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公开(公告)号：US09353044B2
公开(公告)日：2016-05-31
申请号：US14369427
申请日：2012-11-14
Applicant: DOW Global Technologies LLC
Inventor： Stephen W. King , Sadeka Onam , Thomas Z. Srnak
IPC: C07D295/00 , C07C213/02 , C07D295/023 , B01J21/12 , B01J23/889 , B01J23/89 , B01J37/02
CPC classification number: C07C213/02 , B01J21/12 , B01J23/8896 , B01J23/89 , B01J37/0201 , C07C2529/89 , C07D295/00 , C07D295/023 , C07C215/14
Abstract: The invention provides a method for the reductive amination of diethanolamine to form a product composition that includes piperazine (PIP) and aminoethylethanolamine (AEEA). A catalyst with a transitional alumina/second metal oxide support and a mixture of catalytic metals is used for the reaction which results in low levels of non-PIP and non-AEEA side products.
Abstract translation: 本发明提供二乙醇胺还原胺化以形成包括哌嗪（PIP）和氨基乙基乙醇胺（AEEA））的产品组合物的方法。 使用具有过渡氧化铝/第二金属氧化物载体和催化金属的混合物的催化剂用于反应，其导致低水平的非PIP和非AEEA副产物。
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公开(公告)号：US20210205785A1
公开(公告)日：2021-07-08
申请号：US17056534
申请日：2019-05-23
Applicant: Dow Global Technologies LLC
Inventor： Mingzhe Yu , David Gordon Barton , Kurt F. Hirsekorn , Sadeka Onam , Peter N. Nickias , Andrew T. Heitsch , Thomas H. Peterson
Abstract: A heterogeneous procatalyst includes a titanium species, a magnesium chloride component, and a chlorinating agent having a structure A(C)x(R1)3-x, where A is aluminum or boron, R1 is a (C1-C30) hydrocarbyl, and x is 1, 2, or 3. The magnesium chloride component may be thermally treated at a temperature greater than 100 C for at least 30 minutes before or after introduction of the chlorinating agent and titanium species to the heterogeneous procatalyst. The heterogeneous procatalyst having the thermally treated magnesium chloride exhibits improved average molecular weight capability. Processes for producing the heterogeneous procatalyst and processes for producing ethylene-based polymers utilizing the heterogeneous procatalyst are also disclosed.
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Patent Agency Ranking
3.发明授权公开(公告)号：US09783486B2
公开(公告)日：2017-10-10
申请号：US15038984
申请日：2014-11-24
Applicant: Dow Global Technologies LLC
Inventor： Stephen W. King , Sadeka Onam
IPC: C07C211/14 , C07C209/02 , C08G73/02 , C07C209/64 , B01J23/889
CPC classification number: C07C211/14 , B01J23/8896 , C07C209/02 , C07C209/64 , C08G73/0206 , C08G73/0213
Abstract: A process for preparing high molecular weight, branched, acyclic polyalkyleneamines comprising transaminating a reaction mixture that includes at least a first polyalkyleneamine component that contains at least two non-tertiary amine groups separated from one another by a ternary or higher carbon atom and a second polyalkyleneamine component having the formula wherein x, y, and z are the same or different and are integers of from 1 to 10; a, b, c, d, e, and f are the same or different and are H or hydrocarbyl of from 1 to 10 carbon atoms; A, B, C, D, E, are the same or different and are H or hydrocarbyl of from 1 to 10 carbon atoms; provided that at least two of the amine groups are primary or secondary.
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公开(公告)号：US11857935B2
公开(公告)日：2024-01-02
申请号：US17056534
申请日：2019-05-23
Applicant: Dow Global Technologies LLC
Inventor： Mingzhe Yu , David Gordon Barton , Kurt F. Hirsekorn , Sadeka Onam , Peter N. Nickias , Andrew T. Heitsch , Thomas H. Peterson
IPC: C08F4/646 , C08F4/657 , B01J3/00 , B01J21/06 , B01J20/04 , B01J31/14 , B01J35/10 , C08F2/06 , C08F4/02 , C08F210/16 , C08F4/685
CPC classification number: B01J21/063 , B01J20/046 , B01J31/143 , B01J35/1019 , C08F2/06 , C08F4/022 , C08F4/6576 , C08F4/6574 , C08F4/685 , C08F210/16 , C08F2410/03
Abstract: A heterogeneous procatalyst includes a titanium species, a magnesium chloride component, and a chlorinating agent having a structure A(Cl)x(R1)3-x, where A is aluminum or boron, R1 is a (C1-C30) hydrocarbyl, and x is 1, 2, or 3. The magnesium chloride component may be thermally treated at a temperature greater than 100 C for at least 30 minutes before or after introduction of the chlorinating agent and titanium species to the heterogeneous procatalyst. The heterogeneous procatalyst having the thermally treated magnesium chloride exhibits improved average molecular weight capability. Processes for producing the heterogeneous procatalyst and processes for producing ethylene-based polymers utilizing the heterogeneous procatalyst are also disclosed.
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公开(公告)号：US10815331B2
公开(公告)日：2020-10-27
申请号：US16309566
申请日：2017-06-07
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Michael T. Malanga , Sabrina Fregni , George J. Frycek , Stephen W. King , Jean-Paul Masy , Sadeka Onam
Abstract: The present invention discloses a polymeric polyol composition useful for making polyurethane polymers, especially polyurethane foams. Said polyurethane polymer foams demonstrate a good balance of mechanical properties, physical properties, and low emissions. The polymeric polyol composition is the reaction product(s) of (i) a polyamine initiator composition comprising the polymerization product(s) of aminoethylpiperazine with (ii) at least one epoxide compound, at least one glycidyl ether compound, or mixtures thereof.
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公开(公告)号：US20190330405A1
公开(公告)日：2019-10-31
申请号：US16309566
申请日：2017-06-07
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Michael T. Malanga , Sabrina Fregni , George J. Frycek , Stephen W. King , Jean-Paul Masy , Sadeka Onam
Abstract: The present invention discloses a polymeric polyol composition useful for making polyurethane polymers, especially polyurethane foams. Said polyurethane polymer foams demonstrate a good balance of mechanical properties, physical properties, and low emissions. The polymeric polyol composition is the reaction product(s) of (i) a polyamine initiator composition comprising the polymerization product(s) of aminoethylpiperazine with (ii) at least one epoxide compound, at least one glycidyl ether compound, or mixtures thereof.
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公开(公告)号：US20140371452A1
公开(公告)日：2014-12-18
申请号：US14369427
申请日：2012-11-14
Applicant: DOW Global Technologies LLC
Inventor： Stephen W. King , Sadeka Onam , Thomas Z. Srnak
IPC: C07C213/02 , C07D295/00
CPC classification number: C07C213/02 , B01J21/12 , B01J23/8896 , B01J23/89 , B01J37/0201 , C07C2529/89 , C07D295/00 , C07D295/023 , C07C215/14
Abstract: The invention provides a method for the reductive amination of diethanolamine to form a product composition that includes piperazine (PIP) and aminoethylethanolamine (AEEA). A catalyst with a transitional alumina/second metal oxide support and a mixture of catalytic metals is used for the reaction which results in low levels of non-PIP and non-AEEA side products.
Abstract translation: 本发明提供二乙醇胺还原胺化以形成包括哌嗪（PIP）和氨基乙基乙醇胺（AEEA））的产品组合物的方法。 使用具有过渡氧化铝/第二金属氧化物载体和催化金属的混合物的催化剂用于反应，其导致低水平的非PIP和非AEEA副产物。
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