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公开(公告)号：US4510289A
公开(公告)日：1985-04-09
申请号：US451180
申请日：1982-12-20
申请人： Daniel W. Fox , Edward N. Peters , Gary F. Smith
发明人： Daniel W. Fox , Edward N. Peters , Gary F. Smith
CPC分类号： C08L67/02 , C08L69/00 , Y10S525/903 , Y10S525/906
摘要： A thermoplastic composition includes compatible blends of a mixed polycarbonate comprising units derived from a first dihydric phenol, which is a bis(hydroxyaryl) sulfone, a second dihydric phenol; and one or more thermoplastic condensation polymers containing hetero groups.
摘要翻译： 热塑性组合物包括混合聚碳酸酯的相容共混物，其包含衍生自作为双（羟基芳基）砜的第一二元酚的单元，第二二元酚; 和一种或多种含有杂基团的热塑性缩合聚合物。
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2.发明授权Amorphous polyamide having excellent oxygen barrier properties from para-xylylene diamine, isophthalic acid and adipic acid 失效具有优异的对苯二甲胺，间苯二甲酸和己二酸的氧阻隔性的无定形聚酰胺
公开(公告)号：US4983719A
公开(公告)日：1991-01-08
申请号：US383841
申请日：1989-07-21
CPC分类号： C08G69/265
摘要： An amorphous polyamide resin is provided having the combined properties of a high glass transition temperature and excellent oxygen barrier properties. The polyamide is obtained from the reaction products of para-xylylene diamine, adipic acid and isophthalic acid, and finds particular utility as a container layer for hot fill packaging of fruit juices.
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公开(公告)号：US5055531A
公开(公告)日：1991-10-08
申请号：US947660
申请日：1986-12-30
申请人： Daniel W. Fox , Edward N. Peters , Gary F. Smith , Paul D. Sybert
发明人： Daniel W. Fox , Edward N. Peters , Gary F. Smith , Paul D. Sybert
摘要： Copolymers are prepared by the interaction of a melt mix comprising a high molecular weight poly(alkylene arylate) resin with a high molecular weight polycarbonate or polyester carbonate and a catalyst, such as diphenyl phosphate. The copolymers are tough and are useful as molding compounds and are capable of maintaining dimensional stability at temperatures approaching their singale glass transition temperature. The copolymers are characterized by having substantially no content of polyester homopolymer and a ratio of arylate linkages to dihydric phenol arylate linkages of not substantially less than 20:1.
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公开(公告)号：US4652617A
公开(公告)日：1987-03-24
申请号：US816039
申请日：1986-01-03
申请人： Daniel W. Fox , Edward N. Peters , Gary F. Smith
发明人： Daniel W. Fox , Edward N. Peters , Gary F. Smith
摘要： A thermoplastic composition includes compatible blends of a mixed polycarbonate comprising units derived from a first dihydric phenol, which is a bis(hydroxyaryl) sulfone, a second dihydric phenol; and one or more thermoplastic condensation polymers containing hetero groups.
摘要翻译： 热塑性组合物包括混合聚碳酸酯的相容共混物，其包含衍生自作为双（羟基芳基）砜的第一二元酚的单元，第二二元酚; 和一种或多种含有杂基团的热塑性缩合聚合物。
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公开(公告)号：US4461877A
公开(公告)日：1984-07-24
申请号：US446875
申请日：1982-12-06
申请人： Daniel W. Fox , Edward N. Peters , Gary F. Smith
发明人： Daniel W. Fox , Edward N. Peters , Gary F. Smith
摘要： Thermoplastic compositions which are a solution of polycarbonate and poly(ethylene terephthalate) resins are described. These solutions are produced by melt admixture of a polycarbonate prepared from bis(3,5,dimethyl-4-hydroxy phenyl) sulfone and 2,2-bis(4-hydroxy-phenyl) propane and polyethylene terephthalate) to provide the composition with a single glass transition point.
摘要翻译： 描述了作为聚碳酸酯和聚（对苯二甲酸乙二醇酯）树脂溶液的热塑性组合物。 这些溶液通过由双（3,5-二甲基-4-羟基苯基）砜和2,2-双（4-羟基 - 苯基）丙烷和聚对苯二甲酸乙二醇酯制备的聚碳酸酯的熔融混合物熔融混合而制备，以使组合物具有 单一玻璃化转变点。
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6.发明授权Process for preparing purified bis(3,5-dialkyl-4-hydroxyphenyl) sulfone 失效制备纯化的双（3,5-二烷基-4-羟基苯基）砜的方法
公开(公告)号：US4384143A
公开(公告)日：1983-05-17
申请号：US259523
申请日：1981-05-01
申请人： Daniel W. Fox , Edward N. Peters
发明人： Daniel W. Fox , Edward N. Peters
IPC分类号： C08G63/00 , C07C303/44 , C07C317/22 , C08G64/00 , C08G64/08 , C07C147/10
CPC分类号： C07C317/00 , C08G64/081
摘要： Purified bis(3,5-dialkyl-4-hydroxyphenyl) sulfone useful for production of improved carbonate polymer is described. This sulfone is precipitated by deammoniation of an aqueous solution and then removed from the supernatant solution. This produces a product having minimal phenol sulfonic impurities. It may be employed to form carbonate polymer having improved physical properties.
摘要翻译： 描述了可用于生产改进的碳酸酯聚合物的纯化的双（3,5-二烷基-4-羟基苯基）砜。 该砜通过水溶液的脱氨沉淀，然后从上清液中除去。 这产生具有最小苯酚磺酸杂质的产物。 它可用于形成具有改善的物理性质的碳酸酯聚合物。
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公开(公告)号：US4950782A
公开(公告)日：1990-08-21
申请号：US286827
申请日：1988-12-20
申请人： Daniel W. Fox , Edward N. Peters , Paul D. Sybert
发明人： Daniel W. Fox , Edward N. Peters , Paul D. Sybert
摘要： Polycarbonate resins are chain-terminated with a group selected from those of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group consisting of hydrogen, halogen, hydrocarbyl of from 1 to 12 carbon atoms, inclusive; and halogen-substituted hydrocarbyl of 1 to 12 carbon atoms, inclusive; R.sub.1 is attached to a ring carbon atom at one of the 4, 5 or 6 positions; and R.sub.2 and R.sub.3 when taken together represent the divalent moiety of formula: --CH.dbd.CH.sub.2 --CH.sub.2 .dbd.CH--which effectively creates an additional fused aromatic ring structure. The resins exhibit a low plate-out when processed thermally.
摘要翻译： 聚碳酸酯树脂用选自下式的基团链终止：其中R 1，R 2和R 3各自独立地选自氢，卤素，含1至12个碳原子的烃基; 和含有1至12个碳原子的卤素取代的烃基; 在4-5个或6个位置的R1连接到环碳原子上; 并且R 2和R 3一起表示式：-CH = CH 2 -CH 2 = CH-的二价部分，其有效地产生另外的稠合芳环结构。 当热处理时，树脂表现出低的平板。
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公开(公告)号：US4885407A
公开(公告)日：1989-12-05
申请号：US217026
申请日：1988-07-11
申请人： Daniel W. Fox , Edward N. Peters
发明人： Daniel W. Fox , Edward N. Peters
CPC分类号： C08J11/16 , C07C37/0555 , C08J2367/02 , C08J2369/00 , Y02W30/705
摘要： A method for recovering a dihydric phenol from scrap polyester which comprisesa. contacting an aromatic polyester selected from the group consisting of polycarbonate, copolyestercarbonate and a polyarylate with(1) an aqueous ammoniacal solution of sufficient strength of sever the ester bonds of the aromatic polyester and(2) an alkylchloride in which the polyester is at least partially soluble,b. forming two mobile liquid phases, the top phase being aqueous and the bottom phase being the alkyl chloride and containing ammonium dihydric phenolate;c. separating the top phase from the bottom phase;d. recovering from the bottom phase the dihydric phenol.
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公开(公告)号：US4841015A
公开(公告)日：1989-06-20
申请号：US136664
申请日：1987-12-22
申请人： Daniel W. Fox , Edward N. Peters , Paul D. Sybert
发明人： Daniel W. Fox , Edward N. Peters , Paul D. Sybert
摘要： Polycarbonate resins are chain-terminated with a group selected from those of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group consisting of hydrogen, halogen, hydrocarbyl of from 1 to 12 carbon atoms, inclusive; and halogen-substituted hydrocarbyl of 1 to 12 carbon atoms, inclusive; R.sub.1 is attached to a ring carbon atom at one of the 4, 5 or 6 positions; and R.sub.2 and R.sub.3 when taken together represent the divalent moiety of formula:--CH.dbd.CH.sub.2 --CH.sub.2 .dbd.CH--which effectively creates an additional fused aromatic ring structure. The resins exhibit a low plate-out when processed thermally.
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10.发明授权Process for preparing aromatic polycarbonate of improved melt processability with fatty acid 失效制备具有改善的脂肪酸熔融加工性能的芳族聚碳酸酯的方法
公开(公告)号：US4762896A
公开(公告)日：1988-08-09
申请号：US12733
申请日：1987-02-09
CPC分类号： C08K5/09
摘要： The intrinsic viscosity of a high molecular weight aromatic polycarbonate resin is reduced and the melt processability is concomitantly enhanced by the inclusion of a small amount of a fatty acid or acids. The mixture of polymer and acid is more readily extrudable, without detriment to other desirable physical and chemical properties.
摘要翻译： 降低了高分子量芳族聚碳酸酯树脂的特性粘度，并且通过加入少量的脂肪酸或酸，同时提高了熔融加工性。 聚合物和酸的混合物更容易挤出，而不损害其它理想的物理和化学性质。
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