a negative electrode and a non-aqueous electrolyte, wherein the non-aqueous electrolyte contains (i) a compound represented by the general formula (1): Rf—SO2F (1) (where Rf is a C1-13 linear or branched fluorine-containing alkyl group optionally containing an ether bond and optionally containing a double bond).
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公开(公告)号：US11929461B2
公开(公告)日：2024-03-12
申请号：US16092634
申请日：2017-04-05
IPC分类号： H01M10/0567 , H01G9/20 , H01G11/60 , H01G11/62 , H01G11/64 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0569
CPC分类号： H01M10/0567 , H01G11/60 , H01G11/62 , H01G11/64 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0569 , H01G9/20 , H01M2300/0025 , Y02E60/10 , Y02E60/13 , Y02T10/70
摘要： The present invention provides an electrolytic solution capable of providing an electrochemical device, such as a lithium ion secondary battery, or a module that has excellent high-temperature storage performance. The electrolytic solution contains: a homocyclic compound other than aromatic compounds; and a cyclic dicarbonyl compound. The homocyclic compound contains at least one group selected from the group consisting of a nitrile group and an isocyanate group.
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公开(公告)号：US11043698B2
公开(公告)日：2021-06-22
申请号：US16470611
申请日：2017-11-01
发明人： Shigeaki Yamazaki , Kenzou Takahashi , Hiroyuki Arima , Hideo Sakata , Masakazu Kinoshita , Shinichi Kinoshita
IPC分类号： H01M10/0567 , H01M10/0525 , H01M10/0569 , C07F9/28 , C07D317/38 , C07C317/04
摘要： An electrolyte solution whose residual capacity is less likely to decrease and whose percentage increase in resistance is less likely to change even after stored at high temperature. The electrolyte solution contains a compound (1) represented by the following formula (1): R11CFX11(CH2)n11COOR12 wherein R11 is H, F, a C1-C3 non-fluorinated alkyl group, or a C1-C3 fluorinated alkyl group; X11 is H or F; R12 is a C1-C3 non-fluorinated alkyl group or a C1-C3 fluorinated alkyl group; and n11 is an integer of 0 to 3; a fluorinated carbonate; and a specific additive.
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公开(公告)号：US10756384B2
公开(公告)日：2020-08-25
申请号：US15768137
申请日：2016-10-14
发明人： Tomoya Hidaka , Hideo Sakata , Kenzou Takahashi , Hiroyuki Arima , Shigeaki Yamazaki , Yoshiko Kuwajima , Shinichi Kinoshita
IPC分类号： H01M10/0525 , H01M10/0568 , H01M10/0569 , C07C31/36 , C07F5/04 , C07C43/12 , H01G11/64 , C07C255/46 , C07C69/96 , C07C31/42 , H01G9/20 , C07F9/09 , H01G11/62 , C07C255/04 , H01M10/0567 , C07C305/04 , H01M4/38 , H01M4/62 , H01M4/66 , H01M4/02
摘要： The present invention provides an electrolytic solution capable of providing an electrochemical device (e.g., a lithium ion secondary battery) or a module that is less likely to generate gas even in high-temperature storage and has high capacity retention even after high-temperature storage. The present invention relates to an electrolytic solution which may contain a compound represented by Y21R21C—CY22R22 wherein R21 and R22 may be the same as or different from each other, and are each H, an alkyl group, or a halogenated alkyl group; Y21 and Y22 may be the same as or different from each other, and are each —OR23 or a halogen atom; and R23 is H, an alkyl group, or a halogenated alkyl group.
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公开(公告)号：US10686222B2
公开(公告)日：2020-06-16
申请号：US16186649
申请日：2018-11-12
IPC分类号： H01M10/056 , H01M10/0567 , C07F9/00 , C07F9/02 , H01G11/58 , C07F9/09 , H01G11/54 , H01G11/64 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01G11/60 , H01G11/62
摘要： A method for manufacturing a phosphate, which includes reacting, in a solvent, an organophosphate represented by the following formula (2) and an alkali metal hydroxide in an amount of 1.01 mole equivalents or more relative to the organophosphate to provide a composition containing a phosphate represented by the following formula (1), the alkali metal hydroxide, and the solvent; and adding hydrogen fluoride to the composition to neutralize the composition and to precipitate an alkali metal fluoride, thereby providing a composition containing the precipitated alkali metal fluoride, the phosphate represented by the formula (1), and the solvent. The formula (1) is (R11O)(R12O)PO2M, where R11, R12 and M are as defined herein. The formula (2) is (R21O)(R22O)(R23O)PO, where R21, R22, and R23 are as defined herein.
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8.发明申请ELECTROLYTIC SOLUTION, ELECTROCHEMICAL DEVICE, LITHIUM ION SECONDARY BATTERY, AND MODULE 有权电解液，电化学装置，锂离子二次电池和模块公开(公告)号：US20150086877A1
公开(公告)日：2015-03-26
申请号：US14394301
申请日：2013-04-12
发明人： Shigeaki Yamazaki , Hideo Sakata , Mayuko Taeda , Meiten Koh , Aoi Nakazono , Michiru Kagawa , Akiyoshi Yamauchi
IPC分类号： H01M10/0569 , H01M10/0525
CPC分类号： H01M10/0569 , C07D317/36 , H01G11/60 , H01G11/64 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M2300/0034 , Y02E60/122 , Y02E60/13
摘要： The present invention aims to provide an electrolyte solution for forming, for example, a secondary battery having excellent oxidation resistance and high-temperature storage characteristics; an electrochemical device such as a lithium-ion secondary battery that contains the electrolyte solution; and a module that contains the electrochemical device. The present invention provides an electrolyte solution containing a solvent and an electrolyte salt, wherein the solvent contains a fluorine-containing compound (A) represented by formula (1) shown below in an amount of 0.01 to 20% by mass, and a fluorine-containing compound (B) represented by formula (2) shown below in an amount of 10 to 80% by mass: Rf1OCOOR (1) wherein Rf1 is a C1-C4 fluorine-containing alkyl group, and R is a C1-C4 non-fluorinated alkyl group, and Rf2OCOORf3 (2) wherein Rf2 and Rf3 are the same or different, and each is a C1-C4 fluorine-containing alkyl group.
摘要翻译： 本发明的目的在于提供一种用于形成例如具有优异的抗氧化性和高温保存特性的二次电池的电解液; 包含电解质溶液的电化学装置如锂离子二次电池; 以及包含电化学装置的模块。 本发明提供一种含有溶剂和电解质盐的电解质溶液，其中溶剂含有下述式（1）所示的含氟化合物（A）的量为0.01〜20质量％，氟 - 含有下述式（2）所示的含氮化合物（B）的量为10〜80质量％：Rf1OCOOR（1）其中Rf1为C1-C4含氟烷基，R为C1〜 氟化烷基和Rf2OCOORf3（2），其中Rf2和Rf3相同或不同，并且各自为C1-C4含氟烷基。
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公开(公告)号：US11322780B2
公开(公告)日：2022-05-03
申请号：US16319135
申请日：2017-06-16
IPC分类号： H01M10/0568 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01G11/60 , H01G11/62 , H01G11/64 , H01M10/052 , H01G9/20
摘要： An electrolyte solution for an electrochemical device, such as a lithium secondary battery, or module. The electrolyte solution contains: a solvent that contains a fluorinated acyclic carbonate having a fluorine content of 33 to 70 mass %; at least one organosilicon compound selected from a compound represented by the formula (1): (R11)n11—M11—O—SiR12R13R14 and a compound represented by the formula (2): R21R22R23—Si—F; a lithium salt (3) that contains an oxalato-complex as an anion; and a lithium salt (4) represented by the formula (4): LizM31FxOy, where R11, M11, R12, R13, R14, R21, R22, R23 and M31 are as defined herein.
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公开(公告)号：US11276883B2
公开(公告)日：2022-03-15
申请号：US16452081
申请日：2019-06-25
发明人： Atsushi Maruo , Hideo Sakata , Shinichi Kinoshita
IPC分类号： H01M10/0567 , C07F1/02 , H01M10/0568 , H01M10/0569 , H01G11/64 , H01G11/06 , H01G11/60 , H01G11/62 , H01M10/0525
摘要： The present invention provides a novel electrolyte solution capable of providing electrochemical devices whose internal resistance is less likely to increase even after repeated charge and discharge and whose cycle capacity retention ratio is high. The electrolyte solution of the present invention contains a solvent, an electrolyte salt, and at least one selected from the group consisting of compounds represented by R11X11—SO3M11 and compounds represented by R21R22N—SO3M21 in an amount of 0.001 to 10 mass % relative to the solvent.
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