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公开(公告)号：US20220018040A1
公开(公告)日：2022-01-20
申请号：US17336040
申请日：2021-06-01
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria SIMMELINK , Jacobus Johannes MENCKE , Martinus Johannes Nicolaas JACOBS , Roeloef MARISSEN
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US20190212100A1
公开(公告)日：2019-07-11
申请号：US16354021
申请日：2019-03-14
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria SIMMELINK , Jacobus Johannes MENCKE , Martinus Johannes Nicolaas JACOBS , Roeloef MARISSEN
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US20190212098A1
公开(公告)日：2019-07-11
申请号：US16353957
申请日：2019-03-14
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria SIMMELINK , Jacobus Johannes MENCKE , Martinus Johannes Nicolaas JACOBS , Roeloef MARISSEN
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US20220143950A1
公开(公告)日：2022-05-12
申请号：US17551142
申请日：2021-12-14
Applicant: DSM IP ASSETS B.V.
IPC: B32B5/12 , C08F110/02 , C08L23/06 , B32B27/12 , B32B37/10 , B32B7/09 , B32B7/12 , B32B27/32 , D02G3/02 , D01F6/04
Abstract: Multifilament yarn containing n filaments are provided, wherein the filaments are obtained by spinning an ultra-high molecular weight polyethylene (UHMWPE), said yarn having a tenacity (Ten) as expressed in cN/dtex of Ten(cN/dtex)=f×n−0.05×dpf −0.15, wherein Ten is at least 39 cN/dtex, n is at least 25, f is a factor of at least 58 and dpf is the dtex per filament.
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Patent Agency Ranking
公开(公告)号：US20200299866A1
公开(公告)日：2020-09-24
申请号：US16897848
申请日：2020-06-10
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria SIMMELINK , Jacobus Johannes MENCKE , Martinus Johannes Nicolaas JACOBS , Roeloef MARISSEN
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US20170370681A1
公开(公告)日：2017-12-28
申请号：US15672190
申请日：2017-08-08
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria SIMMELINK , Jacobus Johannes MENCKE , Martinus Johannes Nicolaas JACOBS , Roeloef MARISSEN
IPC: F41H5/04 , C08F10/02 , A61L17/04 , D01F6/04 , D02G3/02 , D01D4/02 , A61L27/16 , D01D5/18 , C08L53/02 , D07B1/02
CPC classification number: F41H5/0478 , A61L17/04 , A61L27/16 , C08F10/02 , C08L23/06 , C08L53/02 , C08L2203/12 , D01D4/02 , D01D5/18 , D01F6/04 , D02G3/02 , D07B1/025 , D07B2205/2014 , D07B2801/10 , D10B2321/0211 , F41H5/0471 , F41H5/0485 , Y10T428/24041 , Y10T428/24058 , Y10T428/24124 , Y10T428/249921 , Y10T428/29 , Y10T428/2913 , Y10T428/2967 , Y10T442/2615 , Y10T442/2623
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp* DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US20190212099A1
公开(公告)日：2019-07-11
申请号：US16353993
申请日：2019-03-14
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria SIMMELINK , Jacobus Johannes MENCKE , Martinus Johannes Nicolaas JACOBS , Roeloef MARISSEN
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US20160290769A1
公开(公告)日：2016-10-06
申请号：US15178561
申请日：2016-06-09
Applicant: DSM IP ASSETS B.V.
Inventor： Roelof MARISSEN , Joseph Arnold Paul Maria SIMMELINK , Reinard Jozef Maria STEEMAN , Gijsbertus Hendrikus Maria CALIS , Jacobus Johannes MENCKE , Jean Hubert Marie BEUGELS , David VANEK , Johann VAN ELBURG , Alexander Volker PETERS , Steen TANDERUP , Marko DORSCHU
CPC classification number: F41H5/0471 , B32B5/022 , B32B5/024 , B32B7/005 , B32B27/06 , B32B2571/02 , F41H5/0421 , F41H5/0428 , F41H5/0457 , F41H5/0485 , Y10T156/1015 , Y10T428/24058 , Y10T428/24074 , Y10T428/24479 , Y10T428/2495 , Y10T428/2913
Abstract: The invention relates to ballistic resistant article having a multilayered material sheet which includes a consolidated stack of unidirectional monolayers of drawn polymer, whereby the draw direction of two subsequent monolayers in the stack differs. At least one monolayer comprises a plurality of unidirectional tapes of the drawn polymer, aligned in the same direction, whereby adjacent tapes do not overlap. The invention also relates to a process for the preparation of the multilayered material sheet, and to a ballistic resistant article comprising the multilayered material sheet.
Abstract translation: 本发明涉及具有多层材料片的防弹制品，其包括拉伸聚合物的单向单层的固结叠层，由此叠层中两个后续单层的拉伸方向不同。 至少一个单层包括多个拉伸的聚合物的单向带，沿相同的方向排列，由此相邻的带不重叠。 本发明还涉及制备多层材料片的方法，以及包括多层材料片的防弹制品。
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公开(公告)号：US20140083285A1
公开(公告)日：2014-03-27
申请号：US14092819
申请日：2013-11-27
Applicant: DSM IP ASSETS B.V.
Inventor： Roelof MARISSEN , Joseph Arnold Paul Maria SIMMELINK , Reinard Jozef Maria STEEMAN , Gijsbertus Hendrikus Maria CALIS , Jacobus Johannes MENCKE , Jean Hubert Marie BEUGELS , David VANEK , Johann VAN ELBURG , Alexander Volker PETERS , Steen TANDERUP , Marko DORSCHU
CPC classification number: F41H5/0471 , B32B5/022 , B32B5/024 , B32B7/005 , B32B27/06 , B32B2571/02 , F41H5/0421 , F41H5/0428 , F41H5/0457 , F41H5/0485 , Y10T156/1015 , Y10T428/24058 , Y10T428/24074 , Y10T428/24479 , Y10T428/2495 , Y10T428/2913
Abstract: The invention relates to a multilayered material sheet comprising a consolidated stack of unidirectional monolayers of drawn polymer, whereby the draw direction of two subsequent monolayers in the stack differs. At least one monolayer comprises a plurality of unidirectional tapes of the drawn polymer, aligned in the same direction, whereby adjacent tapes do not overlap. The invention also relates to a process for the preparation of the multilayered material sheet, and to a ballistic resistant article comprising the multilayered material sheet.
Abstract translation: 本发明涉及一种多层材料片，其包括拉伸聚合物的单向单层的固结叠层，由此叠层中两个后续单层的拉伸方向不同。 至少一个单层包括多个拉伸的聚合物的单向带，沿相同的方向排列，由此相邻的带不重叠。 本发明还涉及制备多层材料片的方法，以及包括多层材料片的防弹制品。
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