MEMBRANE DERIVED FROM POLYFUNCTIONAL AMINE AND COMBINATION OF DIFFERENT POLYFUNCTIONAL AMINE-REACTIVE MONOMERS
    5.
    发明申请
    MEMBRANE DERIVED FROM POLYFUNCTIONAL AMINE AND COMBINATION OF DIFFERENT POLYFUNCTIONAL AMINE-REACTIVE MONOMERS 有权
    多功能胺衍生的膜和不同多功能胺反应单体的组合

    公开(公告)号:US20150174534A1

    公开(公告)日:2015-06-25

    申请号:US14407013

    申请日:2013-07-03

    IPC分类号: B01D67/00

    摘要: A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer including the steps of applying a polyfunctional amine monomer and a combination amine-reactive compounds to a surface of the porous support and reacting the constituents to form a thin film polyamide layer, wherein the amine-reactive compounds include: i) a polyfunctional amine-reactive monomer including two to three amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, ii) a polyfunctional amine-reactive monomer including at least four amine-reactive moieties selected from acyl halide, sulfonyl halide and anhydride, and iii) an acid compound including at least on carboxylic acid moiety or salt thereof and at least one amine-reactive moiety selected from acyl halide and sulfonyl halide.

    摘要翻译: 一种制造包括多孔载体和薄膜聚酰胺层的复合聚酰胺膜的方法,包括以下步骤:将多官能胺单体和组合胺反应性化合物施加到多孔载体的表面,并使组分反应形成薄膜 聚酰胺层,其中胺反应性化合物包括:i)包含选自酰基卤,磺酰卤和酸酐的两个至三个胺反应性部分的多官能胺反应性单体,ii)包含至少四个胺的多官能胺反应性单体 - 选自酰基卤,磺酰卤和酸酐的反应性部分,和iii)至少包含羧酸部分或其盐以及至少一种选自酰卤和磺酰卤的胺反应性部分的酸化合物。

    SEPARATION OF HYDROCARBONS FROM AQUEOUS MIXTURE USING FOULING RESISTANT REVERSE OSMOSIS MEMBRANE
    8.
    发明申请
    SEPARATION OF HYDROCARBONS FROM AQUEOUS MIXTURE USING FOULING RESISTANT REVERSE OSMOSIS MEMBRANE 审中-公开
    使用防潮反渗透膜从水性混合物中分离烃

    公开(公告)号:US20160304363A1

    公开(公告)日:2016-10-20

    申请号:US15035900

    申请日:2014-12-15

    摘要: A method for separating hydrocarbons and naphthenic acid from an aqueous mixture containing the same by passing the mixture through a spiral wound element to produce a permeate stream and concentrate stream wherein the concentrate stream has a relatively higher concentration of hydrocarbons than the permeate stream, wherein the spiral wound element includes a composite poly amide membrane comprising a porous support and a thin film poly amide layer, wherein the membrane is characterized by having: i) a NaCl rejection and a benzene tetra carboxylic acid rejection of at least 98% when tested with an aqueous solution containing 2000 ppm NaCl and 100 ppm benzene tetra carboxylic acid at 25° C., pH 8 and ImPa (150 psi); and ii) a dissociated carboxylate content of at least 0.3 moles/kg of polyamide at pH 9.5 as measured by Rutherford Backscattering (RBS).

    摘要翻译: 通过使混合物通过螺旋缠绕元件以产生渗透物流和浓缩物流从其含水混合物中分离烃和环烷酸的方法,其中浓缩物流具有比渗透物流更高浓度的烃,其中 螺旋缠绕元件包括复合聚酰胺膜,其包括多孔载体和薄膜聚酰胺层,其中所述膜的特征在于具有:i)当测试时,具有以下特征:i)NaCl排斥和苯四羧酸排斥率至少为98% 在25℃,pH8和ImPa(150psi)下含有2000ppm NaCl和100ppm苯四羧酸的水溶液; 和ii)通过卢瑟福反向散射(RBS)测量的在pH9.5下至少0.3摩尔/ kg聚酰胺的解离的羧酸盐含量。

    THIN FILM COMPOSITE MEMBRANE DERIVED FROM TETRA-FUNCTIONAL ACYL HALIDE MONOMER
    10.
    发明申请
    THIN FILM COMPOSITE MEMBRANE DERIVED FROM TETRA-FUNCTIONAL ACYL HALIDE MONOMER 有权
    来自TETRA-FUNCTIONAL ACYL HALIDE MONOMER的薄膜复合膜

    公开(公告)号:US20150147470A1

    公开(公告)日:2015-05-28

    申请号:US14405697

    申请日:2013-07-03

    IPC分类号: B01D69/12 B01D71/56 B01D61/02

    摘要: A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer, wherein the method includes the step of applying a polyfunctional amine monomer and a tetraacyl acyl halide monomer represented by Formula (I) to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer; wherein A is selected from: oxygen (—O—); carbon (—C—); silicon (—Si—); each of which may be unsubstituted or substituted, e.g. with alkyl groups of 1-4 carbon atoms; or a carbonyl group (—C(O)—), X is the same or different and is selected from a halogen, and Y is selected from halogen and hydroxide.

    摘要翻译: 一种制备包括多孔载体和薄膜聚酰胺层的复合聚酰胺膜的方法,其中所述方法包括将由式(I)表示的多官能胺单体和四酰基酰卤单体应用于多孔载体的表面的步骤 并使单体界面聚合形成薄膜聚酰胺层; 其中A选自:氧(-O-); 碳(-C-); 硅(-Si-); 其各自可以是未取代的或取代的,例如 具有1-4个碳原子的烷基; 或羰基(-C(O) - ),X相同或不同,选自卤素,Y选自卤素和氢氧根。