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公开(公告)号：US06806326B2
公开(公告)日：2004-10-19
申请号：US10037335
申请日：2001-11-06
IPC分类号： C08F444
CPC分类号： C08F10/02 , C07F7/10 , C07F9/5045 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08L23/08 , C08L23/0838 , C08L25/06 , C08L2203/14 , Y10S526/943 , C08F2/34 , C08L2666/04 , C08F2500/12 , C08F2500/03 , C08F212/08 , C08F214/08 , C08F210/14 , C08F2500/08 , C08F2500/20 , C08F2500/26 , C08F2500/02 , C08F2500/07 , C08F210/08 , C08F210/06 , C08F212/14
摘要： Metal complexes having constrained geometry and a process for preparation thereof, addition polymerization catalysts formed therefrom, processes for preparation of such addition polymerization catalysts, methods of use, and novel polymers formed thereby, including EIPE resins and pseudo-random copolymers, are disclosed and claimed.
摘要翻译： 具有约束几何形状的金属络合物及其制备方法，由其形成的加成聚合催化剂，由此形成的加成聚合催化剂，使用方法和由其形成的新型聚合物的方法，包括EIPE树脂和伪随机共聚物， 。
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公开(公告)号：US06686488B2
公开(公告)日：2004-02-03
申请号：US10037765
申请日：2001-11-06
申请人： David R. Wilson , Robert K. Rosen
发明人： David R. Wilson , Robert K. Rosen
IPC分类号： C07F1700
CPC分类号： C08F10/02 , C07F7/10 , C07F9/5045 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08L23/08 , C08L23/0838 , C08L25/06 , C08L2203/14 , Y10S526/943 , C08F2/34 , C08L2666/04 , C08F2500/12 , C08F2500/03 , C08F212/08 , C08F214/08 , C08F210/14 , C08F2500/08 , C08F2500/02 , C08F2500/20 , C08F2500/26 , C08F210/06 , C08F2500/07 , C08F210/08
摘要： Metal complexes having constrained geometry and a process for preparation thereof, addition polymerization catalysts formed therefrom, processes for preparation of such addition polymerization catalysts, methods of use, and novel polymers formed thereby, including ElPE resins and pseudo-random copolymers, are disclosed and claimed.
摘要翻译： 具有约束几何形状的金属络合物及其制备方法，由其形成的加成聚合催化剂，由此形成的加成聚合催化剂，使用方法和由其形成的新型聚合物的方法，包括ElPE树脂和假无规共聚物， 。
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3.发明授权Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom 失效钛（II）或锆（II）络合物及其加成聚合催化剂
公开(公告)号：US5470993A
公开(公告)日：1995-11-28
申请号：US241523
申请日：1994-05-12
IPC分类号： C07F17/00 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F4/642
CPC分类号： C07F17/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F2420/02 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592
摘要： Novel titanium or zirconium complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +2 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes; catalytic derivatives of such complexes; methods of preparation; and the use thereof as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
摘要翻译： 新的钛或锆络合物含有一个且仅一个环离域，阴离子，π键合基团，其中金属处于+2形式氧化态并具有桥连配体结构，也称为约束几何配合物; 这种络合物的催化衍生物; 准备方法; 以及其作为用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂的用途。
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4.发明授权公开(公告)号：US06800701B2
公开(公告)日：2004-10-05
申请号：US10437161
申请日：2003-05-13
申请人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen
发明人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen
IPC分类号： C08F444
CPC分类号： C07F17/00 , C07C13/32 , C07C13/66 , C07C2602/14 , C07F7/10 , C08F4/65908 , C08F4/65912 , C08F4/65922 , C08F210/02 , C08F2420/02 , C08F2420/05 , Y10S526/943 , C08F4/6592 , C08F212/08
摘要： Compounds and metal complexes comprising a polycyclic, fused ring ligand or inertly substituted derivative thereof having up to 60 atoms other than hydrogen, said ligand comprising at least: (1) a cyclopentadienyl ring, (2) a 6, 7, or 8 membered ring other than a 6-carbon aromatic ring, and (3) an aromatic ring, with the proviso that said 6, 7, or 8 membered ring (2), is fused to both the cyclopentadienyl ring (1), and the aromatic ring (3), polymerization catalysts, a process to prepare the novel compounds and complexes, and olefin polymerization processes using the same are disclosed.
摘要翻译： 包含多于60个氢原子的多环，稠环配体或其惰性取代的衍生物的化合物和金属络合物，所述配体至少包括：（1）环戊二烯基环，（2）6,7或8元环 除了6碳芳环以外，和（3）芳香环，条件是所述6,7或8元环（2）与环戊二烯基环（1）和芳环（ 3），聚合催化剂，制备新型化合物和络合物的方法，以及使用其的烯烃聚合方法。
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5.发明授权
公开(公告)号：US6017842A
公开(公告)日：2000-01-25
申请号：US896897
申请日：1997-07-18
申请人： Robert K. Rosen , James C. Stevens
发明人： Robert K. Rosen , James C. Stevens
IPC分类号： B01J31/22 , C08F4/44 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02
CPC分类号： B01J31/1805 , B01J31/14 , B01J31/2295 , C08F10/00 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943
摘要： Catalyst compositions that are highly tolerant of catalyst poisons comprising a catalytic derivative of a Group 4 metallocene metal complex and an Group 13 metal compound according to the formula R.sup.1.sub.2 M"(NR.sup.2.sub.2),wherein R.sup.1 and R.sup.2 independently each occurrence is a hydrocarbyl, silyl, halocarbyl, halohydrocarbyl, hydrocarbyl-substituted silyl, halocarbyl-substituted silyl, or halohydrocarbyl-substituted silyl group, said R.sup.1 and R.sup.2 having from 1 to 30 carbon, silicon, or mixtures of carbon and silicon atoms, andM" is a Group 13 metal,the molar ratio of complex to Group 13 compound being from 1:0.1 to 1:100.
摘要翻译： 催化剂组合物高度耐受催化剂毒物，其包含第4族金属茂金属络合物的催化衍生物和根据式R12M“（NR22）的第13族金属化合物，其中R1和R2各自独立地为烃基，甲硅烷基， 卤代烃基，卤代烃基，烃基取代的甲硅烷基，卤代烃基取代的甲硅烷基或卤代烃基取代的甲硅烷基，所述R 1和R 2具有1至30个碳，硅或碳和硅原子的混合物，M“为13 金属，络合物与13族化合物的摩尔比为1:0.1至1:100。
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6.发明授权Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides 失效从金属氢氧化物合成环戊二烯基金属配位络合物
公开(公告)号：US5703257A
公开(公告)日：1997-12-30
申请号：US469185
申请日：1995-06-06
CPC分类号： C07F17/00 , C08F10/00 , C08F4/6592 , Y10S526/943
摘要： A process for preparing bridged mono- and bis(cyclopentadienyl) metal dihydrocarbyloxy coordination complexes (I) by contacting in the presence of an aprotic organic diluent a metal compound of the formula M(OR).sub.4 with a dianionic salt compound. A process for preparing bridged mono- and bis(cyclopentadienyl) dihydrocarbyl metal coordination complexes (II) by contacting a complex (I) with a hydrocarbylation agent. A process for preparing bridged mono- and bis(cyclopentadienyl) metal dihalide coordination complexes (III) by contacting a complex (I) with a halogenation agent.
摘要翻译： 通过在非质子有机稀释剂存在下使式M（OR）4的金属化合物与二 - 阴离子盐化合物接触来制备桥联单 - 和双（环戊二烯基）金属二氢氧羰基配位络合物（I）的方法。 通过使络合物（I）与烃基化合物接触来制备桥联单 - 和双（环戊二烯基）二烃基金属配位络合物（II）的方法。 通过使络合物（I）与卤化剂接触来制备桥联单 - 和双（环戊二烯基）金属二卤化物配位络合物（III）的方法。
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7.发明授权Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides 失效从金属氢氧化物合成环戊二烯基金属配位络合物
公开(公告)号：US5504223A
公开(公告)日：1996-04-02
申请号：US186402
申请日：1994-01-25
CPC分类号： C07F17/00 , C08F10/00 , C08F4/6592 , Y10S526/943
摘要： A process for preparing bridged mono- and bis(cyclopentadienyl) metal dihydrocarbyloxy coordination complexes (I) by contacting in the presence of an aprotic organic diluent a metal compound of the formula M(OR).sub.4 with a dianionic salt compound. A process for preparing bridged mono- and bis(cyclopentadienyl)dihydrocarbyl metal coordination complexes (II) by contacting a complex (I) with a hydrocarbylation agent. A process for preparing bridged mono- and bis(cyclopentadienyl) metal dihalide coordination complexes (III) by contacting a complex (I) with a halogenation agent.
摘要翻译： 通过在非质子有机稀释剂存在下使式M（OR）4的金属化合物与二 - 阴离子盐化合物接触来制备桥联单 - 和双（环戊二烯基）金属二氢氧羰基配位络合物（I）的方法。 通过使络合物（I）与烃基化合物接触来制备桥联单 - 和双（环戊二烯基）二烃基金属配位络合物（II）的方法。 通过使络合物（I）与卤化剂接触来制备桥联单 - 和双（环戊二烯基）金属二卤化物配位络合物（III）的方法。
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公开(公告)号：US6121185A
公开(公告)日：2000-09-19
申请号：US227478
申请日：1999-01-08
IPC分类号： B01J31/16 , C07F5/02 , C08F2/04 , C08F4/603 , C08F4/619 , C08F4/64 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/18
CPC分类号： C08F10/00 , C07F5/027 , C08F2410/01 , C08F4/61908 , C08F4/61912 , C08F4/65912 , C08F4/6592
摘要： A catalyst activator, comprising a cation which is a Bronsted acid capable of donating a proton, and an inert, compatible, noncoordinating, anion, characterized by a solubility constant at 25.degree. C. in hexane, cyclohexane or methylcyclohexane of at least 5 weight percent.
摘要翻译： 催化剂活化剂，其包含阳离子，其是能够提供质子的布朗斯台德酸，和惰性的，相容的非配位阴离子，其特征在于在25℃下在己烷，环己烷或甲基环己烷中的溶解度常数至少为5重量％ 。
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公开(公告)号：US5919983A
公开(公告)日：1999-07-06
申请号：US818530
申请日：1997-03-14
IPC分类号： B01J31/16 , C07F5/02 , C08F2/04 , C08F4/603 , C08F4/619 , C08F4/64 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F9/02
CPC分类号： C08F10/00 , C07F5/027 , C08F2410/01 , C08F4/61908 , C08F4/61912 , C08F4/65912 , C08F4/6592
摘要： A catalyst activator, comprising a cation which is a Bronsted acid capable of donating a proton, and an inert, compatible, noncoordinating, anion, characterized by a solubility constant at 25.degree. C. in hexane, cyclohexane or methylcyclohexane of at least 5 weight percent.
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公开(公告)号：US5770538A
公开(公告)日：1998-06-23
申请号：US602544
申请日：1996-02-20
CPC分类号： C07F17/00 , C08F10/00 , C08F10/02 , C08F4/65908 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent anionic ligand group; catalytic derivatives of such complexes including novel zwiterionic complexes; and the use thereof as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
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