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公开(公告)号:US08652988B2
公开(公告)日:2014-02-18
申请号:US13095419
申请日:2011-04-27
申请人: Dick Nagaki , Heiko Weiner , Josefina T. Chapman , Mark O. Scates , Alexandra S. Locke , Craig J. Peterson
发明人: Dick Nagaki , Heiko Weiner , Josefina T. Chapman , Mark O. Scates , Alexandra S. Locke , Craig J. Peterson
IPC分类号: B01J27/198 , B01J23/00
CPC分类号: C07C51/347 , B01J23/22 , B01J27/198 , B01J35/1004 , B01J35/1033 , B01J35/1061 , B01J35/1066 , B01J37/0201 , B01J37/08 , B01J2523/00 , C07C51/353 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition, comprising vanadium and titanium. Preferably, the molar ratio of vanadium to titanium in an active phase of the catalyst composition is greater than 0.5:1.
摘要翻译: 在一个实施方案中,本发明涉及包含钒和钛的催化剂组合物。 优选地,催化剂组合物的活性相中的钒与钛的摩尔比大于0.5:1。
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公开(公告)号:US20130053599A1
公开(公告)日:2013-02-28
申请号:US13214325
申请日:2011-08-22
申请人: Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke , Dick Nagaki , Craig J. Peterson , Mark O. Scates
发明人: Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke , Dick Nagaki , Craig J. Peterson , Mark O. Scates
IPC分类号: B01J27/14 , C07C67/30 , B01J29/04 , C07C51/347 , B01J27/198 , B01J27/182
CPC分类号: B01J27/198 , B01J27/14 , B01J27/18 , B01J35/1004 , B01J35/1038 , B01J35/1061 , B01J37/03 , B01J37/08 , B01J2523/00 , C07C51/21 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition comprising titanium, phosphorus, and less than 1 wt. % vanadium. The catalyst composition has a molar ratio of phosphorus to titanium of at least 1.0:1.0.
摘要翻译: 在一个实施方案中,本发明涉及包含钛,磷和小于1wt。 %钒。 催化剂组合物的磷与钛的摩尔比至少为1.0:1.0。
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公开(公告)号:US20120289743A1
公开(公告)日:2012-11-15
申请号:US13105558
申请日:2011-05-11
申请人: Dick Nagaki , Heiko Weiner , Josefina T. Chapman , Mark O. Scates , Alexandra S. Locke , Craig J. Peterson
发明人: Dick Nagaki , Heiko Weiner , Josefina T. Chapman , Mark O. Scates , Alexandra S. Locke , Craig J. Peterson
IPC分类号: B01J27/198 , B01J21/08 , C07C51/377 , B01J21/06
CPC分类号: B01J23/22 , B01J27/198 , B01J35/1004 , B01J35/1033 , B01J35/1061 , B01J35/1066 , B01J37/0201 , B01J37/08 , B01J2523/00 , C07C51/353 , C07C51/377 , B01J2523/47 , B01J2523/51 , B01J2523/55 , B01J2523/41 , B01J2523/31 , B01J2523/48 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition comprising vanadium, titanium; and at least one oxide additive. The at least one oxide additive is present in an amount of at least 0.1 wt % based on the total weight of the catalyst composition. The molar ratio of titanium to metal additive in an active phase of the catalyst composition is at least 0.05:1.
摘要翻译: 在一个实施方案中,本发明涉及一种催化剂组合物,其包含钒,钛; 和至少一种氧化物添加剂。 基于催化剂组合物的总重量,至少一种氧化物添加剂的存在量为至少0.1重量%。 在催化剂组合物的活性相中钛与金属添加剂的摩尔比为至少0.05:1。
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公开(公告)号:US08642498B2
公开(公告)日:2014-02-04
申请号:US13105558
申请日:2011-05-11
申请人: Dick Nagaki , Heiko Weiner , Josefina T. Chapman , Mark O. Scates , Alexandra S. Locke , Craig J. Peterson
发明人: Dick Nagaki , Heiko Weiner , Josefina T. Chapman , Mark O. Scates , Alexandra S. Locke , Craig J. Peterson
IPC分类号: B01J27/198 , B01J23/00
CPC分类号: B01J23/22 , B01J27/198 , B01J35/1004 , B01J35/1033 , B01J35/1061 , B01J35/1066 , B01J37/0201 , B01J37/08 , B01J2523/00 , C07C51/353 , C07C51/377 , B01J2523/47 , B01J2523/51 , B01J2523/55 , B01J2523/41 , B01J2523/31 , B01J2523/48 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition comprising vanadium, titanium; and at least one oxide additive. The at least one oxide additive is present in an amount of at least 0.1 wt % based on the total weight of the catalyst composition. The molar ratio of titanium to metal additive in an active phase of the catalyst composition is at least 0.05:1.
摘要翻译: 在一个实施方案中,本发明涉及一种催化剂组合物,其包含钒,钛; 和至少一种氧化物添加剂。 基于催化剂组合物的总重量,至少一种氧化物添加剂的存在量为至少0.1重量%。 在催化剂组合物的活性相中钛与金属添加剂的摩尔比为至少0.05:1。
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公开(公告)号:US20130079553A1
公开(公告)日:2013-03-28
申请号:US13240357
申请日:2011-09-22
申请人: Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke , Craig J. Peterson , Mark O. Scates , Dick Nagaki
发明人: Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke , Craig J. Peterson , Mark O. Scates , Dick Nagaki
IPC分类号: C07C51/347 , B01J31/38 , B01J37/08 , B01J27/198 , B01J21/08 , B01J29/04 , B01J21/06 , B01J21/16
CPC分类号: B01J23/22 , B01J27/198 , B01J35/1014 , B01J35/1061 , B01J37/031 , B01J37/08 , B01J2523/00 , C07C51/353 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition comprising vanadium and titanium. The catalyst composition has a surface area of at least 22.6 m2/g and a plurality of pores, and the plurality of pores have a pore diameter of less than 11.9 nm.
摘要翻译: 在一个实施方案中,本发明涉及包含钒和钛的催化剂组合物。 该催化剂组合物具有至少22.6m 2 / g的表面积和多个孔,多个孔的孔径小于11.9nm。
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公开(公告)号:US20120277466A1
公开(公告)日:2012-11-01
申请号:US13095419
申请日:2011-04-27
申请人: Dick Nagaki , Heiko Weiner , Josefina T. Chapman , Mark O. Scates , Alexandra S. Locke , Craig J. Peterson
发明人: Dick Nagaki , Heiko Weiner , Josefina T. Chapman , Mark O. Scates , Alexandra S. Locke , Craig J. Peterson
IPC分类号: B01J27/198 , B01J21/08 , C07C51/347 , B01J21/06 , B01J29/04 , B01J35/00 , B01J21/04
CPC分类号: C07C51/347 , B01J23/22 , B01J27/198 , B01J35/1004 , B01J35/1033 , B01J35/1061 , B01J35/1066 , B01J37/0201 , B01J37/08 , B01J2523/00 , C07C51/353 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition, comprising vanadium and titanium. Preferably, the molar ratio of vanadium to titanium in an active phase of the catalyst composition is greater than 0.5:1.
摘要翻译: 在一个实施方案中,本发明涉及包含钒和钛的催化剂组合物。 优选地,催化剂组合物的活性相中的钒与钛的摩尔比大于0.5:1。
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公开(公告)号:US08802585B2
公开(公告)日:2014-08-12
申请号:US13240357
申请日:2011-09-22
申请人: Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke , Craig T. Peterson , Mark O. Scates , Dick Nagaki
发明人: Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke , Craig T. Peterson , Mark O. Scates , Dick Nagaki
CPC分类号: B01J23/22 , B01J27/198 , B01J35/1014 , B01J35/1061 , B01J37/031 , B01J37/08 , B01J2523/00 , C07C51/353 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition comprising vanadium and titanium. The catalyst composition has a surface area of at least 22.6 m2/g and a plurality of pores, and the plurality of pores have a pore diameter of less than 11.9 nm.
摘要翻译: 在一个实施方案中,本发明涉及包含钒和钛的催化剂组合物。 该催化剂组合物具有至少22.6m 2 / g的表面积和多个孔,多个孔的孔径小于11.9nm。
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公开(公告)号:US08735314B2
公开(公告)日:2014-05-27
申请号:US13248710
申请日:2011-09-29
申请人: Dick Nagaki , Craig Peterson , Mark Scates , Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke
发明人: Dick Nagaki , Craig Peterson , Mark Scates , Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke
CPC分类号: B01J35/1061 , B01J23/22 , B01J27/198 , B01J35/1014 , B01J37/03 , B01J37/031 , B01J37/08 , B01J2523/00 , C07C51/353 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition comprising vanadium and titanium. The catalyst composition further comprises ethylene glycol and citric acid. Preferably, the catalyst composition is substantially free of oxalic acid and lactic acid.
摘要翻译: 在一个实施方案中,本发明涉及包含钒和钛的催化剂组合物。 催化剂组合物还包含乙二醇和柠檬酸。 优选地,催化剂组合物基本上不含草酸和乳酸。
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公开(公告)号:US20130085293A1
公开(公告)日:2013-04-04
申请号:US13248710
申请日:2011-09-29
申请人: Dick Nagaki , Craig Peterson , Mark Scates , Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke
发明人: Dick Nagaki , Craig Peterson , Mark Scates , Heiko Weiner , Josefina T. Chapman , Alexandra S. Locke
CPC分类号: B01J35/1061 , B01J23/22 , B01J27/198 , B01J35/1014 , B01J37/03 , B01J37/031 , B01J37/08 , B01J2523/00 , C07C51/353 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
摘要: In one embodiment, the invention is to a catalyst composition comprising vanadium and titanium. The catalyst composition further comprises ethylene glycol and citric acid. Preferably, the catalyst composition is substantially free of oxalic acid and lactic acid.
摘要翻译: 在一个实施方案中,本发明涉及包含钒和钛的催化剂组合物。 催化剂组合物还包含乙二醇和柠檬酸。 优选地,催化剂组合物基本上不含草酸和乳酸。
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公开(公告)号:US20130158295A1
公开(公告)日:2013-06-20
申请号:US13328231
申请日:2011-12-16
申请人: Ilias S. Kotsianis , Sean Mueller , Dick Nagaki , Tianshu Pan , Craig J. Peterson , Josefina T. Chapman
发明人: Ilias S. Kotsianis , Sean Mueller , Dick Nagaki , Tianshu Pan , Craig J. Peterson , Josefina T. Chapman
IPC分类号: C07C51/00
摘要: In one embodiment, the invention is to a process for producing an acrylate product. The process comprises the step of dehydrating a crude alkylenating agent stream to form a dehydrated alkylenating agent stream and a water stream. The process further comprises reacting acetic acid with at least a portion of the dehydrated alkylenating agent stream to form a crude acrylate product stream comprising acrylate product and alkylenating agent stream. The dehydrating of the crude alkylenating stream is accomplished using at least one evaporator or at least one distillation column.
摘要翻译: 在一个实施方案中,本发明涉及一种生产丙烯酸酯产物的方法。 该方法包括使粗亚烷基化剂流脱水以形成脱水亚烷基化剂流和水流的步骤。 该方法还包括使乙酸与脱水亚烷基化剂物流的至少一部分反应以形成包含丙烯酸酯产物和亚烷基化剂物流的粗丙烯酸酯产物流。 使用至少一个蒸发器或至少一个蒸馏塔来实现粗烷基化流的脱水。
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