An Ethylene Based Polymer
    1.
    发明申请
    An Ethylene Based Polymer 审中-公开
    乙烯基聚合物

    公开(公告)号:US20150344601A1

    公开(公告)日:2015-12-03

    申请号:US14654868

    申请日:2013-12-10

    CPC classification number: C08F210/16 Y02P20/582 C08F4/64193

    Abstract: The instant invention provides an ethylene based polymer.In one embodiment, the instant invention provides an ethylene based polymer comprising the polymerization reaction product of ethylene with optionally one or more α-olefins in the presence of one or more first catalyst systems and optionally one or more second catalyst systems in a dual reactor system or a multiple reactor system, wherein first catalyst system comprises; (a) one ore more procatalysts comprising a metal-ligand complex of formula (I):

    Abstract translation: 本发明提供一种基于乙烯的聚合物。 在一个实施方案中,本发明提供一种乙烯基聚合物,其包含乙烯与任选的一种或多种α-烯烃在一种或多种第一催化剂体系存在下的聚合反应产物和任选的一种或多种第二催化剂体系的双重反应器体系 或多反应器系统,其中第一催化剂体系包括: (a)一种或多种前催化剂,其包含式(I)的金属 - 配体络合物:

    PROCESS FOR PRODUCING LOW MOLECULAR WEIGHT ETHYLENE- AND ALPHA-OLEFIN-BASED MATERIALS
    2.
    发明申请
    PROCESS FOR PRODUCING LOW MOLECULAR WEIGHT ETHYLENE- AND ALPHA-OLEFIN-BASED MATERIALS 有权
    生产低分子量乙烯和基于丙烯的材料的方法

    公开(公告)号:US20140357918A1

    公开(公告)日:2014-12-04

    申请号:US14361552

    申请日:2012-11-28

    Abstract: The present invention generally relates to a process that prepares polyethylenes, poly-α-olefins or poly(co-ethylene-?-olefin) having backbone weight average molecular weights less than 2500 daltons. The process uses a metal-ligand complex as a precatalyst and can be carried out at temperatures ranging from 30° C. to 300° C. The relatively low molecular weight of the products enables improved viscosity control for a wide variety of applications.

    Abstract translation: 本发明一般涉及一种制备聚乙烯,聚-α-烯烃或主链重均分子量小于2500道尔顿的聚(共 - 乙烯-α-烯烃)的方法。 该方法使用金属 - 配体络合物作为预催化剂,并且可以在30℃至300℃的温度范围内进行。相对低分子量的产品可以改善对多种应用的粘度控制。

    Bis(aryl)acetal compounds
    6.
    发明授权
    Bis(aryl)acetal compounds 有权
    双(芳基)缩醛化合物

    公开(公告)号:US08933239B1

    公开(公告)日:2015-01-13

    申请号:US13943232

    申请日:2013-07-16

    CPC classification number: C07F5/025 C07C43/307 C07F5/027 C07F5/04 C07F5/05

    Abstract: A bis(aryl)acetal has the formula wherein Y1 and Y2 are each independently chloro, bromo, iodo, mesylate, tosylate, triflate, or Bx, provided that Y1 and Y2 are not both selected from chloro, bromo, and iodo; each occurrence of Bx is independently a boron-containing functional group bonded to Ar1 or Ar2 via a boron atom; Ar1 and Ar2 are each independently unsubstituted or substituted C6-18 arylene, or unsubstituted or substituted C3-18 heteroarylene; provided that Ar1 and Ar2 are not covalently linked to each other to form a ring structure that includes —Ar1—O—C—O—Ar2—; and R1 and R2 are each independently hydrogen, unsubstituted or substituted C1-18 linear or branched alkyl, unsubstituted or substituted C3-20 cycloalkyl, unsubstituted or substituted C6-18 aryl, or unsubstituted or substituted C3-20 heteroaryl. The bis(aryl)acetal is useful as a monomer for oligoacetal and polyacetal synthesis via Suzuki polycondensation.

    Abstract translation: 双(芳基)缩醛具有下式:其中Y1和Y2各自独立地为氯,溴,碘,甲磺酸酯,甲苯磺酸酯,三氟甲磺酸酯或Bx,条件是Y1和Y2不都选自氯,溴和碘; 每次出现的Bx分别是通过硼原子与Ar 1或Ar 2键合的含硼官能团; Ar1和Ar2各自独立地为未取代的或取代的C6-18亚芳基,或未取代或取代的C3-18亚杂芳基; 条件是Ar 1和Ar 2不彼此共价连接以形成包括-Ar 1 -O-C-O-Ar 2 - 的环结构; 且R 1和R 2各自独立地为氢,未取代或取代的C 1-18直链或支链烷基,未取代或取代的C 3-20环烷基,未取代或取代的C 6-18芳基,或未取代或取代的C 3-20杂芳基。 双(芳基)缩醛可用作通过Suzuki缩聚的低缩醛和聚缩醛合成的单体。

    A Polymerization Process for Producing Ethylene Based Polymers
    10.
    发明申请
    A Polymerization Process for Producing Ethylene Based Polymers 有权
    一种生产乙烯基聚合物的聚合方法

    公开(公告)号:US20150344602A1

    公开(公告)日:2015-12-03

    申请号:US14654875

    申请日:2013-12-10

    Abstract: The instant invention provides a polymerization process for producing ethylene based polymers.In one embodiment, the instant invention provides a polymerization process for producing ethylene based polymers comprising: polymerizing ethylene with optionally one or more α-olefins in the presence of one or more first catalyst systems and optionally one or more second catalyst systems in in a dual reator system or a multiple reactor system, wherein first catalyst system comprises; (a) one ore more procatalysts comprising a metal-ligand complex of formula (I):

    Abstract translation: 本发明提供了一种生产乙烯基聚合物的聚合方法。 在一个实施方案中,本发明提供了一种用于生产基于乙烯的聚合物的聚合方法,其包括:在一种或多种第一催化剂体系和任选的一种或多种第二催化剂体系的存在下,将乙烯与任选的一种或多种α-烯烃聚合, 反应器系统或多反应器系统,其中第一催化剂体系包括: (a)一种或多种前催化剂,其包含式(I)的金属 - 配体络合物:

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