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1.发明申请公开(公告)号：US20090221850A1
公开(公告)日：2009-09-03
申请号：US11911862
申请日：2006-04-13
IPC分类号： C07C205/02
CPC分类号： C07C333/20 , C07C333/30 , C07F9/4006
摘要： The present invention relates to a novel process for preparing alkoxyamines from a nitroxide and a dithiocarbamate by photolysis reaction.This process, which does not generate effluent containing metals, may be carried out in batch or in continuous mode and takes place at a lower temperature than the known processes for synthesizing alkoxyamines.
摘要翻译： 本发明涉及通过光解反应从氮氧化物和二硫代氨基甲酸盐制备烷氧基胺的新方法。 这种不产生含有金属的流出物的方法可以分批或连续进行，并且在比合成烷氧基胺的已知方法更低的温度下进行。
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2.发明授权Alkoxyamines originating from β-phoshorated nitroxides and use thereof in radical polymerisation 有权衍生自＆bgr-的硝基氧化物的烷氧基胺及其在自由基聚合中的用途公开(公告)号：US07772340B2
公开(公告)日：2010-08-10
申请号：US10523481
申请日：2003-07-23
申请人： Jean-Luc Couturier , Olivier Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo , Florence Chauvin , Pierre-Emmanuel Dufils
发明人： Jean-Luc Couturier , Olivier Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo , Florence Chauvin , Pierre-Emmanuel Dufils
IPC分类号： B01J27/24 , C08F2/32 , C08F118/02 , C07F9/40
CPC分类号： C08F4/00 , C07F9/4006
摘要： A subject-matter of the invention is alkoxyamines resulting from β-phosphorated nitroxides corresponding to the formula: in which R represents an alkyl radical having a number of carbon atoms ranging from 1 to 3, R1 represents a hydrogen atom or a residue: in which R3 represents an alkyl radical having a number of carbon atoms ranging from 1 to 20, and R2 represents a hydrogen atom, an alkyl radical having a number of carbon atoms ranging from 1 to 8, a phenyl radical, an alkali metal, such as Li, Na or K, H4N+, Bu4N+ or Bu3HN+, exhibiting a kinetic dissociation constant kd, measured at 120° C. by EPR, of greater than 0.05 s−1. These compounds can be used as initiators for the (co)polymerizations of at least one monomer which can be polymerized by the radical route.
摘要翻译： 本发明的主题是由对应于下式的＆bgr-磷酸化的氮氧化物得到的烷氧基胺：其中R表示碳原子数1至3的烷基，R 1表示氢原子或残基：在 其中R3表示碳原子数为1〜20的烷基，R2表示氢原子，碳原子数为1〜8的烷基，苯基，碱金属等 Li，Na或K，H4N +，Bu4N +或Bu3HN +，其在120℃下通过EPR测量的动力学解离常数kd大于0.05s -1。 这些化合物可以用作可以通过基团路线聚合的至少一种单体的（共）聚合的引发剂。
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3.发明授权Alkoxyamines derived from beta-phosphorylated nitroxides, and use thereof for preparing polymerized or non-polymerized mono- or polyalkoxyamines 失效衍生自β-磷酸化的氮氧化物的烷氧基胺及其用于制备聚合或未聚合的单烷氧基或聚烷氧基胺的用途公开(公告)号：US07214810B2
公开(公告)日：2007-05-08
申请号：US10813822
申请日：2004-03-31
申请人： Jean-luc Couturier , Olivier Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo , Pierre-emmanuel Dufils
发明人： Jean-luc Couturier , Olivier Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo , Pierre-emmanuel Dufils
IPC分类号： C07F9/02
CPC分类号： C08F4/00 , C07F9/4006
摘要： The invention relates to the use of alkoxyamines of formula (I): for the preparation of polymerized or non-polymerized mono- or polyalkoxyamines of formula (II):
摘要翻译： 本发明涉及式（I）的烷氧基胺的用途：用于制备式（II）的聚合或未聚合的单烷氧基或聚烷氧基胺：
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4.发明申请ALKOXYAMINES DERIVED FROM BETA-PHOSPHORYLATED NITROXIDES, AND USE THEREOF FOR PREPARING POLYMERIZED OR NON-POLYMERIZED MONO- OR POLYALKOXYAMINES 审中-公开衍生自磷酸氢二钠的烷氧基胺，以及其制备聚合或非聚合的单羟基烷氧基胺的用途公开(公告)号：US20070167591A1
公开(公告)日：2007-07-19
申请号：US11692377
申请日：2007-03-28
申请人： Jean-Luc Couturier , Olivier Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo , Pierre-Emmanuel Dufils
发明人： Jean-Luc Couturier , Olivier Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo , Pierre-Emmanuel Dufils
IPC分类号： C08F230/02 , C07F9/02
CPC分类号： C08F4/00 , C07F9/4006
摘要： The invention relates to the use of alkoxyamines of formula (I): for the preparation of polymerized or non-polymerized mono- or polyalkoxyamines of formula (II):
摘要翻译： 本发明涉及式（I）的烷氧基胺的用途：用于制备式（II）的聚合或未聚合的单烷氧基或聚烷氧基胺：
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5.发明申请Method for Controlled Free Radical Polymerization or Copolymerization of Methacrylic and/or Methacrylate Monomers or Exclusively Methacrylic and/or Methacrylate Copolymers 审中-公开甲基丙烯酸和/或甲基丙烯酸酯单体或独家甲基丙烯酸和/或甲基丙烯酸酯共聚物的受控自由基聚合或共聚的方法公开(公告)号：US20080274074A1
公开(公告)日：2008-11-06
申请号：US12094696
申请日：2006-11-24
CPC分类号： C08F2/38 , C08F4/00 , C08F220/18
摘要： The invention relates to a method for the polymerization of one or more methacrylate and/or methacrylic monomers, for the synthesis of methacrylate or methacrylic polymers or of exclusively methacrylic and/or methacrylate copolymers, comprising a step of bringing said monomer(s) into contact with one at least of the compounds of formula (I) and (II) below: in which: R1 and R2 may represent a phenyl group, R3 and R4 may together form an ═N-phenyl group, Z represents a group of formula —CR8R9R10, in which R8 and R9 may represent methyl groups and R10 may represent a —COO-phenyl group.
摘要翻译： 本发明涉及聚合一种或多种甲基丙烯酸酯和/或甲基丙烯酸单体，用于合成甲基丙烯酸酯或甲基丙烯酸酯或甲基丙烯酸和/或甲基丙烯酸酯共聚物的方法，包括使所述单体接触的步骤 至少一种式（I）和（II）的化合物：其中：R 1和R 2可以表示苯基，R 1， 3和R 4可以一起形成-N-苯基，Z代表式-CR 8 R 9的基团， R 10，其中R 8和R 9可以表示甲基，R 10可以表示-COO 苯基。
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6.发明申请Alkoxyamines derived from beta-phosphorylated nitroxides, and use thereof for preparing polymerized or non-polymerized mono-or polyalkoxyamines 失效衍生自β-磷酸化氮氧化物的烷氧基胺及其用于制备聚合或未聚合的单或多烷氧基胺的用途公开(公告)号：US20050065119A1
公开(公告)日：2005-03-24
申请号：US10813822
申请日：2004-03-31
申请人： Jean-luc Couturier , Oliver Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo , Pierre-Emmanuel Dufils
发明人： Jean-luc Couturier , Oliver Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo , Pierre-Emmanuel Dufils
CPC分类号： C08F4/00 , C07F9/4006
摘要： The invention relates to the use of alkoxyamines of formula (I): for the preparation of polymerized or non-polymerized mono- or polyalkoxyamines of formula (II):
摘要翻译： 本发明涉及式（I）的烷氧基胺的用途：用于制备式（II）的聚合或未聚合的单烷氧基或聚烷氧基胺：
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7.发明申请Alkoxyamines originating from $g(b)-phoshorylated nitroxides and use thereof in radical polymerisation 有权源自$ g（b） - 羟基化的氮氧化物的烷氧基胺及其在自由基聚合中的用途公开(公告)号：US20060142511A1
公开(公告)日：2006-06-29
申请号：US10523481
申请日：2003-07-23
申请人： Jean Couturier , Oliver Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo
发明人： Jean Couturier , Oliver Guerret , Denis Bertin , Didier Gigmes , Sylvain Marque , Paul Tordo
IPC分类号： C08F2/00
CPC分类号： C08F4/00 , C07F9/4006
摘要： A subject-matter of the invention is alkoxyamines resulting from β-phosphorated nitroxides corresponding to the formula: These compounds can be used as initiators for the (co)polymerizations of at least one monomer which can be polymerized by the radical route.
摘要翻译： 本发明的主题是由对应于下式的β-磷酸化氮氧化物得到的烷氧基胺：这些化合物可以用作至少一种可以通过自由基途径聚合的单体的（共）聚合的引发剂。
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8.发明授权Block copolymer including a polyanion based on a TFSILi anion monomer as a battery electrolyte 有权嵌段共聚物，包括基于作为电池电解质的TFSILi阴离子单体的聚阴离子公开(公告)号：US09431677B2
公开(公告)日：2016-08-30
申请号：US14239905
申请日：2012-09-05
申请人： Renaud Bouchet , Abdelmaula Aboulaich , Sebastien Maria , Trang Phan , Didier Gigmes , Denis Bertin , Rachid Meziane , Jean-Pierre Bonnet , Michel Armand
发明人： Renaud Bouchet , Abdelmaula Aboulaich , Sebastien Maria , Trang Phan , Didier Gigmes , Denis Bertin , Rachid Meziane , Jean-Pierre Bonnet , Michel Armand
IPC分类号： C08F293/00 , H01M10/0565 , C08J5/22 , H01M4/38 , H01M4/58 , H01M10/052 , H01M10/0562
CPC分类号： H01M10/0565 , C08F293/005 , C08F2438/02 , C08J5/2243 , C08J2353/02 , C08J2387/00 , H01M4/382 , H01M4/5825 , H01M10/052 , H01M10/0562 , H01M2300/0082 , Y02E60/122
摘要： The invention relates to a BA diblock or BAB triblock copolymer, in which the A block is a non-substituted poly-oxyethylene chain having a mean molecular weight that is no higher than 100 kDa, and the B block is an anionic polymer which can be prepared using one or more monomers selected from among the vinyl monomers and derivatives thereof, said monomers being substituted with a (trifluoromethylsulfonyl)imide (TFSI) anion. The invention also relates to the uses of such a copolymer, in particular for preparing an electrolyte composition for lithium metal polymer (LMP) batteries.
摘要翻译： 本发明涉及BA二嵌段或BAB三嵌段共聚物，其中A嵌段是平均分子量不高于100kDa的未取代的聚氧乙烯链，B嵌段是可以是 使用一种或多种选自乙烯基单体及其衍生物的单体制备，所述单体被（三氟甲基磺酰基）酰亚胺（TFSI）阴离子取代。 本发明还涉及这种共聚物的用途，特别是制备用于锂金属聚合物（LMP）电池的电解质组合物。
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9.发明授权公开(公告)号：US08735475B2
公开(公告)日：2014-05-27
申请号：US13492149
申请日：2012-06-08
申请人： Armin Pfeil , Johannes Brinkhorst , Didier Gigmes , Luca Valgimigli , Derek Pratt , Denis Bertin
发明人： Armin Pfeil , Johannes Brinkhorst , Didier Gigmes , Luca Valgimigli , Derek Pratt , Denis Bertin
IPC分类号： C08K5/34
CPC分类号： C04B24/02 , B65D25/00 , C04B24/128 , C04B26/02 , C04B28/06 , C04B40/0039 , C04B40/065 , C04B40/0658 , C04B2111/00715 , C08L33/10 , C04B14/06 , C04B14/066 , C04B20/0076 , C04B22/068 , C04B24/2641
摘要： The use of a mixture of 5-pyrimidinol derivatives with sterically hindered phenol derivatives for adjusting the reactivity and the gel time of resin mixtures and reactive resin mortars based on radically polymerizable compounds is described. Furthermore, a resin mixture containing the inhibitor combination, a reactive resin mortar containing this resin mixture and two-component mortar systems with the reactive resin mortar according to the invention and a hardener with improved stability in storage and good low-temperature hardening properties are also described. The resin mixture according to the invention is suitable in particular for chemical fastening of construction elements in boreholes in various substrates.
摘要翻译： 描述了使用5-嘧啶醇衍生物与空间位阻酚衍生物的混合物来调节基于自由基聚合性化合物的树脂混合物和反应性树脂砂浆的反应性和凝胶时间。 此外，含有抑制剂组合的树脂混合物，含有该树脂混合物的反应性树脂砂浆和根据本发明的反应性树脂砂浆的双组分砂浆体系以及具有改进的储存稳定性和良好的低温硬化性能的固化剂也是 描述。 根据本发明的树脂混合物特别适用于将结构元件化学固定在各种基底中的钻孔中。
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10.发明授权公开(公告)号：US08013062B2
公开(公告)日：2011-09-06
申请号：US10502216
申请日：2003-01-21
申请人： Anne-Valerie Ruzette , Florence Chauvin , Olivier Guerret , Denis Bertin , Bruno Vuillemin , Ludwik Leibler , Pierre Gerard , Yannick Ederle
发明人： Anne-Valerie Ruzette , Florence Chauvin , Olivier Guerret , Denis Bertin , Bruno Vuillemin , Ludwik Leibler , Pierre Gerard , Yannick Ederle
CPC分类号： C08L53/00 , C08F293/00 , C08L101/00 , C08L2666/24
摘要： The invention relates to the production and use of block copolymers which are obtained by means of controlled radical polymerization in the presence of nitroxides for the purpose of reinforcing fragile polymer matrices. The invention offers advantages such as (i) simplicity of copolymer synthesis and use and (ii) fine dispersion of the copolymer molecules in the fragile matrix, which ensures both the transparency of the material and high reinforcement against impact. More specifically, the invention relates to the radical synthesis of block copolymers comprising at least three blocks, which include one block having a glass transition temperature of less than 0° C. and a thermoplastic end block having a glass transition temperature of more than 0° C., thereby guaranteeing compatibility with the fragile matrix to be reinforced against impact.
摘要翻译： 本发明涉及通过在氮氧化物存在下通过可控自由基聚合获得的嵌段共聚物的生产和用途，用于增强易碎聚合物基质。 本发明提供了以下优点，例如（i）共聚物合成和使用的简单性和（ii）共聚物分子在易碎基体中的细分散，其确保材料的透明性和高抗冲击性。 更具体地，本发明涉及包含至少三个嵌段的嵌段共聚物的自由基合成，其包括玻璃化转变温度低于0℃的一个嵌段和玻璃化转变温度大于0℃的热塑性端嵌段 C.从而保证与脆弱基质的相容性得到加强抵抗冲击。
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