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1.发明授权
公开(公告)号：US4791081A
公开(公告)日：1988-12-13
申请号：US947788
申请日：1986-12-30
CPC分类号： B01J37/0203 , B01J31/10 , C08F2/18 , C08F214/262 , B01J2231/32 , B01J2231/323 , B01J2231/4205 , B01J2231/52
摘要： This invention discloses improved heterogeneous acid catalysts and a method for preparing these catalysts. A heterogeneous acid catalyst has been prepared by coating a carrier with an aqueous emulsion containing a fluorocarbonsulfonic acid polymer in the sulfonyl fluoride form, removing the excess water, heating to a temperature above the softening point of the polymer for a time, and then converting the polymer to the active sulfonic acid form. The substrate has pores of about 0.1 micrometers or greater and a surface area of about 20 m.sup.2 /g or less.
摘要翻译： 本发明公开了改进的异构酸催化剂及其制备方法。 已经通过用含有磺酰氟形式的氟代磺酸聚合物的水性乳液涂布载体来制备多相酸催化剂，除去多余的水，加热到高于聚合物软化点一段时间的温度，然后将 聚合物与活性磺酸形式。 基材具有约0.1微米或更大的孔隙和约20m 2 / g或更小的表面积。
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公开(公告)号：US4358405A
公开(公告)日：1982-11-09
申请号：US247480
申请日：1981-03-25
IPC分类号： B01J23/86 , C07D203/02
CPC分类号： B01J23/862
摘要： A dehydration catalyst and process for making an alkylenimine from an alkanolamine wherein the catalyst contains oxides of either tantalum or niobium together with the oxides of iron and chromium and in which the ratios of the metals are:M.sub.10 Fe.sub.0.5-2.9 Cr.sub.0.3-1.7wherein M is tantalum or niobium.
摘要翻译： 脱水催化剂和由烷醇胺制备亚烷基亚胺的方法，其中催化剂含有钽或铌的氧化物和铁和铬的氧化物，其中金属的比例为：M10Fe0.5-2.9Cr0.3-1.7 其中M是钽或铌。
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3.发明授权
公开(公告)号：US4316708A
公开(公告)日：1982-02-23
申请号：US811739
申请日：1977-06-30
CPC分类号： B29B11/06 , B01J2/22 , B01J35/026 , B29C45/06 , B29C2045/0475
摘要： A machine and method of operation are disclosed for continuously molding solid pellets from a mud composition. In a specific application, the machine is useful for producing an oxidation catalyst in pellet form. The machine includes a rotatable disk having small openings therein, which provide mold cavities. As the disk is rotated, the mud composition is injected into the mold openings through an injection head, which rides against the front face of the disk. The mud is retained in each mold opening by a backing plate, which rides against the back face of the disk. Ambient air is passed through a heater located at the top of a housing which partially encloses the disk. The heated air is circulated downwardly on both sides of the disk to dry the mud in the mold openings. An ejection head is positioned such that it rides against the front face of the rotating disk at a point behind the injection head. Pressurized air is forced through air passages in the ejection head, which register with the mold openings. The air ejects the dried pellets, and they fall into a collection chute on the back side of the disk.
摘要翻译： 公开了一种机器和操作方法，用于从泥浆组合物连续模制固体颗粒。 在具体应用中，机器可用于制备颗粒形式的氧化催化剂。 该机器包括其中具有小开口的可旋转盘，其提供模腔。 当盘旋转时，泥浆组合物通过注射头注射到模具开口中，注射头抵靠盘的前表面。 泥浆通过背板抵靠在每个模具开口中，背板抵靠盘的背面。 环境空气通过位于壳体顶部的加热器，其部分地包围盘。 加热的空气在盘的两侧向下循环，以干燥模具开口中的泥浆。 喷射头被定位成使得其在注射头后面的一点处抵靠旋转盘的前表面。 加压空气被迫通过与模具开口对准的喷射头中的空气通道。 空气喷射干燥的颗粒，并且它们落入盘的背面的收集槽中。
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公开(公告)号：US4129600A
公开(公告)日：1978-12-12
申请号：US778907
申请日：1977-03-18
IPC分类号： B01J23/887 , C07C45/35 , C07C47/20 , C07C47/22
CPC分类号： B01J23/8876 , C07C45/35 , B01J2523/00
摘要： A method of preparing acrolein and methacrolein by oxidation of propylene and isobutylene over a new improved catalyst providing conversions and yields, each greater than 90% in a single-pass reactor. The improved catalyst contains within certain prescribed proportions the oxides of cobalt, iron, bismuth, molybdenum, potassium, and optionally silicon. The metals have atomic ratios ofCo.sub.3-10 Fe.sub.0.5-3.0 Bi.sub.0.5-3.0 Mo.sub.15 K.sub.0.01-0.5 Si.sub.0.5-3.0and are present in the form of oxides as pellets, spheres, or on a support. With a recycle system, a conversion of the olefin greater than 99% and yield to the aldehyde of greater than 95% are possible.
摘要翻译： 一种通过丙烯和异丁烯氧化制备丙烯醛和异丁烯醛的方法，在一种新型改进的催化剂中提供转化率和产率，每一种都在单程反应器中大于90％。 改进的催化剂在一定规定比例内含有钴，铁，铋，钼，钾和任选的硅的氧化物。 这些金属的原子比为Co3-10Fe0.5-3.0Bi0.5-3.0Mo15K0.01-0.5Si0.5-3。
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公开(公告)号：US4350830A
公开(公告)日：1982-09-21
申请号：US85568
申请日：1979-10-17
IPC分类号： B01J23/88 , B01J23/887 , C07C51/25 , C07C57/055
CPC分类号： B01J23/8878 , C07C51/252 , B01J2523/00
摘要： A method for preparing acrylic acid by oxidation of acrolein over a new and improved catalyst providing conversions of acrolein of greater than 99% with yields of acrylic acid in excess of 95%. The catalyst consists essentially of the oxides of molybdenum, vanadium, chromium, copper and titanium and optionally silicon on an inert carrier. Catalysts useful in the process contain the elements previously mentioned in the atomic ratios ofMo.sub.15 V.sub.5-10 Cu.sub.2-5 Cr.sub.0.2-2 Ti.sub.1-3
摘要翻译： 通过在新的和改进的催化剂上氧化丙烯醛制备丙烯酸的方法，其提供丙烯醛的转化率大于99％，丙烯酸的产率超过95％。 催化剂主要由钼，钒，铬，铜和钛的氧化物和任选的惰性载体上的硅组成。 在该方法中有用的催化剂包含先前提到的元素Mo15V5-10Cu2-5Cr0.2-2Ti的原子比
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公开(公告)号：US4035262A
公开(公告)日：1977-07-12
申请号：US678274
申请日：1976-04-19
CPC分类号： B01J23/8878 , C07C51/252 , B01J2523/00
摘要： A method of preparing acrylic acid by oxidation of acrolein over a new and improved catalyst providing conversions of acrolein of greater than 99% with yields of acrylic acid in excess of 95%. The catalyst consists essentially of the oxides of molybdenum, vanadium, chromium and copper and at least one of tantalum and niobium and optionally silicon on an inert carrier. Catalysts useful in the process contain the elements previously mentioned in the atomic ratios ofMo.sub.15 V.sub.5-10 Cu.sub.2-5 Cr.sub.0.2-2 M.sub.0.1-3where M is tantalum, niobium or mixtures thereof.
摘要翻译： 通过在新的和改进的催化剂上氧化丙烯醛制备丙烯酸的方法，提供大于99％的丙烯醛转化率，丙烯酸的产率超过95％。 催化剂基本上由钼，钒，铬和铜的氧化物以及钽和铌中的至少一种以及任选地在惰性载体上的硅组成。 在该方法中有用的催化剂包含以前在Mo15V5-10Cu2-5Cr0.2-2M0的原子比中提及的元素。
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公开(公告)号：US4289656A
公开(公告)日：1981-09-15
申请号：US169563
申请日：1980-07-17
CPC分类号： B01J23/862
摘要： A dehydration catalyst and process for making an alkylenimine from an alkanolamine wherein the catalyst contains oxides of either tantalum or niobium together with the oxides of iron and chromium and in which the ratios of the metals areM.sub.10 Fe.sub.0.5-2.9 Cr.sub.0.3-1.7wherein M is tantalum or niobium.
摘要翻译： 一种脱水催化剂和由烷醇胺制备亚烷基亚胺的方法，其中催化剂含有钽或铌的氧化物和铁和铬的氧化物，其中金属的比例为M10Fe0.5-2.9Cr0.3-1.7，其中 M是钽或铌。
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公开(公告)号：US4049577A
公开(公告)日：1977-09-20
申请号：US640616
申请日：1975-12-15
CPC分类号： B01J23/8876 , C07C45/35 , B01J2523/00
摘要： A method of preparing acrolein and methacrolein by oxidation of propylene and isobutylene over a new improved catalyst providing conversions and yields, each greater than 90% in a single-pass reactor. The improved catalyst contains within certain prescribed proportions the oxides of cobalt, iron, bismuth, molybdenum, potassium, and optionally silicon. The metals have atomic ratios ofCo.sub.3-10 Fe.sub.0.5-3.0 Bi.sub.0.5-3.0 Mo.sub.15 K.sub.0.01-0.5 Si.sub.0.5-3.0and are present in the form of oxides as pellets, spheres, or on a support. With a recycle system, a conversion of the olefin greater than 99% and yield to the aldehyde of greater than 95% are possible.
摘要翻译： 一种通过丙烯和异丁烯氧化制备丙烯醛和异丁烯醛的方法，在一种新型改进的催化剂中提供转化率和产率，每一种都在单程反应器中大于90％。 改进的催化剂在一定规定比例内含有钴，铁，铋，钼，钾和任选的硅的氧化物。 这些金属具有Co3-10Fe0.5-3.0 Bi0.5-3.0 Mo15K0.01-0.5Si0.5-3的原子比。
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9.发明授权Base coat and primer film-forming compositions containing polyacrylate fibers, acrylic polymer precursors, styrene and polyester resin particularly adapted for automobile finishing applications 失效含有聚丙烯酸酯纤维，丙烯酸聚合物前体，苯乙烯和聚酯树脂的底漆和底漆成膜组合物特别适用于汽车整理应用
公开(公告)号：US4992490A
公开(公告)日：1991-02-12
申请号：US176262
申请日：1988-03-31
IPC分类号： C09D167/06
CPC分类号： C09D167/06
摘要： A coating composition is described that is comprised of (1) polyacrylate fibers, (2) at least one monomer which forms an acrylic polymer, (3) styrene monomer, (4) unsaturated polyester resin, (5) a polymerization inhibitor (to prevent premature polymerization prior to application), and (6) an inert carrier in which each acrylic polymer-forming monomer and the styrene monomer are soluble. The inert carrier described and the miscible/soluble components form a medium wherein polyacrylate fiber suspension is easily achieved and maintained. The coating composition can be used as a base coat or primer without need for finishing prior to application of an overcoat of paint.
摘要翻译： 描述了一种涂料组合物，其包含（1）聚丙烯酸酯纤维，（2）至少一种形成丙烯酸类聚合物的单体，（3）苯乙烯单体，（4）不饱和聚酯树脂，（5）阻聚剂 在应用之前的过早聚合）和（6）其中每个丙烯酸聚合物形成单体和苯乙烯单体都是可溶的惰性载体。 描述的惰性载体和可混溶/可溶组分形成其中聚丙烯酸酯纤维悬浮液容易实现和维持的介质。 涂料组合物可以在施涂涂料外涂层之前用作底涂层或底漆，而不需要整理。
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公开(公告)号：US4301036A
公开(公告)日：1981-11-17
申请号：US170318
申请日：1980-07-18
IPC分类号： B01J23/30 , B01J37/02 , C07D203/02 , B01J21/08
CPC分类号： B01J37/0201 , B01J23/30 , C07D203/02
摘要： A dehydration catalyst containing tungsten oxide on a low surface area support and having a silica coating thereon. The catalyst has increased life and is useful for the dehydration of alkanolamines in making alkylenimines, e.g. ethanolamine is dehydrated to ethylenimine.
摘要翻译： 在低表面积上含有氧化钨的脱水催化剂被支撑并在其上具有二氧化硅涂层。 催化剂具有增加的寿命，并且可用于在制备亚烷基亚胺时脱烷基链烷醇胺。 乙醇胺脱水至乙烯亚胺。
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