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1.发明授权Formulations comprising isosorbide-modified unsaturated polyester resins and low profile additives which produce low shrinkage matrices 有权含有异山梨醇改性的不饱和聚酯树脂和低收缩率基质的低分子添加剂的制剂公开(公告)号：US09034982B2
公开(公告)日：2015-05-19
申请号：US12539659
申请日：2009-08-12
申请人： Dejan D. Andjelkovic , Darcy A. Culkin , Roman Loza , Michael J. Sumner , Timothy A. Tufts , Dennis H. Fisher
发明人： Dejan D. Andjelkovic , Darcy A. Culkin , Roman Loza , Michael J. Sumner , Timothy A. Tufts , Dennis H. Fisher
CPC分类号： C08K5/0008 , C08G63/676 , C08J5/24 , C08J2367/06 , C08L67/06 , C08L101/00
摘要： Formulations comprising an isosorbide-modified unsaturated polyester comprising maleic acid, fumaric acid, itaconic acid or maleic anhydride and isosorbide and one or more low profile additives. The formulations exhibit better shrink control in molding compound formulations with standard low profile additives than their non-isosorbide-modified analogues. These isosorbide-modified unsaturated polyester resins may be applied in molding compounds like sheet molding compounds or bulk molding compounds and may be components of fiber reinforced composites or other composite materials.
摘要翻译： 包含异山梨醇改性的不饱和聚酯的制剂，其包含马来酸，富马酸，衣康酸或马来酸酐和异山梨醇和一种或多种低调添加剂。 该配方在具有标准薄型添加剂的模塑料配方中比其非异山梨醇改性的类似物表现出更好的收缩控制。 这些异山梨醇改性的不饱和聚酯树脂可以应用于模塑化合物如片状模塑料或块状模塑料中，并且可以是纤维增强复合材料或其它复合材料的组分。
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公开(公告)号：US20080090954A1
公开(公告)日：2008-04-17
申请号：US11581381
申请日：2006-10-17
IPC分类号： C08G18/42
CPC分类号： C08G18/672 , C08L67/06 , C08G18/62 , C08L2666/02
摘要： Low shrinkage sheet molded composite (SMC) formulations and methods for producing low shrinkage sheet molded composites from the SMC formulations are provided. Thermosetting low (LPA) profile additive compositions and the use of thermosetting LPA compositions in producing low shrinkage sheet molded composites are also provided. The LPA compositions allow for the production of sheet molded composites with a high quality surface profile which have both high mechanical and dimensional stability.
摘要翻译： 提供了低收缩薄片模制复合材料（SMC）制剂和用于从SMC制剂制备低收缩薄片模塑复合材料的方法。 还提供了热固性低（LPA）型材添加剂组合物和热固性LPA组合物在生产低收缩性片材模塑复合材料中的用途。 LPA组合物允许生产具有高机械和尺寸稳定性的高质量表面轮廓的片状模塑复合材料。
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公开(公告)号：US5504151A
公开(公告)日：1996-04-02
申请号：US334546
申请日：1994-11-08
CPC分类号： C08L67/06
摘要： This invention is the polycapped oligomer adduct of a long chain fatty acid with a multi hydroxy functional or multi epoxy functional compound. This polycapped oligomer is useful in resin compositions to enhance the performance of thermoplastic low profile additives which improve the surface quality of molded composites such as automotive body panels.
摘要翻译： 本发明是长链脂肪酸与多羟基官能或多环氧官能化合物的多孔低聚物加合物。 这种聚合低聚物可用于树脂组合物中，以增强热塑性低分子添加剂的性能，其改善了模塑复合材料如汽车车身板的表面质量。
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公开(公告)号：US4757115A
公开(公告)日：1988-07-12
申请号：US931496
申请日：1986-11-17
CPC分类号： C08G18/3827 , C08G18/672 , C08G18/68 , C08G2120/00
摘要： Thermoset polymers are prepared by reacting an ethylenically unsaturated resin monomer and a bicyclic amide acetal with a polyisocyanate in the absence or presence of a vinyl monomer. Reaction rates are suitable for effecting RIM processing. The resultant polymers exhibit improved impact resistance. Further variation in physical properties can be achieved through the use of a diol chain extender for the polyisocyanate.
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公开(公告)号：US4708971A
公开(公告)日：1987-11-24
申请号：US850647
申请日：1986-04-11
申请人： Anil B. Goel , Timothy A. Tufts
发明人： Anil B. Goel , Timothy A. Tufts
CPC分类号： C08G18/3827 , C08G18/0842 , C08K5/0016 , C08G2120/00
摘要： The process for preparing polyurethanes by the reaction of a bicyclic amide acetal and a polyisocyanate in the presence of a plasticizer such as dioctyl phthalate and a polyurethane catalyst such as stannous octoate is described.
摘要翻译： 描述了在增塑剂如邻苯二甲酸二辛酯和聚氨酯催化剂如辛酸亚锡存在下通过双环酰胺缩醛和多异氰酸酯反应制备聚氨酯的方法。
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公开(公告)号：US4855368A
公开(公告)日：1989-08-08
申请号：US212105
申请日：1988-06-21
IPC分类号： C08F299/06 , C08G18/65 , C08G18/67 , C08G18/68
CPC分类号： C08G18/68 , C08F299/06 , C08G18/6529 , C08G18/6705 , C08G18/672 , C08G2120/00
摘要： Thermoset resinous molding compositions are provided by essentially instantaneously combining and reacting three basic resin forming components. The latter include an oligomeric ester or polyester containing polymerizable unsaturation and free hydroxyl group(s); a polyisocyanate; and an aromatic polyamine. The indicated thermosetting resin systems are especially adapted for use in a reaction injection molding (RIM) operation.
摘要翻译： 通过基本上即时地组合和反应三种基本的树脂形成组分来提供热固性树脂模塑组合物。 后者包括含有可聚合不饱和度和游离羟基的低聚酯或聚酯; 多异氰酸酯; 和芳族多胺。 指示的热固性树脂体系特别适用于反应注射成型（RIM）操作。
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7.发明授权Storage stable blend comprising a long chain polyol, a short chain diol and a urethane 失效储存稳定的共混物，包括长链多元醇，短链二醇和氨基甲酸酯
公开(公告)号：US4839087A
公开(公告)日：1989-06-13
申请号：US185252
申请日：1988-04-20
申请人： Timothy A. Tufts
发明人： Timothy A. Tufts
CPC分类号： C08K5/205 , C08G18/6674 , C08G2120/00 , C08G2130/00
摘要： Disclosed is a storage stable blend of a long chain polyol and a short chain diol wherein the diol is present in an amount whereby the diol and polyol form an incompatible blend. The blend is rendered storage stable by the addition of a compatibilizing amount of a urethane.
摘要翻译： 公开了长链多元醇和短链二醇的储存稳定共混物，其中二醇的存在量为二醇和多元醇形成不相容的共混物。 通过加入相容剂量的氨基甲酸酯使共混物保持稳定。
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8.发明授权Resinous molding compositions of a phenol, an oxazoline and an epoxy compound 失效苯酚，恶唑啉和环氧化合物的树脂成型组合物
公开(公告)号：US4652620A
公开(公告)日：1987-03-24
申请号：US784399
申请日：1985-10-04
CPC分类号： C08G59/56 , Y10T428/31627 , Y10T428/31942
摘要： The disclosure is directed to thermoset resinous compositions having utility in the area of surface coating and molding applications, the latter including the preparation of high performance composites and the use in reaction injection molding processes. The contemplated compositions are obtained by polymerizing a reaction mixture comprising a polyfunctional 2-oxazoline compound, a compound or oligomer containing a plurality of aromatic hydroxyl groups and a polyfunctional epoxide.
摘要翻译： 本公开涉及在表面涂层和模塑应用领域具有实用性的热固性树脂组合物，后者包括制备高性能复合材料以及在反应注射成型工艺中的用途。 考虑的组合物通过聚合包含多官能2-恶唑啉化合物，含有多个芳族羟基的化合物或低聚物和多官能环氧化物的反应混合物而获得。
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9.发明授权Use of bicyclic amide acetals in polyurethane/polyisocyanurate rigid foams as reactive compatibilizers 失效在聚氨酯/聚异氰脲酸酯刚性泡沫中使用双环酰胺缩醛作为反应性增容剂
公开(公告)号：US4579877A
公开(公告)日：1986-04-01
申请号：US732490
申请日：1985-05-10
申请人： Anil B. Goel , Timothy A. Tufts
发明人： Anil B. Goel , Timothy A. Tufts
CPC分类号： C08G18/4225 , C08G18/28 , C08G18/3827 , C08G2105/02 , Y10S521/902
摘要： The use of bicyclic amide acetals as compatibilizing agents in the preparation of rigid polyurethane/polyisocyanate foams from certain polyol mixtures, polyisocyanates and fluorocarbon blowing agents is disclosed.
摘要翻译： 公开了在制备来自某些多元醇混合物，多异氰酸酯和氟代烃发泡剂的硬质聚氨酯/多异氰酸酯泡沫体中使用双环酰胺缩醛作为相容剂。
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10.发明授权Thermoset molding compositions catalyzed by 1,4-benzoquinone salts of 1,8-diaza-bicyclo(5.4.0)undec-7-ene 失效由1,8-二氮杂 - 双环（5.4.0）十一碳-7-烯的1,4-苯醌盐催化的热固性成型组合物
公开(公告)号：US4880846A
公开(公告)日：1989-11-14
申请号：US277884
申请日：1988-11-30
IPC分类号： C08G18/20
CPC分类号： C08G18/2063 , C08G2120/00
摘要： Disclosed is a process for the catalyzed reaction of an isocyanate and an active hydrogen compound wherein the reaction is conducted in the presence of a novel catalyst comprising the salt of 1,8-diazobicyclo(5.4.0)undec-7-ene and 1,4-benzoquinone. Preferred catalyzed reaction mixtures comprise Reaction Injection Molding urethanes (RIM). The novel catalyst salts provide a controlled induction period prior to the onset of gelation of the reaction mixture while providing complete cure of the reaction mixture thereafter.
摘要翻译： 公开了一种异氰酸酯和活性氢化合物的催化反应的方法，其中反应在包含1,8-二氮双环（5.4.0）十一碳-7-烯和1,1-二氮杂双环（5.4.0）十一碳-7-烯的盐的新型催化剂的存在下进行， 4-苯醌。 优选的催化反应混合物包括反应注射成型聚氨酯（RIM）。 新型催化剂盐在反应混合物凝胶化开始之前提供受控的诱导期，同时提供完全固化反应混合物。
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