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    Perfluorovinyl compounds
    2.
    发明授权
    Perfluorovinyl compounds 失效
    全氟乙烯基化合物

    公开(公告)号：US5023380A

    公开(公告)日：1991-06-11

    申请号：US364665

    申请日：1989-06-09

    申请人： David A. Babb ,  Bobby R. Ezzell ,  Katherine S. Clement

    发明人： David A. Babb ,  Bobby R. Ezzell ,  Katherine S. Clement

    IPC分类号： C07C41/01 ,  C07C22/08 ,  C07C41/18 ,  C07C43/17 ,  C07C43/174 ,  C07C43/225 ,  C07C65/21 ,  C07C69/92 ,  C07C323/20 ,  C07C391/00 ,  C07C391/02 ,  C07F5/02 ,  C07F7/12 ,  C07F9/50 ,  C08F16/14 ,  C08F16/24 ,  C08F28/00 ,  C08F28/02 ,  C08F30/04

    CPC分类号： C07C43/17 ,  C07C22/08 ,  C07C43/225 ,  C07C65/21 ,  C07C69/92 ,  C07C2103/18

    摘要： Compounds have a structure represented by Formula I:CF.sub.2 =CF-X-R-(X-CF=CF.sub.2).sub.mwherein R represents an unsubstituted or inertly substituted hydrocarbyl group; each X is independently selected from the group consisting of groups having at least one non-carbon atom between R and --CF=CF.sub.2 ; and m is an integer of from 1 to about 3. Polymers formed from such compounds are also prepared. The compounds are preferably prepared by a method by a process comprising the steps of:(a) forming a salt having anion corresponding to a compound of Formula II:HX--R--(XH).sub.m ; wherein X, R and m are as defined for Formula I;(b) reacting the salt with a 1,2-dihalo-1,1,2, 2-tetrafluoroethane wherein the halo groups are iodine, bromine, chlorine or mixtures thereof, at least one halo group being bromine or iodine, to form a compound of Formula III:Z-CF.sub.2 CF.sub.2 -X-R-(X-CF.sub.2 CF.sub.2 - Z).sub.m wherein X, R and m are as defined for Formula I and each Z is independently iodine or bromine;(c) eliminating the halogen atoms represented by Z to form the perfluorovinyl compound represented by Formula I.

    摘要翻译： 化合物具有由式I表示的结构：CF 2 = CF-X-R-（X-CF = CF 2）m其中R表示未取代或惰性取代的烃基; 每个X独立地选自具有至少一个R和-CF = CF 2之间的非碳原子的基团; 并且m为1至约3的整数。还制备由这些化合物形成的聚合物。 化合物优选通过包括以下步骤的方法的方法制备：（a）形成具有对应于式II化合物的阴离子的盐：HX-R-（XH）m; 其中X，R和m如式I所定义; （b）使盐与1,2-二卤代-1,1,2,2-四氟乙烷反应，其中卤素是碘，溴，氯或其混合物，至少一个卤素基团是溴或碘，以形成 式III化合物：Z-CF 2 CF 2 -XR-（X-CF 2 CF 2 - Z）m其中X，R和m如式I所定义，各Z独立地为碘或溴; （c）除去由Z表示的卤素原子，形成由式I表示的全氟乙烯基化合物。

    Reactive compounds containing perfluorovinyl groups
    3.
    发明授权
    Reactive compounds containing perfluorovinyl groups 失效
    含全氟乙烯基的活性化合物

    公开(公告)号：US5198513A

    公开(公告)日：1993-03-30

    申请号：US668294

    申请日：1991-03-12

    申请人： Katherine S. Clement ,  David A. Babb ,  Bobby R. Ezzell ,  W. Frank Richey

    发明人： Katherine S. Clement ,  David A. Babb ,  Bobby R. Ezzell ,  W. Frank Richey

    IPC分类号： C07C43/225 ,  C07C45/65 ,  C07C45/70 ,  C07C45/72 ,  C07C47/575 ,  C07C49/84 ,  C07C65/21 ,  C07C69/017 ,  C07C69/92 ,  C07C205/37 ,  C07C217/84 ,  C08G64/10 ,  C08G64/14

    CPC分类号： C07C47/575 ,  C07C205/37 ,  C07C217/84 ,  C07C43/225 ,  C07C45/65 ,  C07C45/70 ,  C07C45/72 ,  C07C49/84 ,  C07C65/21 ,  C07C69/017 ,  C07C69/92 ,  C08G64/10 ,  C08G64/14

    摘要： A compound having at least one perfluorovinyl group and at least one functional group is suitable for reacting with and/or forming polymers. The compound is preferably of Formula I:(G)n-R-(X--CF.dbd.CF.sub.2).sub.mwherein R represents an optionally substituted hydrocarbyl group, X represents any group which links R and a perfluorovinyl group; n is the number of G groups, m is the number of (XCF.dbd.CF.sub.2) groups; and G represents any reactive functional group or a group convertible into a reactive functional groups.A process for preparing a compound of Formula I comprises the steps of:(a) preparing a 2-halotetrafluoro compound of the Formula III:(Q--CF.sub.2 --CF.sub.2 -X).sub.m -R-(G").sub.n wherein R, X, m and n are as described for Formula I and Q is bromine, chlorine or iodine; and G" is a functional group, or a functional group suitable for conversion into G;(b) chemically modifying group G" to produce functional group G; and(c) dehalogenating the 2-halotetrafluoro compound to form the corresponding trifluorovinyl compound.

    摘要翻译： 具有至少一个全氟乙烯基和至少一个官能团的化合物适于与聚合物反应和/或形成聚合物。 化合物优选为式I：（G）n-R-（X-CF = CF 2）m，其中R表示任选取代的烃基，X表示连接R和全氟乙烯基的任何基团; n是G基团的数目，m是（XCF = CF 2）基团的数目; G表示任何反应性官能团或可转化为反应性官能团的基团。 制备式I化合物的方法包括以下步骤：（a）制备式III的2-卤代四氟化合物：（Q-CF2-CF2-X）mR-（G“）n，其中R，X， m和n如式I所述，Q是溴，氯或碘; G“是官能团，或适合转化为G的官能团; （b）化学修饰基团G“以产生官能团G; 和（c）使2-卤代四氟化合物脱卤以形成相应的三氟乙烯基化合物。

    Perfluorovinyl compounds
    4.
    发明授权
    Perfluorovinyl compounds 失效
    全氟乙烯基化合物

    公开(公告)号：US5162468A

    公开(公告)日：1992-11-10

    申请号：US668296

    申请日：1991-03-12

    申请人： David A. Babb ,  Katherine S. Clement ,  Bobby R. Ezzell

    发明人： David A. Babb ,  Katherine S. Clement ,  Bobby R. Ezzell

    IPC分类号： C07C22/08 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C69/92

    CPC分类号： C07C43/17 ,  C07C22/08 ,  C07C43/225 ,  C07C65/21 ,  C07C69/92 ,  C07C2103/18

    摘要： Compounds have a structure represented by Formula I:CF.sub.2 .dbd.CF--X--R--(X--CF.dbd.CF.sub.2).sub.mwherein R represents an unsubstituted or inertly substituted hydrocarbyl group; each X is independently selected from the group consisting of groups having at least one non-carbon atom between R and --CF.dbd.CF.sub.2 ; and m is an integer of from 1 to about 3. Polymers formed from such compounds are also prepared. The compounds are preferably prepared by a method by a process comprising the steps of:(a) forming a salt having anion corresponding to a compound of Formula II:HX--R--(XH.sub.m); wherein X, R and m are as defined for Formula I:(b) reacting the salt with a 1,2-dihalo-1,1,2,2-tetrafluoroethane wherein the halo groups are iodine, bromine, chlorine or mixtures thereof, at least one halo group being bromine or iodine, to form a compound of Formula III:Z--CF.sub.2 CF.sub.2 --X--R--(X--CF.sub.2 CF.sub.2 --Z).sub.m wherein X, R and m are as defined for Formula I and each Z is independently iodine or bromine;(c) eliminating the halogen atoms represented by Z to form the perfluorovinyl compound represented by Formula I.

    摘要翻译： 化合物具有由式I表示的结构：CF 2 = CF-X-R-（X-CF = CF 2）m其中R表示未取代或惰性取代的烃基; 每个X独立地选自具有至少一个R和-CF = CF 2之间的非碳原子的基团; 并且m为1至约3的整数。还制备由这些化合物形成的聚合物。 化合物优选通过包括以下步骤的方法的方法制备：（a）形成具有对应于式II化合物的阴离子的盐：HX-R-（XHm）; 其中X，R和m如式I所定义：（b）盐与1,2-二卤代-1,1,2,2-四氟乙烷反应，其中卤素是碘，溴，氯或其混合物， 至少一个卤素基团是溴或碘，以形成式III的化合物：Z-CF 2 CF 2 -XR-（X-CF 2 CF 2 -Z）m其中X，R和m如式I所定义，各Z独立地为碘 或溴; （c）除去由Z表示的卤素原子，形成由式I表示的全氟乙烯基化合物。