公开(公告)号：US20130045393A1

公开(公告)日：2013-02-21

申请号：US13658460

申请日：2012-10-23

Applicant: DSM IP ASSETS B.V.

Inventor： Matthias Jozef Gertruda BROUNS ,  Joseph Petronella FRIEDERICHS ,  Johan Franz Gradus Antonius JANSEN ,  Marco Marcus Matheus DRIESSEN

IPC: C08F265/04 ,  B32B27/10 ,  B82Y40/00 ,  B82Y30/00

CPC classification number: C08F283/01 ,  B82Y30/00 ,  B82Y40/00 ,  Y10T428/31902 ,  C08F212/08

Abstract: There is disclosed a process for preparing organic nano-particles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin and a hydrophobic monomer; (b) dispersing the solution obtained in step (a) in an aqueous phase to form a stable emulsion where the aqueous phase is the continuous phase; and (c) using an initiator to cure the emulsion obtained in step (b) in the presence of a water soluble inhibitor to form a dispersion of nano-particles. The invention further provides organic nano-particles obtainable by the process according to the invention; various uses of said nano-particles; such as in paper, dye, toner and personal care compositions and topical medicaments comprising said nano-particles.

Abstract translation: 公开了一种制备有机纳米颗粒的方法，包括以下步骤：（a）制备包含不饱和聚酯和/或乙烯基酯树脂和疏水性单体的溶液; （b）将步骤（a）中获得的溶液分散在水相中以形成稳定的乳液，其中水相是连续相; 和（c）使用引发剂在水溶性抑制剂的存在下固化步骤（b）中获得的乳液以形成纳米颗粒的分散体。 本发明还提供可通过本发明方法获得的有机纳米颗粒; 所述纳米颗粒的各种用途; 例如纸，染料，调色剂和个人护理组合物以及包含所述纳米颗粒的局部药物。

公开(公告)号：US20190249018A1

公开(公告)日：2019-08-15

申请号：US16344488

申请日：2017-10-30

Applicant: DSM IP ASSETS, B.V.

Inventor： Paulus Antonius Maria STEEMAN ,  Marco Marcus Matheus DRIESSEN

IPC: C09D11/101 ,  C09D11/104 ,  C09D11/30 ,  C08F290/06 ,  C09D11/107 ,  B33Y70/00

CPC classification number: C09D11/101 ,  B29C64/124 ,  B29C64/153 ,  B33Y10/00 ,  B33Y70/00 ,  C08F290/061 ,  C08F290/064 ,  C09D11/104 ,  C09D11/107 ,  C09D11/30 ,  G03F7/0388 ,  C08F2220/281

Abstract: Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a TPA-based polyester comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the TPA-based polyester comprises the reaction product of a terephthalic acid and a polyol. The composition may further comprise a second network-forming component.

公开(公告)号：US20130084461A1

公开(公告)日：2013-04-04

申请号：US13689138

申请日：2012-11-29

Applicant: DSM IP ASSETS B.V.

Inventor： Matthias Jozef Gertruda BROUNS ,  Joseph Petronella FRIEDERICHS ,  Johan Franz Gradus Antonius JANSEN ,  Marco Marcus Matheus DRIESSEN

IPC: C08F267/06

CPC classification number: C08F267/06 ,  C08F263/00 ,  C08F263/02 ,  C08F283/01 ,  C08L51/003 ,  C08L51/08 ,  C09D151/003 ,  C09D151/08 ,  Y10T428/3179 ,  Y10T428/31906 ,  C08L2666/02

Abstract: The invention provides a process for preparing organic nanoparticles comprising the steps of: (a) preparing a solution comprising an unsaturated polyester and/or a vinyl ester resin, an initiator and a hydrophobic monomer; (b) emulsifying the solution obtained in step (a) in an aqueous phase; and thereafter (c) curing the emulsified solution. The invention further provides organic nanoparticles obtainable by the process according to the invention; various uses of said nanoparticles; and paper, dye compositions and toner compositions comprising said nanoparticles.

公开(公告)号：US20200369896A1

公开(公告)日：2020-11-26

申请号：US16771263

申请日：2018-12-14

Applicant: DSM IP Assets B.V.

Inventor： Paulus Antonius Maria STEEMAN ,  Adrianus Cornelis Bastiaan BOGAERDS ,  Marco Marcus Matheus DRIESSEN ,  Rudolfus Antonius Theodorus Maria VAN BENTHEM ,  Robbert VAN SLUIJS ,  Franciscus Johannes Marie DERKS

IPC: C09D11/101 ,  C09D11/38 ,  B29C64/112 ,  B33Y10/00 ,  B33Y70/10 ,  B29C64/209

Abstract: Described herein are methods and compositions for forming three-dimensional objects via material jetting processes, the methods including the repeated steps of selectively depositing a liquid thermoset material onto a surface from a nozzle of at least one jetting head in a first specified direction and exposing at least a portion of the liquid thermoset material to a source of actinic radiation in order to form a three-dimensional object from the cured thermoset material, wherein the jetting head is configured to eject droplets of the liquid thermoset material from the nozzle at prescribed elevated operating temperatures, and wherein the liquid thermoset material is chosen so as to possessing prescribed viscosity and rheological characteristics.

公开(公告)号：US20190284405A1

公开(公告)日：2019-09-19

申请号：US16344510

申请日：2017-10-30

Applicant: DSM IP ASSETS, B.V.

Inventor： Paulus Antonius Maria STEEMAN ,  Marco Marcus Matheus DRIESSEN ,  Guido Joseph Elisabeth HANSEN

IPC: C09D11/102 ,  C09D11/101 ,  B33Y10/00 ,  B33Y70/00 ,  B29C64/124

Abstract: Thermoset compositions and methods for forming three-dimensional articles via an additive fabrication process, and articles made therefrom are disclosed herein. In an embodiment, a composition comprises a first network-forming component comprising a first oligomer comprising a backbone and having at least 2 polymerizable groups, one or more first network monomers, and a first network initiator. The backbone of the first oligomer comprises a polyepoxide based on Bisphenol A, F, or S, a polyepoxide based on hydrogenated Bisphenol A, F, or S, a polycarbonate, or a polyimide. The composition may further comprise a second network-forming component.