Fatty acid amide lubricity aids and related methods for improvement of lubricity of fuels
    1.
    发明授权
    Fatty acid amide lubricity aids and related methods for improvement of lubricity of fuels 失效
    脂肪酸酰胺润滑助剂及相关的改善燃料润滑性的方法

    公开(公告)号:US06562086B1

    公开(公告)日:2003-05-13

    申请号:US08883634

    申请日:1997-06-26

    Abstract: A fuel composition of improved lubricity comprises a lubricity-increasing amount of a lubricity aid dissolved in low sulfur diesel fuel and spark ignition fuels. The lubricity aid is an alkanolamide of a fatty acid, an alkanolamide of a modified fatty acid or a mixture thereof. If the lubricity aid is other than an alkanolamide of an aryl-substituted fatty acid, the composition further necessarily comprises a haze-inhibiting amount of a dehazer. The lubricity of such fuels may be enhanced without acceptably increasing the tendency of the fuel to become hazy upon contact with water.

    Abstract translation: 具有改善的润滑性的燃料组合物包括溶解在低硫柴油燃料和火花点燃燃料中的润滑增加量的润滑助剂。 润滑助剂是脂肪酸的链烷醇酰胺,改性脂肪酸的链烷醇酰胺或其混合物。 如果润滑助剂不是芳基取代的脂肪酸的链烷醇酰胺,则组合物还必须包含雾度抑制量的除雾剂。 这种燃料的润滑性可以增强,而不会可接受地增加燃料在与水接触时变得模糊的倾向。

    Quaternary ammonium hydroxides as mercaptan scavengers
    3.
    发明授权
    Quaternary ammonium hydroxides as mercaptan scavengers 有权
    季铵氢氧化物作为硫醇清除剂

    公开(公告)号:US6013175A

    公开(公告)日:2000-01-11

    申请号:US152807

    申请日:1998-09-14

    CPC classification number: C10G29/20 C07C213/04

    Abstract: A method for scavenging mercaptans in a hydrocarbon fluid is disclosed. According to the method, an effective mercaptan-scavenging amount of an aqueous scavenging composition is added to the fluid. The composition comprises a quaternary ammonium hydroxide of the formula R.sup.1 R.sup.2 R.sup.3 R.sup.4 NOH. R.sup.1 and R.sup.2 are, independently, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. R.sup.3 is an alkyl group of from two to about eighteen carbon atoms, an aryl group of from two to about eighteen carbon atoms or an alkylaryl group of from four to about eighteen carbon atoms. R.sup.2 and R.sup.3 may be joined to form a heterocyclic ring including the N and optionally an oxygen atom. R.sup.4 is --(CH.sub.2 CH.sub.2 O).sub.n H, wherein n is an integer from one to about eighteen, or --CHR.sup.5 CHR.sup.6 Y, wherein R.sup.5 and R.sup.6 are, independently, hydrogen, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. Y is a non-acidic group. Related compositions and methods are also disclosed.

    Abstract translation: 公开了一种在烃流体中清除硫醇的方法。 根据该方法,将有效的硫醇清除量的除水组合物加入到流体中。 组合物包含式R1R2R3R4NOH的季铵氢氧化物。 R1和R2独立地为1至约18个碳原子的烷基,6至约18个碳原子的芳基或7至约18个碳原子的烷基芳基。 R3是具有2至约18个碳原子的烷基,2至约18个碳原子的芳基或4至约18个碳原子的烷基芳基。 R2和R3可以连接形成包括N和任选的氧原子的杂环。 R4为 - (CH2CH2O)nH,其中n为1至约18的整数,或-CHR 5 CHR 6 Y,其中R 5和R 6独立地为氢,1至约18个碳原子的烷基,6至 约十八个碳原子或七至十八个碳原子的烷基芳基。 Y是非酸性基团。 还公开了相关的组合物和方法。

    Use of olefinic imines to scavenge sulfur species
    4.
    发明授权
    Use of olefinic imines to scavenge sulfur species 失效
    使用烯属亚胺清除硫物质

    公开(公告)号:US5567213A

    公开(公告)日:1996-10-22

    申请号:US636813

    申请日:1996-04-25

    CPC classification number: C10L1/2283 C09K8/532 C10G29/20

    Abstract: A method for scavenging sulfur species from a petroleum-derived medium is disclosed. The method comprises contacting the medium with sulfur species scavenging amount of an imine of the formula ##STR1## wherein x is an integer from 1 to 10, R' is an organic moiety having a number of valences equal to x, R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In an alternative embodiment, the imine is produced by a condensation reactionic between an amine having at least one primary amino group and a carbonyl of the formula ##STR2## wherein R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In yet other embodiments, the imine is produced by a condensation reaction between an amine having at least one primary amino group and an aldehyde having at least one alpha-hydrogen in an aldehyde to primary amino group molar ratio of at least about 2:1, are also disclosed.

    Abstract translation: 公开了一种从石油衍生的介质中清除硫物质的方法。 该方法包括使培养基与清除硫的物质接触式为式的亚胺,其中x是1至10的整数,R'是具有等于x的价数的有机部分,R 1是氢或 一价有机部分,R是一价烯烃部分,条件是R和R 1含有总共约4至约40个碳原子。 在替代实施方案中,亚胺通过具有至少一个伯氨基的胺与式有机部分的羰基之间的缩合反应产生,R是一价烯烃部分,条件是R和R 1含有 约4至约40个碳原子。 在其它实施方案中,亚胺通过具有至少一个伯氨基的胺与具有至少一个α-羟基的醛与醛与伯氨基摩尔比至少约2:1的缩合反应产生, 也被披露。

    Quaternary ammonium hydroxides as mercaptan scavengers

    公开(公告)号:US5840177A

    公开(公告)日:1998-11-24

    申请号:US931675

    申请日:1997-09-16

    CPC classification number: C10G29/20 C07C213/04

    Abstract: A method for scavenging mercaptans in a hydrocarbon fluid is disclosed. According to the method, an effective mercaptan-scavenging amount of an aqueous scavenging composition is added to the fluid. The composition comprises a quaternary ammonium hydroxide of the formula R.sup.1 R.sup.2 R.sup.3 R.sup.4 NOH. R.sup.1 and R.sup.2 are, independently, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. R.sup.3 is an alkyl group of from two to about eighteen carbon atoms, an aryl group of from two to about eighteen carbon atoms or an alkylaryl group of from four to about eighteen carbon atoms. R.sup.2 and R.sup.3 may be joined to form a heterocyclic ring including the N and optionally an oxygen atom. R.sup.4 is --(CH.sub.2 CH.sub.2 O).sub.n H, wherein n is an integer from one to about eighteen, or --CHR.sup.5 CHR.sup.6 Y, wherein R.sup.5 and R.sup.6 are, independently, hydrogen, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. Y is a non-acidic group. Related compositions and methods are also disclosed.

    Use of olefinic imines to scavenge sulfur species
    6.
    发明授权
    Use of olefinic imines to scavenge sulfur species 失效
    使用烯属亚胺清除硫物质

    公开(公告)号:US5567212A

    公开(公告)日:1996-10-22

    申请号:US430208

    申请日:1995-04-27

    CPC classification number: C10L1/2283 C09K8/532 C10G29/20

    Abstract: A method for scavenging sulfur species from a petroleum-derived medium is disclosed. The method comprises contacting the medium with sulfur species scavenging amount of an imine of the formula ##STR1## wherein x is an integer from 1 to 10, R' is an organic moiety having a number of valences equal to x, R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In an alternative embodiment, the imine is produced by a condensation reaction between an amine having at least one primary amino group and a carbonyl of the formula ##STR2## wherein R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In yet other embodiments, the imine is produced by a condensation reaction between an amine having at least one primary amino group and an aldehyde having at least one alpha-hydrogen in an aldehyde to primary amino group molar ratio of at least about 2:1, are also disclosed.

    Abstract translation: 公开了一种从石油衍生的介质中清除硫物质的方法。 该方法包括使培养基与清除硫的物质接触式为式的亚胺,其中x是1至10的整数,R'是具有等于x的价数的有机部分,R 1是氢或 一价有机部分,R是一价烯烃部分,条件是R和R 1含有总共约4至约40个碳原子。 在另一个实施方案中,亚胺是通过具有至少一个伯氨基的胺和式的羰基之间的缩合反应产生的,其中R1是氢或一价有机部分,R是一价的 烯烃部分,条件是R和R 1含有总共约4至约40个碳原子。 在其它实施方案中,亚胺通过具有至少一个伯氨基的胺与具有至少一个α-羟基的醛与醛与伯氨基摩尔比至少约2:1的缩合反应产生, 也被披露。

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