摘要:
Polycarbonates are provided based on aromatic bis-hydroxy compounds which contain s-triazine compounds as linking members between 2 mols of the aromatic bis-hydroxy compounds bonded in each case via an oxygen atom thereof, on the one hand, and via carbon atoms of the s-triazine ring, on the other, the s-triazine rings carrying, on at least one further carbon atom, organic radicals with functional groups, these radicals being bonded via oxygen, nitrogen or sulphur. The novel polycarbonates may be used as selective solvents for hydrocarbons mixed with water or for making resins or coatings.
摘要:
Polycarbonates are provided based on aromatic bis-hydroxy compounds which contain s-triazine compounds as linking members between 2 mols of the aromatic bis-hydroxy compounds bonded in each case via an oxygen atom thereof, on the one hand, and via carbon atoms of the s-triazine ring, on the other, the s-triazine rings carrying, on at least one further carbon atom, organic radicals with functional groups, these radicals being bonded via oxygen, nitrogen or sulphur. The novel polycarbonates may be used as selective solvents for hydrocarbons mixed with water or for making resins or coatings.
摘要:
The subject disclosure is concerned with a process for synthesizing soluble thermoplastic graft polymers of polycarbonate and ethylenically unsaturated monomers by polymerizing these monomers and aromatic polycarbonates carrying addition polymerizable end groups in a dilute solution of no more than 30 wt. % of reactants based on the weight of solution. The graft polymers so obtained are also encompassed by the inventive concept.
摘要:
The present invention is concerned with a process for the production of high molecular weight thermoplastic ppolycarbonates having improved flame resistance and in conjunction with glass fibres, improved mechanical properties and the polycarbonates so produced. A solution polycarbonate is reacted with an alkali metal salt soluble in the melt of the polycarbonate until the Staudinger Index has increased by about 3 to 30 cm.sup.3 /g. This usually requires about 0.0001 to 0.1 wt. % of the salt, based on the weight of polycarbonate and a temperature of about 250.degree. to 400.degree. C for between about 1 and 30 minutes. In a preferred embodiment the reaction is conducted in a self-cleaning twin screw extruder.
摘要:
Thermoplastic moulding compositions ofA. 15 to 80 % by weight of an aromatic polycondensate containing s-triazine rings, andB. 20 to 85 % by weight of a graft polymer obtained by polymerizing a mixture ofB.1. 50 to 90 % by weight of styrene, .alpha.-methyl styrene, methyl methacrylate or mixtures thereof andB.2. 10 to 50 % by weight of acrylonitrile, methacrylonitrile, methyl methacrylate or mixtures thereof,Onto a diene or acrylate rubber, the mixture as a whole containing from 5 to 25 % by weight of s-triazine rings, based on (A) and (B), and 5 to 40% by weight of rubber, based on (A) and (B).
摘要:
The present invention relates to polycondensates of the formula 10, their use for absorbing metal ions of the transition elements of the periodic system and their use for the preparation of polymers containing metals of formula 11 which have e.g. improved resistance to heat and to chemicals compared to the corresponding polycondensates of formula 10.
摘要:
Homopolymers and copolymers based on alkenoyloxybenzylidene-malonic esters of the formula ##SPC1##WhereR.sup.1 is hydrogen or C.sub.1 to C.sub.4 -alkyl;R.sup.2 is C.sub.1 to C.sub.12 -alkyl or cycloalkyl andR.sup.3 is hydrogen, C.sub.1 to C.sub.8 -alkyl, C.sub.1 to C.sub.8 -alkoxy or halogen, and plastics, i.e., polycarbonates, stabilized therewith.
摘要:
The present invention relates to polycondensates of the formula 10, their use for absorbing metal ions of the transition elements of the periodic system and their use for the preparation of polymers containing metals of formula 11 which have e.g. improved resistance to heat and to chemicals compared to the corresponding polycondensates of formula 10.
摘要:
The present invention relates to polycondensates of the formula 10, their use for absorbing metal ions of the transition elements of the periodic system and their use for the preparation of polymers containing metals of formula 11 which have e.g. improved resistance to heat and to chemicals compared to the corresponding polycondensates of formula 10.
摘要:
Catalysts consisting ofA) an alcoholate of the rare earths, a carboxylate of the rare earths, a complex compound of the rare earths with diketones and/or an addition compound of the halides of the rare earths with an oxygen or nitrogen donor compound,B) an aluminium trialkyl, a dialkyl aluminium hydride and/or an alumoxane,C) another Lewis acid andD) an inert, particulate inorganic solid with a specific surface of greater than 10 m.sup.2 /g (BET) and a pore volume of 0.3 to 15 ml/gare eminently suitable for the polymerization of conjugated dienes, more particularly butadiene, in the gas phase.