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1.发明授权Process to alkylate an aromatic with a dilute stream comprising propylene and ethylene 有权用包含丙烯和乙烯的稀释流将芳族化合物烷基化的方法
公开(公告)号：US6063976A
公开(公告)日：2000-05-16
申请号：US135919
申请日：1998-08-18
IPC分类号： C07B61/00 , C07C2/66 , C07C2/68 , C07C2/64 , C07C15/067
CPC分类号： C07C2/66 , C07C2529/08 , C07C2529/70 , C07C2529/85
摘要： The present invention provides a method comprising (a) contacting a first reaction mixture comprising an aromatic and a dilute stream comprising ethylene and propylene with a large pore microporous solid acid catalyst, preferably a large pore zeolite catalyst, which is effective to promote alkylation of the aromatic under first conditions effective to maintain a liquid phase comprising the aromatic and effective to cause the propylene to alkylate said aromatic but substantially ineffective to cause the ethylene to alkylate said aromatic, forming propylated aromatic and a second dilute stream comprising ethylene but substantially depleted of propylene, and (b) recovering the propylated aromatic.
摘要翻译： 本发明提供了一种方法，其包括（a）将包含乙烯和丙烯的芳族和稀释物流的第一反应混合物与大孔微孔固体酸催化剂，优选大孔沸石催化剂接触，该催化剂有效促进烷基化 在第一条件下芳族化合物有效地保持包含芳族化合物的液相并且有效地使丙烯烷基化所述芳族但实质上无效以使乙烯烷基化所述芳族化合物，形成丙基化芳族化合物和第二稀释流，其包含乙烯但基本上不含丙烯 ，和（b）回收丙基化芳族化合物。
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公开(公告)号：US5463157A
公开(公告)日：1995-10-31
申请号：US146374
申请日：1993-10-29
IPC分类号： C07C1/20 , C07C2/30 , C07C11/113 , C07C41/06 , C07C51/14 , C07C2/04 , C07C2/24 , C07C2/26 , C07C2/34
CPC分类号： C07C2/30 , C07C1/20 , C07C11/113 , C07C41/06 , C07C51/14 , C07C2521/04 , C07C2521/16 , C07C2529/06 , C07C2531/02 , C07C2531/08 , C07C2531/14 , Y02P30/42
摘要： A method for producing 3-methyl-2-pentene which is substantially free of any other C.sub.6 olefin, except 2-ethyl-1-butene, by first producing a stream that contains 2-ethyl-1-butene from the trimerization of ethylene, and second by recovering the 2-ethyl-1-butene as 3-methyl-2-pentene via etherification, separation of the ether, and decomposition of the ether back to predominantly 3-methyl-2-pentene with some 2-ethyl-1-butene.
摘要翻译： 通过首先从乙烯的三聚反应产生含有2-乙基-1-丁烯的物流，生产除2-乙基-1-丁烯之外基本上不含任何其它C 6烯烃的3-甲基-2-戊烯的方法， 其次是通过醚化作为3-甲基-2-戊烯回收2-乙基-1-丁烯，乙醚的分离和乙醚的分解回到主要是3-甲基-2-戊烯与一些2-乙基-1 丁烯。
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3.发明授权Process of removing contaminants from an olefin stream using extractive distillation 有权使用萃取蒸馏从烯烃流中除去污染物的方法公开(公告)号：US06559248B2
公开(公告)日：2003-05-06
申请号：US09943695
申请日：2001-08-31
申请人： Dan E. Hendriksen , Minquan Cheng , Keith H. Kuechler , David R. Lumgair , Michael P. Nicoletti , Richard Shutt
发明人： Dan E. Hendriksen , Minquan Cheng , Keith H. Kuechler , David R. Lumgair , Michael P. Nicoletti , Richard Shutt
IPC分类号： C08F1006
摘要： Disclosed is a method of purifying olefin containing oxygenate contaminants. The method incorporates the use of extractive distillation. Under the appropriate conditions, olefins containing very low levels of oxygenate contaminants can be recovered.
摘要翻译： 公开了一种纯化含有含氧化合物污染物的烯烃的方法。 该方法包括萃取蒸馏的使用。 在合适的条件下，可以回收含有非常低水平的含氧化合物污染物的烯烃。
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公开(公告)号：US5731486A
公开(公告)日：1998-03-24
申请号：US503134
申请日：1995-07-17
CPC分类号： C07C2/30 , C07C11/113 , C07C51/14
摘要： A method for producing 3-methyl-2-pentene which is substantially free of any other C.sub.6 olefin, except 2-ethyl-1-butene, by first producing a stream that contains 2-ethyl-1-butene from the trimerization of ethylene, and second by recovering the 2-ethyl-1-butene as 3-methyl-2-pentene via etherification, separation of the ether, and decomposition of the ether back to predominantly 3-methyl-2-pentene with some 2-ethyl-1-butene.
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公开(公告)号：US5430213A
公开(公告)日：1995-07-04
申请号：US58616
申请日：1993-05-06
IPC分类号： B01J31/22 , C07B61/00 , C07C2/04 , C07C2/38 , C07C5/25 , C07C11/12 , C08F4/42 , C08F4/70 , C08F36/00 , C08F36/20 , C08F210/00 , C07C2/76
CPC分类号： C07C2/04 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Pure 1,4-dienes are produced at high rates of reaction by reacting a conjugated diene and an alpha monoolefin at a temperature below 70.degree. C. in the presence of a catalyst consisting essentially of a 1,3-bis(diphenylphosphino)propane ligand of Co(II)(acetylacetonate).sub.2 or Co(III)(acetylacetonate).sub.3 or CoCl.sub.2 in combination with a dialkylaluminum halide such as diethylaluminum chloride.
摘要翻译： 在基本上由1,3-双（二苯基膦基）丙烷配体组成的催化剂存在下，在低于70℃的温度下使共轭二烯和α单烯烃反应，以高反应速率生产纯1,4-二烯 的Co（II）（乙酰丙酮化物）2或Co（III）（乙酰丙酮化物）3或CoCl 2与二烷基卤化铝如二乙基氯化铝的组合。
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公开(公告)号：US5118871A
公开(公告)日：1992-06-02
申请号：US645352
申请日：1991-01-24
申请人： John J. Cikut , Robert C. Michaelson , Dan E. Hendriksen , Terry A. Fons , Di-Yi Ou , Daniel D. Rosenfeld
发明人： John J. Cikut , Robert C. Michaelson , Dan E. Hendriksen , Terry A. Fons , Di-Yi Ou , Daniel D. Rosenfeld
摘要： A method for producing alkyl tertiary alkyl ether involves supplying a feed including isoolefins, alcohols, and dialkyl sulfides into a feed zone of a reactor; contacting the feed with a catalyst material in the reaction zone; and catalytically reacting the isooolefins and alcohols under conditions which favor forming resultant ether and inhibiting reaction of dialkyl sulfides with the catalyst material.
摘要翻译： 制备烷基叔烷基醚的方法包括将包括异烯烃，醇和二烷基硫化物的进料供应到反应器的进料区; 使进料与反应区中的催化剂材料接触; 并在有利于形成所得乙醚并抑制二烷基硫化物与催化剂材料的反应的条件下使异戊烯和醇催化反应。
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7.发明授权Hydrogen chloride-free catalyst system for dimerizing and codimerizing olefins 失效用于二烯化和烯化烯烃的无氯化物催化剂体系
公开(公告)号：US5059739A
公开(公告)日：1991-10-22
申请号：US429877
申请日：1989-10-31
申请人： Dan E. Hendriksen
发明人： Dan E. Hendriksen
IPC分类号： B01J31/22 , B01J31/14 , B01J31/18 , C07B61/00 , C07C2/30 , C07C2/32 , C07C11/02 , C07C11/107
CPC分类号： C07C2/30 , B01J31/143 , B01J31/1805 , B01J2231/20 , B01J2531/66 , C07C2527/132 , C07C2531/02 , C07C2531/14 , C07C2531/34
摘要： A substantially hydrogen chloride-free active catalyst system for dimerization and codimerization of alpha-olefins. The catalyst system includes, as one catalyst, a complex of a tungsten salt and an aniline, and, as a second catalyst, an alkyl aluminum halide.
摘要翻译： 一种基本上不含氯化氢的活性催化剂体系，用于α-烯烃的二聚化和共二聚。 催化剂体系包括作为一种催化剂的钨盐和苯胺的络合物，和作为第二催化剂的烷基铝卤化物。
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