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公开(公告)号：US06362347B1
公开(公告)日：2002-03-26
申请号：US09508619
申请日：2000-03-14
申请人： Dieter Baumann , Hermann Pütter , Heinz Hannebaum
发明人： Dieter Baumann , Hermann Pütter , Heinz Hannebaum
IPC分类号： C07D30788
CPC分类号： C07D307/88 , C25B3/04
摘要： Phthalides in as-obtained phthalide synthesis reaction mixtures are recovered in pure form by (a) distilling compounds having a boiling point below the boiling point of the phthalide from the reaction mixture, provided such compounds are present in the reaction mixture, to obtain a crude phthalide as bottom product, (b) crystallizing the phthalide from a melt of the crude phthalide.
摘要翻译： 通过（a）从反应混合物中蒸出沸点低于苯并呋喃沸点的化合物，反应混合物中存在这样的化合物，得到粗产物，得到粗产物 苯酞作为底部产物，（b）从粗苯二酸酯的熔体中结晶苯酞。
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公开(公告)号：US06315884B1
公开(公告)日：2001-11-13
申请号：US09508114
申请日：2000-03-20
申请人： Hermann Pütter , Dieter Baumann , Heinz Hannebaum
发明人： Hermann Pütter , Dieter Baumann , Heinz Hannebaum
IPC分类号： C25B300
CPC分类号： C07D307/88 , C25B3/04
摘要： A process for preparing phthalides by I. reducing phthalic acid or phthalic acid derivatives, where the carboxyl groups may be replaced by units which can be derived from the carboxyl groups by a condensation reaction and where one or more of the hydrogens of the o-phenylene unit may be substituted by inert radicals, at a cathode in a undivided electrolytic cell and dissolved in an electrolyte, II. discharging the electrolyte from the electrolytic cell when the reaction has proceeded to the stage where the molar ratio (M), formed by the proportion of phthalide and the sum of the proportions of phthalide and phthalic acid of phthalic acid derivatives in the electrolyte, is from 0.8:1 to 0.995:1, and III. crystallizing the phthalides from the electrolyte and removing them from the mother liquor, if appropriate after distillative work-up of the electrolyte is described.
摘要翻译： 一种通过I制备酞嗪的方法。 还原邻苯二甲酸或邻苯二甲酸衍生物，其中羧基可以被可以通过缩合反应衍生自羧基的单元代替，并且其中一个或多个邻 - 亚苯基单元的氢可以被惰性基团取代， 在未分解的电解槽中的阴极处溶解在电解质中。 当反应进行到其中由苯酞的比例形成的摩尔比（M）与电解质中邻苯二甲酸衍生物的苯酞和邻苯二甲酸的比例之和的比例为 0.8：1至0.995：1，和III。 在电解液的蒸馏处理之后，如果适当，则将来自电解质的酞菁结晶并将其从母液中除去。
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3.发明授权公开(公告)号：US06245945B1
公开(公告)日：2001-06-12
申请号：US09623059
申请日：2000-08-25
IPC分类号： C07C4542
CPC分类号： C07C45/515 , C07C45/59 , C07D307/88
摘要： A process for the selective hydrolysis of acetals in the presence of phthalides comprises reacting a mixture (M) comprising a) a phthalide of the formula (I) where: R1,R2,R3 and R4: are independently hydrogen, C1-C4-alkyl or halogen, and b) an acetal or ketal of the formula (II) where: R5 and R6: are independently C1-C6-alkyl, C6-C10-aryl or together ethylene, and R7 and R8: are independently C1-C6-alkyl, or one radical is a hydrogen and the other is a phenyl radical where from 1 to 3 hydrogen atoms of the phenyl radical may be replaced by C1-C6-alkyl radicals or C1-C4-alkoxy radicals, or R7 and R8 are together C3-C6-alkanediyl, and a hydrogen atom may be replaced by a hydroxyl group, at from 10 to 200° C. in the presence of from 1 to 10 mol of water, based on the amount of acetal or ketal of the formula (II), to hydrolyze the acetal or ketal of the formula (II) to the corresponding aldehyde or ketone.
摘要翻译： 在含有苯并呋喃存在下选择性水解缩醛的方法包括使包含a）式（I）的苯酞的混合物（M）反应，其中：R1，R2，R3和R4独立地是氢，C1-C4-烷基或 卤素和b）式（II）的缩醛或缩酮，其中：R 5和R 6独立地为C 1 -C 6烷基，C 6 -C 10 - 芳基或一起为乙烯，R 7和R 8独立地为C 1 -C 6烷基，或 一个基团是氢，另一个是苯基，其中苯基的1至3个氢原子可以被C 1 -C 6 - 烷基或C 1 -C 4 - 烷氧基取代，或者R 7和R 8一起是C 3 -C 6 （II）的缩醛或缩酮的量，可以在10〜200℃的存在下，在1〜10摩尔的水的存在下，用羟基代替氢原子， 以将式（II）的缩醛或缩酮水解成相应的醛或酮。
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公开(公告)号：US06822124B2
公开(公告)日：2004-11-23
申请号：US10432249
申请日：2003-05-22
申请人： Hermann Pütter , Andreas Fischer
发明人： Hermann Pütter , Andreas Fischer
IPC分类号： C07C4702
CPC分类号： C25B3/00
摘要： A method for producing alcoxylated carbonyl compounds of general formula (I) (compounds I): R1aR2C(OR3)b wherein R1, R2 represent hydrogen or C1-C6-alkyl, R3 independently means C1-C6-alkyl, a is 0 or 1, b 2 or 3 with the proviso that the sum of a and b is 3, by means of anodic oxidation of germinal dialcoxy compounds of general formula (II) (compounds II) wherein R4, R5, R6, R7 represent hydrogen or C1-C6-alkyl, R5, R6 represent C1-C6-alkyl or C1-C6-alcoxy, in the presence of a C1-C6-alkyl alcohol (compounds III). A usual compound (compound IV) is used as a cathodic depolarizer suitable for electrochemical oxidation. The anodic oxidation and cathodic reduction is carried out in an undivided electrolyte cell in the presence of C1-C6-alkyl alcohols.
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公开(公告)号：US06713656B2
公开(公告)日：2004-03-30
申请号：US10262980
申请日：2002-10-03
IPC分类号： C07C4330
CPC分类号： C07C41/56 , C07C43/303 , C07C47/198
摘要： A process is described for preparing diacetals of glyoxal by reacting from 40 to 75% by weight aqueous glyoxal with monohydric alcohols in the presence of an acid catalyst, which comprises leaving a liquid mixture which, at the beginning of the reaction, comprises alcohol and glyoxal in a molar ratio of at least 15:1 and also water in a concentration of not more than 8% by weight in contact with the acid catalyst until concentration in the reaction mixture of the diacetal formed reaches at least 70% of the equilibrium concentration without more than 5% by weight of the alcohol used having already been distilled off.
摘要翻译： 描述了一种通过在酸催化剂的存在下使40至75重量％的乙二醛与一元醇反应来制备乙二醛的二缩醛的方法，其包括在反应开始时包含醇和乙二醛的液体混合物 至少15:1的摩尔比和与酸催化剂接触的浓度不超过8重量％的水，直到形成的二缩醛的反应混合物中的浓度达到平衡浓度的至少70％而没有 超过5％（重量）所用的醇已被蒸馏掉。
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公开(公告)号：US20090171107A1
公开(公告)日：2009-07-02
申请号：US12300902
申请日：2007-05-11
IPC分类号： C07F1/08
CPC分类号： C25B3/12
摘要： The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
摘要翻译： 本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种金属离子配位的至少两种有机化合物，其包括以下步骤：（a）至少一个阳极的氧化，所述至少一个阳极包含对应于至少一种金属 在至少一种第一有机化合物存在下的反应介质中，所述第一有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳已经被选自N，O 和S形成包含所述至少一种金属离子和所述第一有机化合物的反应中间体; 和（b）将反应中间体在规定温度下与至少一种与至少一种金属离子配位的第二有机化合物反应，第二有机化合物衍生自二羧酸，三羧酸或四羧酸。
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公开(公告)号：US06409908B1
公开(公告)日：2002-06-25
申请号：US09459726
申请日：1999-12-13
申请人： Günther Huber , Hermann Pütter , Kerstin Schierle-Arndt , Dieter Schläfer , Josef Guth , Bernd Schube , Diethard Lenz
发明人： Günther Huber , Hermann Pütter , Kerstin Schierle-Arndt , Dieter Schläfer , Josef Guth , Bernd Schube , Diethard Lenz
IPC分类号： C25B100
CPC分类号： C25C3/02
摘要： In a process for producing an alkali metal from alkali metal amalgam by electrolysis using an alkali metal amalgam as anode, a solid electrolyte which conducts alkali metal ions and a liquid alkali metal as cathode, the alkali metal amalgam as anode is kept in motion.
摘要翻译： 在碱金属汞齐作为阳极通过电解制造碱金属的方法中，将碱金属离子和液态碱金属作为阴极进行电解的固体电解质，作为阳极的碱金属汞齐保持运动。
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公开(公告)号：US06287448B1
公开(公告)日：2001-09-11
申请号：US09531471
申请日：2000-03-20
IPC分类号： C25C100
摘要： A process for producing metallic lithium starting from an aqueous solution of at least one lithium salt comprises the following steps: (I) Production of a lithium amalgam from an aqueous solution of at least one lithium salt; and (II) Electrolysis using an anode comprising the lithium amalgam, a solid electrolyte which conducts lithium ions, and liquid lithium as cathode, wherein the lithium amalgam as anode is kept in motion.
摘要翻译： 从至少一种锂盐的水溶液开始制造金属锂的方法包括以下步骤：（I）从至少一种锂盐的水溶液制备锂汞齐; 和（II）使用包含锂汞齐的阳极，导电锂离子的固体电解质和液体锂作为阴极的电解，其中作为阳极的锂汞齐保持运动。
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公开(公告)号：US07879221B2
公开(公告)日：2011-02-01
申请号：US12300902
申请日：2007-05-11
CPC分类号： C25B3/12
摘要： The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
摘要翻译： 本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种金属离子配位的至少两种有机化合物，其包括以下步骤：（a）至少一个阳极的氧化，所述至少一个阳极包含对应于至少一种金属 在至少一种第一有机化合物存在下的反应介质中，所述第一有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳已经被选自N，O 和S形成包含所述至少一种金属离子和所述第一有机化合物的反应中间体; 和（b）将反应中间体在规定温度下与至少一种与至少一种金属离子配位的第二有机化合物反应，第二有机化合物衍生自二羧酸，三羧酸或四羧酸。
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10.发明授权公开(公告)号：US06909016B2
公开(公告)日：2005-06-21
申请号：US10432253
申请日：2001-11-16
IPC分类号： C07C51/353 , C07D307/32 , C25B3/00 , C25B3/02 , C25B3/04 , C07C55/00
CPC分类号： C07D307/32 , C07C51/353 , C25B3/00 , C25B3/04 , C07C55/24
摘要： A process for preparing butanetetracarboxylic acid derivatives as product of value I by coupled electrosynthesis which comprises cathodically reducing a compound selected from the group consisting of maleic esters, maleic ester derivatives, fumaric esters and fumaric ester derivatives where at least one hydrogen atom in positions 2 and 3 may be replaced by inert groups and obtaining a product of value II at the node.
摘要翻译： 通过偶联电合成制备丁酸四羧酸衍生物作为值I的产物的方法，其包括阴极还原选自马来酸酯，马来酸酯衍生物，富马酸酯和富马酸酯衍生物的化合物，其中位置2和 3可以由惰性基团代替，并在节点处获得值II的乘积。
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